Absorption spectrum of the hydrated electron paired with nonreactive metal cations

Radiation Physics and Chemistry

Volumn 74, Issue 5, 2005, Pages 288-296

  Bonin, Julien ^a   Lampre, Isabelle ^a   Mostafavi, Mehran ^a  

^a UNIVERSITÉ PARIS SUD   (France)

Author keywords

Absorption spectroscopy; Alkaline; Earth alkaline; Hydrated electron; Terbium

Indexed keywords

ABSORPTION SPECTROSCOPY; HYDRATION; POSITIVE IONS;

EARTH ALKALINE; HYDRATED ELECTRON; SALT CONCENTRATION;

ELECTRONS;

CHLORIDE; METAL ION; PERCHLORATE; WATER;

ABSORPTION SPECTROSCOPY; ARTICLE; CONCENTRATION (PARAMETERS); ELECTRON; SPECTRAL SENSITIVITY;

EID: 27644455498     PISSN: 0969806X     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.radphyschem.2005.03.016     Document Type: Article

References (48)

1. J.C. Alfano, P.K. Walhout, Y. Kimura, and P.F. Barbara Ultrafast transient-absorption spectroscopy of the aqueous solvated electron J. Chem. Phys. 98 7 1993 5996 5998
2. M. Anbar, and E.J. Hart The effect of solvent and solutes on the absorption spectrum of solvated electrons J. Phys. Chem. 69 4 1965 1244 1247
3. M. Anbar, and J.K. Thomas Pulse radiolysis studies of aqueous sodium chloride solutions J. Phys. Chem. 68 12 1964 3829 3835
4. 2O solutions ? J. Phys. Chem. A 103 32 1999 6339 6343
5. M. Assel, R. Laenen, and A. Laubereau Dynamics of excited solvated electrons in aqueous solution monitored with femtosecond-time and polarization resolution J. Phys. Chem. A 102 13 1998 2256 2262
6. J.H. Baxendale, E.M. Fielden, and J.P. Keene The pulse radiolysis of aqueous solutions of some inorganic compounds Proc. R. Soc. London, Ser. A 286 1965 320 336
7. B. Bockrath, and L.M. Dorfman Pulse radiolysis studies. XXII. Spectrum and kinetics of the sodium cation-electron pair in tetrahydrofuran solutions J. Phys. Chem. 77 8 1973 1002 1006
8. J. Bonin, I. Lampre, B. Soroushian, and M. Mostafavi First observation of electron paired with divalent and trivalent nonreactive metal cations in water J. Phys. Chem. A 108 33 2004 6818 6820
9. S. Bratos, and J.-C. Leicknam Ultrafast transient absorption spectroscopy of the hydrated electron: a theory Chem. Phys. Lett. 261 1996 117 122
10. S. Bratos, J.-C. Leicknam, D. Borgis, and A. Staib Subpicosecond pump-probe absorption of the hydrated electron: nonlinear response theory and computer simulation Phys. Rev. E 55 6 1997 7217 7227
11. -) in aqueous solution J. Phys. Chem. Ref. Data 17 2 1988 513 886
12. G.V. Buxton, Q.G. Mulazzani, and A.B. Ross Critical review of rate constants for reactions of transients from metal ions and metal complexes in aqueous solution J. Phys. Chem. Ref. Data 24 3 1995 1055 1349
13. Z. Czerwik, M. Wypych, and J. Kroh Pulse radiolysis study of electrons in frozen alkaline solutions J. Radioanal. Nucl. Chem. Art. 101 2 1986 275 283
14. J.W. Fletcher, and W.A. Seddon Alkali metals species in liquid amines, ammonia, and ethers. Formation by pulse radiolysis J. Phys. Chem. 77 26 1975 3055 3064
15. hyd in concentrated aqueous solution J. Am. Chem. Soc. 112 8 1990 2925 2931
16. H. Gelabert, and Y. Gauduel Short-time electron transfer processes in ionic aqueous solution: counterion and H/D isotope effects on electron-atom pairs relaxation J. Phys. Chem. 100 33 1996 13993 14004
17. S. Gordon, J.C. Sullivan, W.A. Mulac, D. Cohen, and K.H. Schmidt Pulse radiolysis of the lanthanide and actinide elements P. Hedvig R. Schiller Proceedings of the Fourth Tihany Symposium on Radiation Chemistry 1977 Akademiai Kiado Budapest 753 760
18. W.C. Gottschall, and E.J. Hart The effect of temperature on the absorption spectrum of the hydrated electron and on its bimolecular recombination reaction J. Phys. Chem. 71 7 1967 2102 2106
19. L.I. Grossweiner, and M.S. Matheson The kinetics of the dihalide ions from the flash photolysis of aqueous alkali halide solutions J. Phys. Chem. 61 8 1957 1089 1095
20. E. Hankiewicz, and D. Schulte-Frohlinde The rate of hydrated electron reaction with neutral and anionic scavengers in concentrated salt solutions J. Phys. Chem. 81 26 1977 2614 2618
21. E.J. Hart, and J.W. Boag Absorption spectrum of the hydrated electron in water and in aqueous solutions J. Am. Chem. Soc. 84 1962 4090 4095
