An efficient method for determination of the degree of substitution of cellulose esters of long chain aliphatic acids

Cellulose

Volumn 12, Issue 5, 2005, Pages 449-458

  Freire, C S R ^a   Silvestre, A J D ^a   Neto, C Pascoal ^a   Rocha, R M A ^b  

^a UNIVERSITY OF AVEIRO   (Portugal)

^b LECO Instrumentos   (Spain)

Author keywords

Alkaline hydrolysis; Cellulose esters; Degree of substitution (DS); Fatty acids; GC MS

Indexed keywords

ESTERIFICATION; FATTY ACIDS; FOURIER TRANSFORM INFRARED SPECTROSCOPY; GAS CHROMATOGRAPHY; HYDROLYSIS; MASS SPECTROMETRY; POLYESTERS; SUBSTITUTION REACTIONS; SURFACE TREATMENT; VOLUMETRIC ANALYSIS;

ALIPHATIC ACIDS; ALKALINE HYDROLYSIS; GAS CHROMATOGRAPHY-MASS SPECTROMETRY (GC-MS); SUFACE FIBER MODIFICATION;

CELLULOSE DERIVATIVES;

ALIPHATIC COMPOUNDS; CELLULOSE ESTERS; DEGREE OF SUBSTITUTION; ESTERIFICATION; FATTY ACIDS; GAS CHROMATOGRAPHY; HYDROLYSIS; MASS SPECTROMETERS; SURFACE TREATMENT; VOLUMETRY;

CELLULOSE;

EID: 27744460003     PISSN: 09690239     EISSN: None     Source Type: Journal    
DOI: 10.1007/s10570-005-2203-2     Document Type: Article

References (15)

1. K. Blau and J. Halket 1993 Handbook of Derivatives for Chromatography John Wiley & Sons Chichester, UK
2. G. Chauvelon L. Saulnier A. Buleon J.-F. Thibault C. Gourson R. Benhaddou R. Granet and P. Krausz 1999 Acidic activation of cellulose and its esterification by long-chain fatty acid J. Appl. Polym. Sci. 74 1933-1940 10.1002/ (SICI)1097-4628(19991121)74:8<1933::AID-APP7>3.0.CO;2-K
3. K.J. Edgar C.M. Buchanan J.S. Debenham P.A. Rundquist B.D. Seiler M.C. Shelton and D. Tindall 2001 Advances in cellulose ester performance and application Prog. Polym. Sci. 26 1605-1688 10.1016/S0079-6700(01)00027-2
4. C.S.R. Freire A.J.D. Silvestre and C. Pascoal Neto 2002 Identification of new hydroxyl fatty acids and ferulic acid esters in wood of Eucalyptus globulus Holzforschung 56 143-149 10.1515/HF.2002.024
5. D.N.-S. Hon 1996 Chemical Modification of Lignocellulosic Materials Marcel Dekker Inc. New York
6. P. Jandura B.V. Kokta and B. Riedl 2000 Fibrous long-chain organic acid cellulose esters and their characterization by diffuse reflectance FTIR spectroscopy, solid-state CP/MAS 13 C-NMR, and X-Ray Diffraction J. Appl. Polym. Sci. 78 1354-1365 10.1002/ 1097-4628(20001114)78:7<1354::AID-APP60>3.0.CO;2-V
7. P. Jandura B.V. Kokta and B. Riedl 2001 Cellulose fibers/polyethylene hybrid composites: Effect of long chain organic acid cellulose esters and organic peroxide on rheology and tensile properties J. Reinf. Plast. Comp. 20 697-717 10.1177/073168401772679048
8. D. Klemm B. Philipp T. Heinze U. Heinze and W. Wagenknecht 1998 Comprehensive Cellulose Chemistry Wiley-VCG Verlag Germany
9. H. Matsumura J. Sugiyama and W.G. Glasser 2000 Cellulosic nanocomposites. I. Thermally deformable cellulose hexanoates from heterogeneous reaction J. Appl. Polym. Sci. 78 2242-2253 10.1002/ 1097-4628(20001220)78:13<2242::AID-APP20>3.0.CO;2-5
10. G. Samaranayake and W.G. Glasser 1993 Cellulose derivatives with low DS. II. Analysis of alkanoates Carbohyd. Polym. 22 79-86 10.1016/ 0144-8617(93)90069-G
11. C. Satgé B. Verneuil P. Branland R. Granet P. Krausz J. Rozier and C. Petit 2002 Rapid homogeneous esterification of cellulose induced by microwave irradiation Carbohyd. Polym. 49 373-376 10.1016/ S0144-8617(02)00004-8
12. C. Vaca-Garcia and M.E. Borredon 1999 Solvent-free fatty acylation of cellulose and lignocellulosic wastes, part 2: Reaction with fatty acids Bioresource Technol. 70 135-142 10.1016/S0960-8524(99)00034-6
13. C. Vaca-Garcia M.E. Borredon and A. Gaseta 2001 Determination of the degree of substitution (DS) of mixed cellulose esters by elemental analysis Cellulose 8 225-231 10.1023/A:1013133921626
14. P. Wang and B.Y. Tao 1994 Synthesis and characterization of long-chain fatty acid cellulose esters (FACE) J. Appl. Polym. Sci. 52 755-761 10.1002/app.1994.070520605
15. P. Wang and B.Y. Tao 1995 Synthesis of cellulose-fatty acid esters for use as biodegradable plastics J. Environ. Polym. Deg. 3 115-119 10.1007/ BF02067487