Ethyl acrylate-hydroxyethyl acrylate and hydroxyethyl acrylate-methacrylic acid: Reactivity ratio estimation from cross-linked polymer using high resolution magic angle spinning spectroscopy

Journal of Macromolecular Science - Pure and Applied Chemistry

Volumn 42 A, Issue 10, 2005, Pages 1369-1385

  Sahloul, N ^a   Emwas, A ^a   Power, W ^a   Penlidis, A ^a  

^a UNIVERSITY OF WATERLOO   (Canada)

Author keywords

Copolymerization; Ethyl acrylate; High resolution magic angle spinning; Hydroxyethyl acrylate; Methacrylic acid; Reactivity ratio estimation; Solution polymerization

Indexed keywords

COMPOSITION; COMPUTER SOFTWARE; COPOLYMERIZATION; COPOLYMERS; FREE RADICAL POLYMERIZATION; GELS;

ETHYL ACRYLATE; HIGH RESOLUTION MAGIC ANGLE SPINNING; HYDROXYETHYL ACRYLATE; METHACRYLIC ACID; REACTIVITY RATIO ESTIMATION; SOLUTION POLYMERIZATION;

POLYACRYLATES;

EID: 27744442973     PISSN: 10601325     EISSN: 15205738     Source Type: Journal    
DOI: 10.1080/10601320500205558     Document Type: Article

References (13)

1. Novak, R.W. (1991) Encyclopedia of Chemical Technology; Wiley and Sons: New York; Vol. 1, 314.
2. Ana, V., Castilla, C.I., and Jose Maria, M. (2003) Water sorption properties of poly (ethyl acrylate-co-hydroxyethyl methacrylate) macroporous hydrogels. Macromol Symp., 200 (Functional Networks and Gels).
3. Montheard, J.P., Chatzopoulos, M., and Chappard, D. (1992) Hydroxyethyl methacrylate (HEMA): Chemical and applications in biomedical fields. J. Macromol. Sci., C32: 1.
4. Kageyama, H.; Kobayashi, T.; Ikeda, S.. Aqueous pigment pastes and thei manufacture and use in paints. Patent No. EP-459634 Date: 19911204.
5. Yasunaga, H. and Ando, I. (1993) A 13C PST/MAS NMR study of the structure and molecular motion of a crosslinked polymer in the gel phase. J. Molecular Structure, 30 (1-3): 129-136.
6. Rault, J., Lucas, A., Naffati, R., and Monleon Pradas, M. (1997) Thermal transition in hydrogels of Poly(ethyl acrylate)/poly(hydroxyethyl acrylate) interpenetrating networks. Macromolecules, 30: 7866-7873.
7. Catala, J.M., Nonn, A., Pujol, J.M., and Brossas, J. (1986) Radical copolymerization of 2-hydroxyethyl acrylate with alkylacrylate. Polym. Bull, 15: 311-315.
8. McIsaac, S. (1994) A kinetic study of styrene-ethyl acrylate copolymerization. Department of Chemical Engineering, University of Waterloo M.A.Sc. Thesis.
9. Chen, M., Han, Z., Huang, L., and Wu, P. (1997) Measurement of relative reactivity ratios of hydroxyethyl acrylate and butyl acrylate by nuclear magnetic resonance spectrometry. Huadong Ligong Daxue Xuebao, 23 (2): 210 (via translation).
10. Tidwell, P. and Mortimer, G.J. (1965) An improved method of calculating copolymerization reactivity ratios. Polym. Sci. Part A, 3: 369.
11. Power, W.P. (2003) High resolution magic angle spinning applications to solid phase synthetic systems and other semi-solids. Ann. Rep. NMR Spectrosc., 51: 261.
12. Brandrup, J. and Immergut, E. (1989) Polymer Handbook; Wiley Interscience: New York.
13. Polic, A., Duever, A., and Penlidis, A. (1998) Case studies and literature review on the estimation of copolymerization reactivity ratios. J. Polym. Sci. Part A: Polym. Chem., 36: 813.