Between myth and reality: Mummy pigment from the Hafkenscheid collection

Studies in Conservation

Volumn 50, Issue 3, 2005, Pages 161-178

  Languri, Georgiana M ^a   Boon, Jaap J ^b  

^a DSM RESOLVE   (Netherlands)

^b FOM INSTITUTE AMOLF   (Netherlands)

Author keywords

[No Author keywords available]

Indexed keywords

ASPHALT; BACTERIA; DEGRADATION; FATTY ACIDS; FUNGI; GAS CHROMATOGRAPHY; LIPIDS; MASS SPECTROMETRY; OILS AND FATS; OXIDATION; RESINS;

DIRECT TEMPERATURE RESOLVED MASS SPECTROMETRY (DTMS); LINSEED OIL; LIPID FRACTION; MEGILP; MUMMY PIGMENT; MYRISTIC ACID;

PIGMENTS;

BACTERIA (MICROORGANISMS); CONIFEROPHYTA;

EID: 27644546855     PISSN: 00393630     EISSN: None     Source Type: Journal    
DOI: 10.1179/sic.2005.50.3.161     Document Type: Article

References (86)

1. McHenry, R. (ed.), The New Encyclopaedia Britannica, 15th edn, Vols. 4 and 8, Encyclopaedia Britannica, Chicago (1992).
2. Woodcock, S., 'Body colour: the misuse of mummy', The Conservator 20 (1996) 87-94.
3. Pey, I., 'The Hafkenscheid Collection. The "sample book" of the Amsterdam paintware trader, Michiel Hafkenscheid (1772-1846) from A(sphaltum) to Z(innober green)', in Looking through paintings, Leids Kunsthistorisch Jaarboek XI, ed. E. Hermens, Uitgeverij de Prom and Archetype Publications (1998) 465-500.
4. Gettens, R.J., and Stout, G.L., Painting Materials. A Short Encyclopaedia, Dover Publications, New York (1966).
5. Yen, T.F., 'Asphaltic materials', in Encyclopaedia of Polymer Science and Engineering, 2nd edn, index volume, Wiley-Interscience (1990) 1-10.
6. Bilkady, Z., Babylon to Baku, Stanhope-Seta, London (1996) 89-211.
7. Nissenbaum, A., 'Molecular archaeology: organic geochemistry of Egyptian mummies', Journal of Archaeological Scienee 19 (1992) 1-6.
8. White, R., 'Brown and black organic glazes, pigments and paints', National Gallery Technical Bulletin 10 (1986) 58-71.
9. Lucas, A., Ancient Egyptian Materials and Industries, 4th edn, History and Mysteries of Man, London (1962) 271, 303-308.
10. D'Auria, S., Lacovara, P., and Roehrig, C.H., Mummies and Magic. The Funerary Arts of Ancient Egypt (Reprinted with changes by the Dallas Museum of Arts from the 1988 Boston edition), Museum of Fine Arts, Boston (1992) 9, 14-19.
11. Zaki, A., and Iskander, Z., 'Materials and method used for mummifying. The body of Amentefnekht, Saqqara 1941', Annales du Service des Antiquités de l'Egypte (1943) 223-250.
12. Buckley, S.A., and Evershed, R.P., 'Organic chemistry of embalming agents in Pharaonic and Graeco-Roman mummies', Nature 413 (2001) 837-841.
13. Wisseman, S., 'Preserved for the afterlife', Nature 413 (2001) 783-784.
14. Proefke, M.L., and Rinehart, K.L., 'Analysis of an Egyptian mummy resin by mass spectrometry', Journal of the American Society for Mass Spectrometry 3 (1992) 582-589.
15. Connan, J., 'Use and trade of bitumen in antiquity and prehistory: molecular archaeology reveals secrets of past civilisations', Philosophical Transactions of the Royal Society of London, B 354 (1999) 33-50.
16. Harell, J.A., and Lewan M.D., 'Sources of mummy bitumen in ancient Egypt and Palestine', Archaeometry 44(2) (2002) 285-293.
17. Nissenbaum, A., 'Utilization of Dead Sea asphalt throughout history', Reviews in Chemical Engineering 9(3-4) (1993) 365-383.
