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Volumn 127, Issue 45, 2005, Pages 15706-15707

Nickel-catalyzed trans-alkynylboration of alkynes via activation of a boron-chlorine bond

Author keywords

[No Author keywords available]

Indexed keywords

ALKYNE; BORON; CARBON; CHLORINE; ETHER DERIVATIVE; NICKEL; TIN DERIVATIVE;

EID: 27844533006     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja055396z     Document Type: Article
Times cited : (115)

References (25)
  • 15
    • 84891290003 scopus 로고    scopus 로고
    • Tamaru, Y., Ed.; Wiley: Weinheim, Germany
    • For Ni-catalyzed reactions of alkynes, see: Ikeda, S. In Modern Organonickel Chemistry; Tamaru, Y., Ed.; Wiley: Weinheim, Germany, 2005; p 102.
    • (2005) Modern Organonickel Chemistry , pp. 102
    • Ikeda, S.1
  • 16
    • 0035977619 scopus 로고    scopus 로고
    • As far as we are aware, Pd-catalyzed diboration and silaboration in the presence of alkenyl iodide are the only examples of catalytic reactions in which involvement of oxidative addition of B-X bonds is proposed, although the boron iodide is generated in situ in those reactions, (a) Yang, F.-Y.; Cheng, C.-H. J. Am. Chem. Soc. 2001, 123, 761.
    • (2001) J. Am. Chem. Soc. , vol.123 , pp. 761
    • Yang, F.-Y.1    Cheng, C.-H.2
  • 18
    • 0000463021 scopus 로고
    • For the related alkynylation of alkynes using alkynylstannanes, see: (a) (silylalkynylation, Pd) Chatani, N.; Amishiro, N.; Murai, S. J. Am. Chem. Soc. 1991, 113, 7778.
    • (1991) J. Am. Chem. Soc. , vol.113 , pp. 7778
    • Chatani, N.1    Amishiro, N.2    Murai, S.3
  • 21
    • 0035833290 scopus 로고    scopus 로고
    • Formation of borylpalladium (II) chloride complexes by oxidative addition of the B-Cl bond to a Pd(0) complex has been reported. See: Onozawa, S.-y.; Tanaka, M. Organometallics 2001, 20, 2956. The boryl complex undergoes insertion of alkynes into B-Pd, giving a cis-addition product.
    • (2001) Organometallics , vol.20 , pp. 2956
    • Onozawa, S.-Y.1    Tanaka, M.2
  • 23
    • 0001310248 scopus 로고
    • Carbene-like zwitterionic resonance structures have been proposed for the cis-trans isomerization of the alkenyl transition metal complexes. (a) Brady, K. A.; Nile, T. A. J. Organomet. Chem. 1981, 206, 299.
    • (1981) J. Organomet. Chem. , vol.206 , pp. 299
    • Brady, K.A.1    Nile, T.A.2


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.