Bis(chloromethyl) sulfone and sulfoxide as precursors of the corresponding α,α′-dianionic synthons by a chlorine-lithium exchange

Synthesis

Volumn , Issue 18, 2005, Pages 3095-3102

  Gómez, Cecilia ^a   Maciá, Beatriz ^a   Soler, Tatiana ^a   Yus, Miguel ^a  

^a UNIVERSITY OF ALICANTE   (Spain)

Author keywords

Chloro lithium exchange; Dimethyl sulfone dianion; Dimethyl sulfoxide dianion; DTBB catalyzed lithiation

Indexed keywords

HYDROLYSIS; NEGATIVE IONS; SULFUR COMPOUNDS; SYNTHESIS (CHEMICAL); TEMPERATURE DISTRIBUTION;

CHLORO-LITHIUM EXCHANGE; DIMETHYL SULFONE DIANION; DIMETHYL SULFOXIDE DIANION; DTBB-CATALYZED LITHIATION;

ION EXCHANGE;

1 (1 HYDROXYCYCLOHEXYLMETHYLSULFINYLMETHYL) 1 CYCLOHEXANOL; 1 (1 HYDROXYCYCLOHEXYLMETHYLSULFONYLMETHYL) 1 CYCLOHEXANOL; 1 (1 HYDROXYCYCLOPENTYLMETHYLSULFONYLMETHYL) 1 CYCLOPENTANOL; 1 (2 HYDROXY 2 METHYLPROPYLSULFONYL) 2 METHYL 2 PROPANOL; 1 (2 HYDROXY 2 PHENYLPROPYLSULFONYL) 2 PHENYL 2 PROPANOL; 1 (2 HYDROXY 3,3 DIMETHYLBUTYLSULFINYL) 3,3 DIMETHYL 2 BUTANOL; 1 (2 HYDROXY 3,3 DIMETHYLBUTYLSULFONYL) 3,3 DIMETHYL 2 BUTANOL; 1 CYCLOHEXYL 2 (2 CYCLOHEXYL 2 HYDROXYETHYLSULFONYL) 1 ETHANOL; 1,1 DICYCLOPROPYL 2 (2,2 DICYCLOPROPYL 2 HYDROXYETHYLSULFINYL) 1 ETHANOL; 1,1 DICYCLOPROPYL 2 (2,2 DICYCLOPROPYL 2 HYDROXYETHYLSULFONYL) 1 ETHANOL; 2 (2 HYDROXY 2 PHENYLETHYLSULFONYL) 1 PHENYL 1 ETHANOL; 2 (2 HYDROXYBICYCLO[2.2.1]HEPT 2 YLMETHYLSULFINYLMETHYL)BICYCLO[2.2.1]HEPTAN 2 OL; 2 (2 HYDROXYBICYCLO[2.2.1]HEPT 2 YLMETHYLSULFONYLMETHYL)BICYCLO[2.2.1]HEPTAN 2 OL; 3 (2 ETHYL 2 HYDROXYBUTYLSULFINYLMETHYL) 3 PENTANOL; 3 (2 ETHYL 2 HYDROXYBUTYLSULFONYLMETHYL) 3 PENTANOL; 4 (2 HYDROXY 2 PROPYLPENTYLSULFINYLMETHYL) 4 HEPTANOL; 4 (2 HYDROXY 2 PROPYLPENTYLSULFONYLMETHYL) 4 HEPTANOL; BIS(CHLOROMETHYL)SULFONE; CARBONYL DERIVATIVE; CHLORINE; LITHIUM; NORBORNANE DERIVATIVE; SULFONE DERIVATIVE; SULFOXIDE; UNCLASSIFIED DRUG; WATER;

ARTICLE; CATALYSIS; HYDROLYSIS; LITHIATION; SYNTHESIS; TEMPERATURE; X RAY CRYSTALLOGRAPHY;

EID: 28344434833     PISSN: 00397881     EISSN: None     Source Type: Journal    
DOI: 10.1055/s-2005-918410     Document Type: Article

References (47)

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