The chemistry of 1,3-dithiole-2-thione-4,5-dithiolate (dmit)

Coordination Chemistry Reviews

Volumn 117, Issue C, 1992, Pages 99-131

  Olk, Ruth Maria ^a   Olk, Bernhard ^a,b   Dietzsch, Wolfgang ^a   Kirmse, Reinhard ^a   Hoyer, Eberhard ^a  

^a UNIVERSITY OF LEIPZIG   (Germany)

^b Central Institute of Isotope and Radiation Research   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 2842515496     PISSN: 00108545     EISSN: None     Source Type: Journal    
DOI: 10.1016/0010-8545(92)80021-I     Document Type: Article

References (297)

1. Metal 1,2-Dithiolene and Related Complexes
2. Recent Advances in the Chemistry of Transition Metal Complexes of Unsaturated Bidentate Sulfur Donor Ligands (Metal Dithienes)
3. Structural Systematics of 1,1- and 1,2-Dithiolato Chelates
4. Dithiolenchelate
5. Dithiolium Salts and Dithio-β-Diketone Complexes of the Transition Metals
6. Zur Komplexbildung isomerer N-Methyl-thiobenzhydrazide
7. Beiträge zur Chemie des Schwefelkohlenstoffs und Selenkohlenstoffs, II. Die Kondensierende Spontan-Entschwefelung von Salzen und Estern der Cyan-Dithioameisensäure. Freie Cyan-Dithioameisensäure
8. Dimercapto-isotrithion - ein neuer, ungesättigter 1,2-Dithiolatligand
9. 1.3-DITHIOL-2-THION-4.5-DITHIOLAT AUS SCHWEFELKOHLENSTOFF UND ALKALIMETALL
10. New molecular metals based on metal complexes of sulphur donor ligands
11. Synthesis, properties, and structure of conductive and superconductive molecular complexes and derived organometallic polymers
12. Organic Conductors Based on Multi-Sulfur π-Donor And/Or π-Acceptor Molecules-Bedt-Ttf, Bmdt-Ttf, Bpdt-Ttf, And m(dmit)2-
13. The Design, Synthesis and Characterization of the Molecular Components of Organic Conductors
14. Ph.D. Thesis
15. Thion- und Dithioester, XXIV. Synthese von Tetrathiooxalestern
16. Elektrochemische Redukton von Schwefelkohlenstoff in aprotischen Lösungsmitteln
17. Elektrochemische Darstellung von Tetraalkylammoniumsalzen der Tetrathiooxaisäure
18. The Role of Carbon Monosulfide in the Electrochemical Preparation of 4,5-Bis(methylthio)-1,3-dithiole-2-thione.
19. Preparation and Properties of Some New 1-D Solids
20. �ber Chalkogenolate. LXX. Versuche zur Darstellung von Tetrathiooxalaten �ber Alkylthio-1,3-dithiol-2-thione
21. Structures of tetramethylammonium bis(2-thioxo-1,3-dithiole-4,5-dithiolato)niccolate(III) andtetra-n-propylammonium bis(2-thioxo-1,3-dithiole-4,5-dithiolato)niccolate(III)
22. New radical anion complex, [(CH3)4N][Ni(dmit)2]2 with metal-semimetal phase transition.
23. The first molecular superconductor based on .PI.-acceptor molecules and closed-shell cations, [(CH3)4N][Ni(dmit)2]2, low-temperature X-ray studies and superconducting transition.
24. The first molecular superconductor based on the π-acceptor molecule and the closed shell cation, [(CH3)4N][Ni(dmit)2]2
25. Crystal structure and electrical conductivity of (Et4N)0.5(Ni(dmit)2).
26. Nickel Chelates of Trithione- and Isotrithionedithiolate - a New Class of 1,2-Dithiolates. Part I. The Crystal Structure of Tetrabutylammonium Bis(isotrithionedithiolato)nickelate(II).
27. Nickel Chelates of Trithione- and Isotrithionedithiolate -- a New Class of 1,2-Dithiolates. Part III. The Crystal Structure of Tetrabutylammonium Bis(isotrithionedithiolato)nickelate(III).
28. Tetrathiafulvalene. XIX. Synthese und Eigenschaften elektronenleitender Poly-Dithiolenkomplexe mit Ethylentetrathiolat und Tetrathiafulvalentetrathiolat als Br�ckenliganden
29. A new two-dimensional conducting mixed valence compound derived from a nickel bisdithiolato-complex