18. Connan, J., Nissenbaum, A., and Dessort, D., 'Molecular archaeology: export of Dead Sea asphalt to Canaan and Egypt in the Chalcolithic-Early Bronze Age (4th-3rd millennium BC)', Geochimica et Cosmochimica Acta 56 (1992) 2743-2759.
19. Harley, R., Artists' Pigments c. 1600-1835. A study in English Documentary Sources, 2nd edn, Butterworth Scientific, London (1982) 148-163.
20. Nissenbaum, A., 'Dead Sea asphalt: historical aspects', The American Association of Petroleum Geologists Bulletin 62(5) (1978) 837-844.
21. Forbes, R.J., Bitumen and Petroleum in Antiquity, E.J. Brill, Leiden (1936) 93-95.
22. Carlyle, L.A., A Critical Analysis of Artists' Handbooks, Manuals and Treatises on Oil Painting Published in Britain Between 1800-1900: with Reference to Selected Eighteenth Century Sources, unpublished PhD dissertation, University of London (1991) Vol. 1, 141-149; Vol. 2 158-165, 201-209.
23. Carlyle, L., The Artist's Assistant. Oil painting Instruction Manuals and Handbooks in Britain 1800-1900 with Reference to Selected Eighteenth-century Sources, Archetype, London (2001) 101-106; 209-210; 391-409; 479-484.
24. Pey, E.B.F., 'De firma Michiel Hafkenscheid en Zoon. Een negentiende-eeuwse handel in schildermaterialen te Amsterdam', Bulletin KNOB 86(2) (1987) 49-70.
25. Doerner, M., Malmaterial und seine Verwendung im Bilde, Ferdinand Enke Verlag, Stuttgart (1976) 45.
26. Bothe, C.I., 'Organic brown pigments', in Artists' Pigments, Vol. 4, ed. B. Berrie, National Gallery of Art, Washington DC (2005), forthcoming.
27. Languri, G.M., Molecular Studies of Asphalt, Mummy and Kassel Earth Pigments: Their Characterisation, Identification and Effect on the Drying of Traditional Oil Paint, published PhD dissertation (MolArt report 9), University van Amsterdam, FOM-AMOLF (2004).
28. Spielmann, P.E., 'To what extent did the ancient Egyptians employ bitumen for embalming?', Journal of Egyptian Archaeology XVIII (1932) 177-180.
29. Benson, G.G., Hemingway, S.R., and Leach, F.N., 'The analysis of the wrappings of Mummy 1770', in Manchester Museum Mummy Project, ed. A.R. David, Manchester University Press, Manchester (1979) 119-131.
30. Petit, J., 'Une substance curieuse: la momie', Double Liaison-Chimie des Peintures 328-329 (1983) 23/29-27/33.
31. Èejka, J., Frydrych, M., Kaprálová, F., and Urbanec, Z., 'Contribution to the chemical research on Egyptian mummies', Zeitschrifi für Egypt. Sprache und altertunskunde 103(2) (1976) 128-139.
32. Colombini, M.P., Modugno, F., Silvano, F., and Onor, M., 'Characterization of the balm of an Egyptian mummy from the seventh century BC', Studies in Conservation 45 (2000) 19-29.
33. Colombini, M.P., and Modugno, F., 'Characterisation of organic materials in works of art by gas chromatography-mass spectrometry', in 6th International Conference of the Associazione Italiana Prove Non Destruttive Monitoraggio Diagnostica on Non Destructive Testing Microanalysis for the Diagnostics and Conservation of the Cultural and Environmental Heritage, ed. C. Parisi, Rome (1999) 1163-1171.
34. Proefke, M.L., Rinehart, K.L., Raheel, M., Ambrose, S.H., and Wisseman, S.U., 'Probing the mysteries of ancient Egypt. Chemical analysis of a Roman period Egyptian mummy', Analytical Chemistry 64(2) (1992) 105A-111A.
35. Rullkötter, J., and Nissenbaum, A., 'Dead Sea asphalt in Egyptian mummies: molecular evidence', Naturwissenschafien 75 (1988) 618-621.
