Structure-property relationships for model heterocyclic polymer networks: Effect of network density

Journal of Macromolecular Science - Physics

Volumn 44 B, Issue 5, 2005, Pages 697-709

  Kramarenko, Victor Yu ^a   Alig, Ingo ^b   Privalko, Valery P ^c  

^a NATIONAL TECHNICAL UNIVERSITY   (Ukraine)

^b FRAUNHOFER INSTITUTE FOR STRUCTURAL DURABILITY AND SYSTEM RELIABILITY LBF   (Germany)

^c INSTITUTE OF MACROMOLECULAR CHEMISTRY   (Ukraine)

Author keywords

Glass transition; Heterocyclic networks; Network density; Viscoelastic behavior

Indexed keywords

DIELECTRIC RELAXATION; DIFFERENTIAL SCANNING CALORIMETRY; GLASS TRANSITION; MONOMERS; ORGANIC POLYMERS; REACTION KINETICS; SPECTROSCOPIC ANALYSIS; STOICHIOMETRY; VISCOELASTICITY;

DYNAMIC MECHANICAL SPECTROSCOPY; HETEROCYCLIC POLYMER NETWORKS (HPN); NETWORK DENSITY; VISCOELASTIC BEHAVIOR;

MACROMOLECULES;

EID: 27644494406     PISSN: 00222348     EISSN: 1525609X     Source Type: Journal    
DOI: 10.1080/00222340500251139     Document Type: Article

References (29)

1. Flory, P.J. Principles of Polymer Chemistry; Cornell Univ. Press: Ithaca, 1953.
2. Treloar, L.R.G. The Physics of Rubber Elasticity, 3rd Ed.; Oxford Univ. Press: Clarendon, 1975.
3. Mark, J.E.; Erman, B. Rubberlike Elasticity. A Molecular Primer; Wiley-Interscience: New York, 1988.
4. Irzhak, V.I.; Rozenberg, B.A.; Enikolopyan, N.S. Polymer Networks: Synthesis, Structure, Properties; Nauka, Moscow, 1979 (in Russian).
5. Roland, C.M. Constraints on local segmental motion in poly(vinylethylene) networks. Macromolecules 1994, 27, 4242-4247.
6. Glatz-Reichenbach, J.K.W.; Sorriero, L.J.; Fitzgerald, J.J. Influence of cross-linking on the molecular relaxation of an amorphous copolymer near its glass-transition temperature. Macromolecules 1994, 27, 1338-1343.
7. Crawford, E.; Lesser, A.J. The effect of network architecture on the thermal and mechanical behavior of epoxy resins. J. Polym. Sci., Polym. Phys. 1998, 36, 1371-1382.
8. Kramarenko, V.Yu.; Ezquerra, T.A.; Sics, I.; Balta Calleja, F.J.; Privalko, V.P. Influence of cross-linking on the segmental dynamics in model polymer networks. J. Chem. Phys. 2000, 113, 447-452.
9. Kramarenko, V.Yu.; Ezquerra, T.A.; Privalko, V.P. Probing the subglass relaxation behavior in model heterocyclic polymer networks by dielectric spectroscopy. Phys. Rev. E 2001, 64, 051802-1-051802-7.
10. Kramarenko, V.Yu.; Ezquerra, T.A.; Privalko, V.P. Relationships between conductivity and local topology in heterocyclic polymer networks. Phys. Rev. E 2003, 67, 031801-1-031801-7.
11. Tobolsky, A.V.; Carlson, D.W.; Indictor, N. Rubber elasticity and chain configuration. J. Polymer Sci. 1961, 54, 175-192.
12. Nielsen, L.E. Mechanical Properties of Polymers and Composites; Marcel Dekker Inc.: New York, 1974.
13. Angell, C.A. Relaxation in liquids, polymers and plastic crystals - strong/fragile patterns and problems. J. Non-Cryst. Solids 1991, 131-133, 13-31.
14. 1 = 16-17 in the WLF equation is physical - and the fragility of polymers. Polymer 1997, 38, 6261-6266.
15. Bohmer, R.; Ngai, K.L.; Angell, C.A.; Plazek, D.J. Nonexponential relaxations in strong and fragile glass formers. J. Chem. Phys. 1993, 99, 4201-4209.
16. Fox, T.G.; Loshaek, S. Influence of molecular weight and degree of crosslinking on the specific volume and the glass transition of polymers. J. Polymer Sci. 1955, 40, 371-390.
17. Couchman, P.R. The composition dependent glass transition: relation between temperature, pressure and composition. Polym. Eng. Sci. 1984, 24, 135-142.
18. Donth, E.-J. Relaxation and Thermodynamics in Polymers. Glass Transition; Akademie Verlag: Berlin, 1992.
19. Donth, E. Characteristic length of the glass transition. J. Polymer Sci. Physics 1996, 34, 2881-2892.
20. Hempel, E.; Hempel, G.; Hensel, A.; Schick, C.; Donth, E. Characteristic length and dynamic glass transition near Tg for a wide assortment of glass-forming substances. J. Phys. Chem. B 2000, 104, 2460-2466.
21. Donth, E. Does temperature fluctuate? The fluctuation-dissipation theorem considered as an equation describing quantum mechanical experiments, and application to the dynamic glass transition. J. Phys. Condens. Matter 2000, 12, 10371-10388.
22. Shteinberg, V.G.; Efremova, A.I.; Rosenberg, B.A. Influence of cross-linking density on relaxation properties of polymers. Polymer Sci. 1979, A 21, 1259-1263.
23. Shibayama, K.; Suzuki, Y. Effect of crosslinking density on the viscoelastic properties of unsaturated polyesters. J. Polym. Sci. 1965, A 3, 2637-2651.
24. Katz, D.; Salee, G. Crosslinked oligoethylene glycols: correlation between their structure and some rheological properties. J. Polym. Sci. A-2 1968, 6, 801-811.
25. Pang, K.P.; Gilham, J.K. Anomalous behavior of cured epoxy resins: density at room temperature versus time and temperature of cure. J. Appl. Polym. Sci. 1989, 37, 1969-1991.
26. Shan, L.; Robertson, C.G.; Verghese, K.N.; Burts, E.; Riffle, J.S.; Ward, T.C.; Reifsnider, K.L. Influence of vinyl ester/styrene network structure on thermal and mechanical behavior. J. Appl. Polym. Sci. 2001, 80, 917-927.
27. Rault, J. Origin of the Vogel-Fulcher-Tammann law in glass-forming materials: the α-β bifurcation. J. Non.-Cryst. Solids 2000, 271, 177-217.
28. Ward, I.M. Mechanical Properties of Solid Polymers; Wiley-Interscience: London, 1975.
29. Badamshina, E.R.; Grigoryeva, V.A.; Komratova, V.V.; Kuzaev, A.I.; Baturin, S.M. Gel permeation chromatography study of copolycyclotrimerization of aliphatic mono- and diisocyanates. Polym. Sci. 1993, A35, 179-182.