30. Molecular structure and solid-state properties of the two-dimensional conducting mixed-valence complex [NBu4]0.29[Ni(dmit)2] and the neutral [Ni(dmit)2](H2dmit = 4,5-dimercapto-1,3-dithiole-2-thione); members of an electron-transfer series
31. Structures of twoM(S5C3)2NBu4(M= Pt, Ni) semiconductor salts
32. TWO-DI MENS IONALITY AND ANISOTROPY TO THE CONDUCTIVITY OF A MIXED VALENCE NICKEL BISDITHIOLATO-COMPLEX
33. (n-Bu4N)x[Pd(dmit)2] (x = 0.5 and 0.33): Metal-like conductivity v.s. stacking of “true” dimers with metal-metal bond; Comparison with δ-TTF[Pd(dmit)2]2
34. SOME NEW CONDUCTING COMPLEXES OF NICKEL
35. Structural and electronic properties of a new two-dimensional molecular metal, Et2Me2N[Ni(dmit)2]2
36. Crystal and electronic structures of a new two-dimensional molecular metal, .ALPHA.-Et2Me2N[Ni(dmit)2]2.
37. Conductive Langmuir-Blodgett films of dialkyldimethylammonium-Ni(dmit)2 complexes.
38. Conductive Langmuir-Blodgett films of transition metals with sulfur containing ligands
39. Charge-Transfer-Komplexe von Metalldithiolenen, IV. Viologene als redoxaktive Akzeptoren – Synthese und elektrische Leitfähigkeit
40. Synthesis, Electrical Conductivity, and Crystal Structure of (AsPh4)0.25[Ni(dmit)2]
41. Electrical Properties of 3, 4, 5-Tris (Alkylthio) -1, 2-Dithiolium Charge Transfer COMPLEXES
42. A new type of low-temperature molecular metal based on [Ni(dmit)2] anions (H2dmit = 4,5-dimercapto-1,3-dithiole-2-thione)
43. Highly Conducting Transition Metal Complexes Derived from the DMIT-Ligand
44. Use of Electrochemical Techniques in the Synthesis, Characterization and Application of Molecular Conductors: Cation Effects in the Oxidation and Reduction of TTF[Ni(dmit)2]2Electrodes
45. NMR Analysis of Spin Fluctuations in the Organic Conductor TTF[Ni(dmit)2]2
46. Pressure-temperature phase diagram of α′-TTF [Pd(Dmit)2]2
47. The crystal structure of (BEDT-TTF)(Ni(dmit)2). A new route to design of organic conductors.
48. Origin of the Multi-dimensional Properties and the Charge Distribution Rule of the Molecular Conductors Based on π-Donor and π-Acceptor Molecules
49. New molecular conductors, .ALPHA.- and .BETA.-(EDT-TTF)[Ni(dmit)2]. Metal with anomalous resistivity maximum vs. semiconductor with mixed stacks.
50. Crystal structure of a new molecular conductor (DBTTF)(Ni(dmit)2).
51. Conducting solids based on some new unsymmetrical tetraheterofulvalenes
52. The crystal and electronic structures of a new molecular conductor, (TMTSF)(Ni(dmit)2).
53. The crystal and electronic structures of a new molecular conductor, (HMTTeF)2(Pt(dmit)2).
54. Ferromagnetic interactions in decamethylferrocenium salts of nickel bis(dichalcogenides)
55. Tetrathiafulvalene. XV. M��bauer-spektroskopische Untersuchung von monomeren und polymeren Eisendithiolenkomplexen
56. NEW CONDUCTING IRON COMPLEXES DERIVED FROM THE 1,3-DITHI0L-2-THI0N-4,5-DITHIOLATE LIGAND (DMIT)2-
57. X-Ray crystal structure of bis(N-ethylpyridinum) bis[4,5-dimercapto-1,3-dithiole-2-thionato(2?)]cuprate(II) and electrical properties of its oxidized salts
58. Metallic temperature dependence in the conductivity of langmuir-blodgett films of tridecylmethylammonium-Au(dmit)2.
59. Photophysikalische und photochemische Eigenschaften von Metalldithiolenen
60. Charge-Transfer-Komplexe von Metalldithiolenen mit Viologenen
61. Chem. Abstr.
62. X-Ray crystal structure of (2,2?-bipyrimidine)[1,2-dicyanoethylene-1,2-dithiolato(2?)]platinum(II)?N,N-dimethylformamide and properties of PtS2N2-type complexes
