The influence of core size on electronic coupling in shell-core nanoparticles: Gold clusters capped with pyrenoxylalkylthiolate

Photochemical and Photobiological Sciences

Volumn 2, Issue 11, 2003, Pages 1177-1180

  Canepa, Marina ^a   Fox, Marye Anne ^a   Whitesell, James K ^a  

^a NORTH CAROLINA STATE UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

1 DODECANETHIOL; 9 (1 PYRENOXYL)OCTANE 1 THIOL; GOLD; NANOPARTICLE; PYRENE DERIVATIVE; PYRENOXYLALKYLTHIOLATE; THIOL DERIVATIVE; UNCLASSIFIED DRUG;

ABSORPTION SPECTROSCOPY; ARTICLE; CHEMICAL STRUCTURE; FLUORESCENCE SPECTROSCOPY; PRIORITY JOURNAL; SYNTHESIS;

EID: 27944440928     PISSN: 1474905X     EISSN: 14749092     Source Type: Journal    
DOI: 10.1039/b306306b     Document Type: Article

References (15)

1. M. Brust, M. Walker, D. Bethell, D. J. Schiffrin and R. Whyman, Synthesis of thiol-derivatized gold nanoparticles in a two-phase liquid-liquid system, J. Chem. Soc., Chem. Commun., 1994, 801-802.
2. Colloidal Gold: Principles, Methods, and Applications, ed. M. A. Hayat, Academic Press, Inc., San Diego, 1991, vol. 3.
3. R. S. Ingram and R. W. Murray, Electroactive three-dimensional monolayers: anthraquinone ω-functionalized alkanethiolate-stabilized gold clusters, Langmuir, 1998, 14, 4115-4121.
4. Cluster and Colloids, ed. G. Schmid, VCH, Weinheim, 1994.
5. S. Chen, R. S. Ingram, M. J. Hosteller, J. J. Pietron, R. W. Murray, T. G. Schaaff, J. T. Khoury, M. M. Alvarez and R. L. Whette, Gold nanoelectrodes of varied size: transition to molecules-like charging, Science, 1998, 280, 2098-2101.
6. S. Chen and R. W. Murray, Arenethiolate monolayer-protected gold clusters, Langmuir, 1999, 15, 682-689.
7. M. A. Fox and M. D. Wooten, Characterization, adsorption, and photochemistry of self-assembled monolayers of 10-thiodecyl 2-anthryl ether on gold, Langmuir, 1997, 13, 7099-7105.
8. J. Hu and M. A. Fox, A convenient trimethylsilylthioxy-dehalogenation reaction for the preparation of functionalized thiols, J. Org. Chem., 1999, 64, 4959-4961.
9. L. J. De Jongh, H. B. Brom, J. M. Van Ruitenbeek, R. C. Thiel, G. Schmid, G. Longoni, A. Ceriotti, R. E. Benfield and R. Zanoni, Physical and chemical properties of high-nuclearity metal-cluster compounds: model systems for small metal particles, NATO ASI Ser., Ser. B, 1992, 283, 151-168.
10. R. Elghanian, J. J. Storhoff, R. C. Mucic, R. L. Letsinger and C. A. Mirkin, Selective colorimetric detection of polynucleotides based on the distance-dependent optical properties of gold nanoparticles, Science, 1997, 277, 1078-1080.
11. P. Alivisatos, perspectives on the physical chemistry of semiconductor nanocrystals, J. Phys. Chem., 1996, 100, 13226-13239.
12. M. J. Hostetler, J. E. Wingate, C.-J. Zhong, J. E. Harris, R. W. Vachet, M. R. Clark, J. D. Londono, S. J. Green, J. J. Stokes, G. D. Wignall, G. L. Glish, M. D. Porter, N. D. Evans and R. W. Murray, Alkanethiolate gold cluster molecules with core diameters form 1.4 to 5.2 nanometers: core and monolayer properties as a function of core size, Langmuir, 1998, 14, 17-30.
13. U. Kreibig and M. Vollmer, Optical properties of metal clusters, Springer Ser. Mat. Sci., 1995, 25.
14. K. W. Kittredge, M. A. Fox and J. K. Whitesell, Effect of alkyl chain length on the fluorescence of 9-alkylfluorenyl thiols as self-assembled monolayers on gold, J. Phys. Chem., 2001, 105, 2323-2328.
15. R. F. Khairutdinov, Physical chemistry of nanocrystalline semiconductors, Colloid J. (Transl. of Kolloidn. Zh.), 1997, 59, 535-548.