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Compound 2 is one of a few crystallographically characterized, dinuclear sodium-iron complexes described to date. See: (a) Steinhauser, S.; Heinz, U.; Sander, J.; Hegetschweiler, K. Z. Anorg. Allg. Chem. 2004, 630, 1829-1838.
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The synthesis of 1 is described elsewhere. See: Kodanko, J. J.; Morys, A. J.; Lippard, S. J. Org. Lett. 2005, 7, 4585-4588.
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The identity of NaOTf was confirmed by IR. See: Vardhan, H. B.; Bach, R. D. J. Org. Chem. 1992, 57, 4948-4954.
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For examples of triply carboxylate-bridged diiron complexes, see: (a) Kuzelka, J.; Farrell, J. R.; Lippard, S. J. Inorg. Chem. 2003, 42, 8652-8662.
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0141628525
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and references therein
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Only a few metal-bound picolinic esters have been characterized by X-ray crystallography. For recent examples, see: March, R.; Clegg, W.; Coxall, R. A.; Cucurull-Sánchez, L.; Lezama, L.; Rojo, T.; González-Duarte, P. Inorg. Chim. Acta 2003, 353, 129-138 and references therein.
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21
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28044432584
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note
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2.
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22
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33747080452
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The observed wavelength and extinction coefficients are consistent with a d-d transition, as measured for an ethyl picolinate Fe(II) complex. Compare: Hay, R. W.; Clark, C. R. Transition Met. Chem. 1979, 4, 28-31.
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