63. Structure and Bonding 70
64. Preparation of Tetrathiafulvalenes (TTF) and their Selenium Analogs -Tetraselenafulvalenes (TSeF)
65. Synthesis, Reactions, and Selected Physico-Chemical Properties of 1,3-and 1,2-Tetrachalcogenafulvalenes
66. Superconducting fluctuations and the peierls instability in an organic solid
67. Crystal structure of the radical-cation radical-anion salt from 2,2?-bi-1,3-dithiole and 7,7,8,8-tetracyanoquinodimethane
68. One-Dimensional Inorganic Complexes
69. „Organische Metalle” – Die intermolekulare Wanderung der Aromatizität
70. Rational Design of Synthetic Metal Superconductors
71. New Organic Superconductors
72. Superconductivity in organic charge transfer salts
73. Electrochemical synthesis of 1,3,4,6-tetrathiapentalene-2,5-dithione
74. Tetrathiafulvalene; Neue polymere Tetrathiafulvalen-Dithiolen-Metallkomplexe mit elektronenleitenden Eigenschaften
75. Tetrathiafulvalene; Photochemische Bildung von Heterofulvalenen und Dithiolenkomplexen
76. ?Organic metals?: alkylthio substitution effects in tetrathiafulvalene?tetracyanoquinodimethane charge-transfer complexes
77. Synthesis and properties of tetrathiafulvalene?metal bisdithiolene macromolecules
78. A novel behavior of electrical resistivity in a new two-dimensional organic metal, (BEDT-TTF)2ClO4(1,1,2-trichloroethane)0.5.
79. Synthesis of Biethylenedithiolylene-Tetrathiafulvalene Donors (BEDT-TTF) and Electrochemical Preparation of their Charge Transfer Complexes
80. Crystal Structures and Electrical Properties of BEDT-TTF Coeipounds
81. (BEDT-TTF)+2J-3: A Two-Dimensional Organic Metal
82. A new series of radical-cation salts based on asymmetrical ethylenedithiodimethyl-tetrathiafulvalene (EDTDM-TTF). Properties and crystal structure of (EDTDM-TTF)2PF6
83. The Study of Charge Transfer Complexes of Bedt-TTF Derivatives
84. Chemical and Physical Properties of Cation Radical Salts of BEDT-TTF
85. Organic superconductor .BETA.-(BEDT-TTF)2IBr2 obtained by diffusion method.
86. Pyrazinoethylenedithiotetrathiafulvalene: a new unsymmetrical ?-donor
87. Chemical and Physical Properties of Capped and Uncapped Alkylthio Substituted Tetrathiafulvalenes and Their Charge Transfer Complexes
88. Uncapped alkylthio substituted tetrathiafulvalenes (TTCn-TTF) and their charge transfer complexes.
89. Electrical conductivities of tetrakis(alkylthio)tetrathiafulvalene(TTCn-TTF) and tetrakis(alkyltelluro)tetrathiafulvalene(TTeCn-TTF).
90. Tetrachalcogenafulvalenes with outer chalcogeno substituents. Precursors of organic metals, superconductors, LB films, etc.
91. Syntheses and physical properties of tetrakis(methylthio)tetraselenafulvalene (TTC1-TSeF) and tetrakis(methylseleno)tetraselenafulvalene(TSeC1-TSeF).
92. Synthesis and properties of tetrakis(alkylseleno)tetrathiafulvalene.
93. Ein Donorkäfig mit verbogener Tetrathiafulvalen-Einheit
94. Bis(phenylethylenedithio)tetrathiafulvalene (BPhEDT-TTF)
95. Reduction der Kohlensäure zu Oxalsäure
96. Tetrathiooxalate. Electrochemical Preparation and X-Ray Structure Determination of a Tetrathiooxalate.
97. Über die Einwirkung von Natriumamalgam auf Schwefelkohlenstoff
98. Structure of 4,5-di(benzoylthio)-4,5-didehydro-1,3-dithiolane-2-thione
99. Syntheses of bis(vinylenedithio)tetrathiafulvalene and bis(methylvinylenedithio)tetrathiafulvalene.
100. New multi-sulfur 1,2-dithiolene complexes. Preparation, structure, and electrochemical properties.
101. A pseudo-centrosymmetric chiral crystal structure: (5S,6S)-5,6-dihydro-5,6-dimethyl-1,3-dithiolo[4,5-b][1,4]dithiin-2-thione