36. Wright, M.M., and Wheals, B.B., 'Pyrolysis-mass spectrometry of natural gums, resins, and waxes and its use for detecting such materials in ancient Egyptian mummy cases (cartonnages)', Journal of Analytical and Applied Pyrolysis 11 (1987) 195-211.
37. Maurer, J., Möhring, T., Rullkötter, J., and Nissenbaum, A., 'Plant lipids and fossil hydrocarbons in embalming material of Roman period murmmes from the Dakhleh Oasis, Western Desert, Egypt', Journal of Archaeological Science 29 (2002) 751-762.
38. Marschner, R.F., and Wright, H.T., 'Asphalts from Middle Eastern archaeological sites', Advances in Chemistry Series, Archeological Chemistry 2 171 (1978) 150-171.
39. Koller, J., Baumer, U., Kaup, Y., Estpüler, H., and Weser, U., 'Embalming was used in Old Kingdom', Nature 391 (1998) 343-344.
40. Buckley, S.A., Stott, A.W., and Evershed, R.P., 'Studies of organic residues from ancient Egyptian mummies using high temperature-gas chromatography-mass spectrometry and sequential thermal desorption-gas chromatography-mass spectrometry and pyrolysis-gas chromatography-mass spectrometry', Analyst 124 (1999) 443-452.
41. Edwards, H.G.M., Farwell, D.W., Heron, C.P., Croft, H., and David, A.R., 'Cats' eyes in a new light: Fourier transform Raman spectroscopic and gas chromatographic-mass spectrometric study of Egyptian mummies', Journal of Raman Spectroscopy 30 (1999) 139-146.
42. Tchapla, A., Goursaud, S., Bleton, J., Mejanelle, P., Héron, S., Lesellier, E., and Pardo, C., 'Identification des constituants organiques des objets d'art ou archéologiques. The characterisation of organic matter from artistic or archaeological objects', Plein Sud- Spécial Recherche (1996) 59-65.
43. Hodge, K.C., and Newton, G.A., 'Radiocarbon dating', in Manchester Museum Mummy Project, ed. A.R. David, Manchester University Press, Manchester (1979) 137-147.
44. Languri, G.M., van der Horst, J., and Boon, J.J., 'Characterisation of a "unique" asphalt sample from the early 19th century Hafkenscheid painting materials collection by analytical pyrolysis MS and GC/MS', Journal of Analytical and Applied Pyrolysis 63 (2002) 171-196.
45. Languri, G.M., van der Horst, J., and Boon, J.J., Erratum to 'Characterisation of a "unique" asphalt sample from the early 19th century Hafkenscheid painting materials collection by analytical pyrolysis MS and GC/MS', Journal of Analytical and Applied Pyrolysis 64 (2002) 123-124.
46. Nali, M., Corana, F., and Montanary, L., 'Pyrolysis/gas chromatography/ mass spectrometry in the analysis of asphaltenes', Rapid Communications in Mass Spectrometry 7 (1993) 684-687.
47. Peters, K.E., and Moldowan, J.M., The Biomarker Guide. Interpreting Molecular Fossils in Petroleum and Ancient Sediments, Prentice Hall, New Jersey (1993) 70-74, 76-77.
48. Seifert, W.K., Carlson, R.M.K., and Moldowan, J.M., 'Geomimetic synthesis, structure assignment and geochemical correlation application of monoaromatized petroleum steroids', Advances in Organic Geochemistry (1981) 710-724.
49. Charrié-Duhaut, A., Lemoine, S., Adam, P., Connan, J., and Albrecht, P., 'Abiotic oxidation of petroleum bitumens under natural conditions', Organic Geochemistry 31 (2000) 977-1003.
50. van der Doelen, G.A, Molecular Studies' of Fresh and Aged Triterpenoid Varnishes, published PhD dissertation (MolArt report 1), University van Amsterdam, FOM-AMOLF (1999).
