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0 = 6.1 wt%. However, poly(DMDPM) exhibits very low solubility in liquid R134a under 40 °C and 150 bar when the molecular weight is higher than a few thousand mass units.
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2 to a lower field upon coordination to a transition metal. Values in a range of 150-250 ppm have been reported, and the chemical shifts may differ widely even for complexes with the same coordination mode. A concerted rotation of the two carbon dioxide ligands, in which both molecules rotate in the same direction, has been demonstrated by variable-temperature NMR spectroscopy.
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