Effect of substituents in the manganese μ-oxo porphyrins catalyzed oxidation of cyclooctane with molecular oxygen

Inorganic Chemistry Communications

Volumn 8, Issue 12, 2005, Pages 1125-1127

  Poltowicz J ^a   Tabor, E ^a   Pamin, K ^a   Haber, J ^a  

^a INSTITUTE OF CATALYSIS AND SURFACE CHEMISTRY   (Poland)

Author keywords

oxo metalloporphyrins; Cyclooctane oxidation; Metalloporphyrins

Indexed keywords

EID: 27744586759     PISSN: 13877003     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.inoche.2005.09.003     Document Type: Article

References (11)

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9. -4 M of metallocomplex or μ-oxo metallocomplex was introduced into the reaction mixture (60 mL) when the required reaction conditions were attained. After 6 h of reaction time, the oxidation was stopped by immersing the hot reactor in a cold water bath and the reaction mixture was analyzed by means of Agilent Technologies 689N gas chromatograph with Innowax (30 m) capillary column.
10. Cyclovoltagrams were recorded with the EP-21 potentiostat in 0.1 M tetraethyl ammonium perchlorate/acetonitrile solution. A glassy carbon was a working electrode, SCE was a reference electrode and platinum wire was used as a counter electrode.
11. J. Połtowicz, and J. Haber J. Mol. Catal. A: Chemical 220 2004 43