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L). All samples were prepared such that the polymer-to-phospholipid ratio was held between 8 mol %. Hydration of the solid components in deionized water was accomplished by repeated cycles of heating (50°C), vortex mixing, and cooling on an ice bath until sample uniformity was achieved. 4-Nitro-4′-(dimethylamino)azobenzene (TCI America, Portland, OR) was introduced as a solid into the preformed complex fluid and dissolution promoted by cycling through the phase transition. Dye-doped poly(methyl methacrylate), PMMA (MW 120 000, Sigma-Aldrich, St. Louis, MO), was prepared by dissolution of the polymer and chromophore at 2 wt % in toluene. Thin solid films were prepared by spin-coating the prefiltered solution onto clean glass substrates. After evaporation of the solvent at room temperature, the films were dried under vacuum to ensure removal of the casting solvent. Film thicknesses were between 0.5 and 1 μm thick as determined by measurement using a profilometer.
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27744600547
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m) was taken as the temperature at the peak of the endothermic transition.
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27744482248
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UV-vis absorption spectra were recorded on a Gary model 5G UV-vis-NIR spectrophotometer or an Ocean Optics (Dunedin, FL) SD2000 fiber-optic spectrometer that was outfitted with a Peiltier capable of controlling the sample temperature between 10 and 35°C ± 0.7°C.
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27744599242
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2 area, Edmund Optics) covered with a 630 nm interference band-pass filter (Oriel, Stanford, CT) was used to record the voltage (intensity) using an analogdigital converter (PMD-DAQ & SOFTwire program, Measurement Computing, Middleboro, MA). Measurements made on the complex fluids were carried out in a 3 mm square quartz cuvette employing a custom-built Peilter stage for temperature control (±1°C).
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