51. van der Doelen, G.A., van den Berg, K.J., and Boon, J.J., 'Comparative chromatographic and mass-spectrometric studies of triterpenoid varnishes: fresh material and aged samples from paintings', Studies in Conservation 43 (1998) 249-264.
52. van der Doelen, G.A., van den Berg, K.J., Boon, J.J., Shibayama, N., de la Rie, E.R., and Genuit, W.J.L., 'Analysis of fresh triterpenoid resins and aged triterpenoid varnishes by high-performance liquid chromatography-atmospheric pressure chemical ionisation (tandem) mass spectrometry', Journal of Chromatography A 809 (1998) 21-37.
53. Scalarone, D., van der Horst, J., Boon, J.J., and Chiantore, O., 'Direct-temperature mass spectrometric detection of volatile terpenoids and natural terpenoid polymers in fresh and artificially aged resins', Journal of Mass Spectrometry 38(6) (2003) 607-617.
54. Pey, E.B.F., 'The organic pigments of the Hafkenscheid Collection', Restauro 95(2) (1989) 146-150.
55. Pey, E.B.F., 'The Hafkenscheid Collection. A collection of pigments and painting materials dating from the first half of the 19th century', Maltechnick-Restauro 93(2) (1987) 23-33.
56. Carlyle, L.A., and Southall, A., 'No short mechanic road to fame. The implications of certain artists' materials for the durability of British painting: 1770-1840', in Robert Vernon's Gift. British Art for the Nation 1847, ed. R. Hamlyn, Tate Gallery, London (1993) 21-26.
57. Boon, J.J., 'Analytical pyrolysis mass spectrometry: new vistas opened by temperature-resolved in-source PYMS', International Journal of Mass Spectrometry and Ion Process 118/119 (1992) 755-787.
58. van den Berg, K.J., Boon, J.J., Pastorova, I., and Spetter, L.F.M., 'Mass spectrometric methodology for the analysis of highly oxidized diterpenoid acids in old master paintings', Journal of Mass Spectrometry 35(4) (2000) 512-533.
59. van den Berg, J.D.J., and Boon, J.J., 'Unwanted alkylation during direct methylation of fatty (di)acids using tetramethylammonium hydroxide reagent in a Curie-point pyrolysis unit', Journal of Analytical and Applied Pyrolysis 61 (2001) 45-63.
60. Hashimoto, N., Aoyama, T., and Shiori, T., 'New methods and reagents in organic synthesis. 14. A simple efficient preparation of methyl esters with trimethylsilyldiazomethane and its application to gas chromatographic analysis of fatty acids', Chemical Pharmaceutical Bulletin 29 (1981) 1475.
61. Bielleman, J.-F., 'Configuration en C-20 du dittrocarptol', Bulletin de la Société Chimique de France 9 (1967) 3459-3462.
62. Budzikiewicz, H., Wilson, J.M., and Djerasi, C., 'Mass spectrometry in structural and stereochemical problems. XXXII. Pentacyclic triterpenes', Journal of the American Chemical Society 85 (1963) 3688-3699.
63. Enzell, C.R., and Wahlberg, I., 'Terpenes and Terpenoids', in Biochemical Applications of Mass Spectrometry. First supplementary volume, ed. G.R. Waller and O.C. Derner, Wiley Interscience, New York (1980) 311-406.
64. McLafferty, F.W., and Stauffer, D.B., The Wiley/NBS Registry of Mass Spectral Data, Vol. 2, Molecular Weights 198-258, John Wiley & Sons, New York (1989).
65. van den Berg, J.D.J., Analytical Chemical Studies on Traditional Linseed Oil Paints, pubhshed PhD dissertation (MolArt report 6), University van Amsterdam, Amsterdam, FOM-AMOLF (2002).