102. Synthetic studies on extended S-donor ligands as potential molecular conductors
103. A NEW SYNTHETIC ROUTE TO 1,3-DITHIOLIUM SALTS INVOLVING NEIGHBORING GROUP PARTICIPATION OF DITHIOCARBAMATE GROUP
104. Thiophilic reaction of 2,4,6-tri-t-butylphenyl-lithium with carbon disulphide: umpolung of the reactivity of carbon disulphide
105. Crowned tetrathiafulvalene derivatives.
106. A crown ether tetrathiafulvalene cage
107. A novel macrocycle containing the 4,5-dithio-1,3-dithiole-2-thione unit and a related macrocycle incorporating the tetrathiafulvalene moiety
108. 1,2-DITHIOL-3-THION-4,5-DITHIOLAT AUS SCHWEFELKOHLENSTOFF UND ALKALIMETALL
109. Nickel Chelates of Trithione- and Isotrithionedithiolate -- a New Class of 1,2-Dithiolates. Part II. The Crystal Structure of Tetramethylammonium Bis(isotrithionedithiolato)nickelate(II).
110. 13C-NMR-spektroskopische Charakterisierung von Derivaten des 1,2-Dithiol-3-thion-4,5-dithiolats (dmt)
111. Trithione- and Isotrithionedithiolate. A New Class of Unsaturated 1,2-Dithiolates. IV. The Crystal Structure of Dipotassium 1,2-Dithiole-3-thion-4,5-Dithiolate, K2C3S5.
112. Transition metal complexes derived from multisulfur ligands
113. Selenium-77 NMR of coordination compounds with unsaturated selenium ligands and/or selenium (II) central ions
114. Tellurium-125 NMR investigations on coordination compounds of tellurium(II) with unsaturated dithio, thioseleno and diseleno ligands
115. Zur Koordinationschemie des 1,3-Dithiol-2-on-4,5-dithiolats (dmid) - ein Vergleich mit 1,3-Dithiol-2-thion-4,5-dithiolat (dmit). Kristall- und Molek�lstruktur des Tetrabutylammonium-bis(1,3-dithiol-2-on-4,5-dithiolato)nickelat(III), (n-C4H9)4N[Ni(dmid)2]
116. Electrochemical reduction of carbon diselenide and preparation of 4,4?,5,5?-tetra(selenomethoxy)tetraselenafulvalene
117. NEW SYNTHETIC APPROACHES TO TETRATHIAFULVALENE DERIVATIVES: SYSTEMATIC MODIFICATIONS OF BEDT-TTF AND TMTTF DONORS
118. Bis(ethylenediseleno)tetraselenafulvalene (BEDSe-TSeF)
119. Bis(2-Thione-1,3-dithiole-4,5-diselenolato)nickelate(II): A Precursor for Mixed Sulfur/Selenium Heterocycles
120. Synthesis of organometallic mixed sulfur-selenium π-acceptor molecules
121. Synthesis of Stable Sources for 1,2-Diselenolate Dianion Chemistry :Bis(2-Selenoxo-1,3-Diselenole-4,5-diselenolato) zincate (II) and 4,5-Benzoylseleno-1,3-diselenole-2-selenone
122. Die elektrochemische Reduktion von CSSe und CSe2 in Dimethylformamid: Heterocyclische 1,2-Dichalkogenolate und ihre Koordinationschemie
123. Synthese und spektroskopische Eigenschaften von 4,5-Dibenzoylseleno-1,3-diselenol-2-selon
124. Crystal structure and properties of (NMe4)2(Cu(C3Se5)2)2MeCN.
125. X-Ray molecular structures of [Zn(C3Se5)2]2? and [Zn(CSe4)2]2? anion complexes
126. 4, 5-Dibenzoylseleno-1, 3-dithiol-2-thion
127. Zur Koordinationschemie des 1,3-Dithiol-2-thion-4,5-diselenolats (dsit) - ein Vergleich mit 1,3-Dithiol-2-thion-4,5-dithiolat (dmit)
128. Zur Koordinationschemie des 1,3-Dithiol-2-selon-4,5-diselenolats (dsise) und des 1,3-Dithiol-2-selon-4,5-dithiolats (dmise). Kristall- und Molek�lstruktur des Tetrabutylammonium-bis-(1,3-dithiol-2-selon-4,5-diselenolato)nickelat(II) und -(III), [(n-C4H9)4N]2[Ni(dsise)2] und (n-C4H9)4N[Ni(dsise)2]
129. Synthese und NMR-spektroskopische Charakterisierung von 4,5-Dibenzoylseleno-1,3-dithiol-2-selon und (Bu4N)2[Zn(dsise)2]
130. The structure of novel conductive dithiolate complexes
131. Novel Solid State Materials Derived from Transition Metal Bis-dithiolene Complexes