22. E.J. Hart, S. Gordon, and J.K. Thomas Rate constants of hydrated electron reactions with organic compounds J. Phys. Chem. 68 6 1964 1271 1274
23. B. Hickel Effect of ion pairing on the reactivity of solvated electrons in ethyl alcohol J. Phys. Chem. 82 9 1978 1005 1010
24. F.-Y. Jou, and G.R. Freeman Temperature and isotope effects on the shape of the optical absorption spectrum of solvated electron in water J. Phys. Chem. 83 18 1979 2383 2387
25. I.V. Kreitus Effect of solution microstructure on the hydrated electron absorption spectrum J. Phys. Chem. 89 10 1985 1987 1990
26. J. Kroh, and P. Polevoi Formation of electron-cation pairs in the radiolysis of alkaline ice Radiat. Phys. Chem. 11 1978 111 115
27. R. Laenen, and T. Roth Generation of solvated electrons in neat water: new results from femtosecond spectroscopy J. Mol. Struct. 598 2001 347 351
28. D.R. Lide CRC Handbook of Chemistry and Physics 1995 CRC Press Boca Raton, FL
29. F.H. Long, H. Lu, and K.B. Eisenthal Femtosecond studies of the presolvated electron: an excited state of the solvated electron ? Phys Rev. Lett. 64 12 1990 1469 1472
30. V. Ludwig, K. Coutinho, and S. Canuto Sequential classical-quantum description of the absorption spectrum of the hydrated electron Phys. Rev. Lett. B 70 21 2004 4110(1-4)
31. W. Marbach, A.N. Asaad, and P. Krebs Optical absorption of solvated electrons in water and in tetrahydrofuran/water mixtures J. Phys. Chem. A 103 1 1999 28 32
32. - in the temperature range -4 to 390°J. Phys. Chem. 75 18 1971 2798 2805
33. A. Migus, Y. Gauduel, J.L. Martin, and A. Antonetti Excess electrons in liquid water: first evidence of a prehydrated state with femtosecond lifetime Phys. Rev. Lett. 58 15 1987 1559 1562
34. K.A. Motakabbir, J. Schnitker, and P.J. Rossky Transient photophysical hole-burning spectroscopy of the hydrated electron: a quantum dynamical simulation J. Chem. Phys. 90 12 1989 6916 6924
35. E. Neria, A. Nitzan, R.N. Barnett, and U. Landman Quantum dynamical simulations of nonadiabatic processes: solvation dynamics of the hydrated electron Phys. Rev. Lett. 67 8 1991 1011 1014
36. C. Nicolas, A. Boutin, B. Levy, and D. Borgis Molecular simulation of a hydrated electron at different thermodynamic state points J. Chem. Phys. 118 21 2003 9689 9696
37. E. Peled, D. Meisel, and G. Czapski Concentration effects on primary processes in the radiation chemistry of aqueous solutions J. Phys. Chem. 76 25 1972 3677 3882
38. P.J. Rossky, and J. Schnitker The hydrated electron: quantum simulation of structure, spectroscopy, and dynamics J. Phys. Chem. 92 15 1988 4277 4285
39. G.A. Salmon, W.A. Seddon, and J.W. Fletcher Pulse radiolytic formation of solvated electrons, ion-pairs and alkali metal anions in tetrahydrofuran Can. J. Chem. 52 1974 3259 3268
40. J. Schnitker, and P.J. Rossky Quantum simulation study of the hydrated electron J. Chem. Phys. 86 6 1987 3471 3485
41. J. Schnitker, K. Motakabbir, P.J. Rossky, and R. Friesner A priori calculation of the optical absorption spectrum of the hydrated electron Phys. Rev. Lett. 60 5 1988 456 459
42. W.A. Seddon, J.W. Fletcher, F.C. Sopchyshyn, and R. Catterall Solvated electrons and the effect of coordination on the optical absorption spectra of alkali metal cation-electron pairs in ethers Can. J. Chem. 55 4 1977 3356 3363
43. B. Soroushian, I. Lampre, P. Pernot, V. De Waele, S. Pommeret, and M. Mostafavi Formation and geminate recombination of solvated electron upon two-photon ionisation of ethylene glycol Chem. Phys. Lett. 394 2004 313 317
44. + cation with an excess electron in bulk water J. Chem. Phys. 120 11 2004 5261 5268
45. J.K. Thomas, S. Gordon, and E.J. Hart The rates of reaction of the hydrated electron in aqueous inorganic solutions J. Phys. Chem. 68 6 1964 1524 1527
46. A. Walqvist, G. Martyna, and B.J. Berne Behavior of the hydrated electron at different temperatures: structure and absorption spectrum J. Phys. Chem. 92 7 1988 1721 1730
47. R.J. Woods, B. Lesigne, L. Gilles, C. Ferradini, and J. Pucheault Pulse radiolysis of aqueous lithium chloride solutions J. Phys. Chem. 79 24 1975 2700 2704
48. K. Yokoyama, C. Silva, D.H. Son, P.W. Walhout, and P.F. Barbara Detailed investigation of the femtosecond pump-probe spectroscopy of the hydrated electron J. Phys. Chem. A 102 35 1998 6957 6966