66. McLafferty, F.W., and Stauffer, D.B., The Wiley/NBS Registry of Mass Spectral Data, vol. 3, Molecular Weights 259-314, John Wiley & Sons, New York (1989).
67. Nelson, D.R., and Blomquist, G., 'Insect waxes', in Waxes: Chemistry, Molecular Biology and Funaions, ed. K.J. Hamilton, Bell and Bain, Glasgow (1995) 1-90.
68. Ogunkoya, L., 'Application of mass spectrometry in structural problems in triterpenes', Phytochemistry 20 (1981) 121-126.
69. El'kin, J.N., Dzizenko, A.K., and Eljakov, G.B., 'Mass spectrometric study of some triterpenes', Khimiia Prirodnykh Soedinenii 7 (1971) 286-294.
70. Wyrzykiewicz, E., Wrzeciono, U., and Zaprutko, L., 'Triterpenoids. Part IV. Mass spectrometry of pentacyclic triterpenoids: 18β- and 18α-11-oxooleanohc acid derivatives', Organic Mass Spectrometry 24 (1989) 105-108.
71. Townsend, J., 'Nineteenth-century paint media: the formulation and properties of megilps', in IIC Congress, Painting Techniques History, Materials and Studio Practice, Dublin, 1998, ed. A. Roy and P. Smith, IIC, London (1998) 205-210.
72. Kolattukudy, P.E., Chemistry and Biochemistry of Natural Waxes, Elsevier, Amsterdam (1976) 201-229.
73. Boon, J.J., Rainford D., and Pureveen, J., 'Massaspectrometrische analyse van wassen', Kunstmagazine 9 (1994) 13-15.
74. McLafferty, F.W., Interpretation of Mass Spectra, 3rd edn, University Science Books, Mill Valley (1980) 285.
75. Koller, J., Baumer, U., Grosser, D., and Schmid, E., 'Mastix/Mastic', in Lacke des Barock und Rokoko/Baroque and Rococo Lacquers, ed. K. Walch and J. Koller, Karl M. Lipp Verlag, München (2003) 347-358 [reprint of 1997 edition].
76. Pastorova, I., Chemically Linking Past and Present: Comparative Studies of Chars and Resins, unpublished PhD dissertation, University van Amsterdam (1997) 104-107.
77. Mills, J.S. and White, R., The Organic Chemistry of Museum Objects, 2nd edn, Butterworth-Heinemann, Oxford (1994) 33.
78. Pastorova, I., van der Berg, K.J., Boon, J.J., and Verhoeven, J.W., 'Analysis of oxidised diterpenoid acids using thermally assisted methylation with TMAH', Journal of Analytical and Applied Pyrolysis 43 (1997) 41-57.
79. Gillan, F.T, and Johns, R.B., 'Chemical markers for marine bacteria: fatty acids and pigments', in Biological Markers in the Sedimentary Record, ed. R.B. Johns, Elsevier, New York (1986) 291-306.
80. Papageorgiou, V.P., Bakola-Christianopoulou, M.N., Apazidou, K.K., and Psarros, E.E., 'Gas chromatographic-mass spectroscopic analysis of the acidic triterpenic fraction of mastic gum', Journal of Chromatography A 769 (1997) 263-273.
81. Lantz, J.-P., and Wolff, R.E., 'Structure d'un nouvel acide triterpénique, l'acide shoréique', Bulletin de la Société Chimique de France 5 (1968) 2131-2133.
82. Marner, F.-J., Freyer, A., and Lex, J., 'Triterpenoids from gum mastic, the resin of Pistacia lentiscus', Phytochemistry 30(11) (1991) 3709-3712.
83. Barton, D.H.R., and Seoane, E., 'Triterpenoids. Part XXII. The constitution and stereochemistry of masticadienoic acid', Journal of the Chemical Society (1956) 4150-4157.
84. Williams, W., An Essay on the Mechanic of Oil Colours, S. Hazard (1787) 43.
85. Mérimée, J.F.L., The Art of Painting in Oil and in Fresco, Whittaker & Co., London (1839) 181.
86. Boitelle, R., Reconstructions of Bituminous Paints Based on 19th Century Sources, unpublished report, Stichting Restauratie Atelier Limburg, Maastricht (1999).