Synthesis of ene-allenes via palladium-catalyzed hydride-transfer reaction of propargylic amines under mild conditions

Tetrahedron Letters

Volumn 46, Issue 48, 2005, Pages 8333-8336

  Nakamura, Hiroyuki ^a   Tashiro, Satoshi ^a   Kamakura, Takaya ^a  

^a GAKUSHUIN UNIVERSITY   (Japan)

Author keywords

Allene; Hydride transfer; Palladium catalyst; Propargylic amines

Indexed keywords

ALLENE DERIVATIVE; AMINE; CHLORIDE; FUNCTIONAL GROUP; NITROGEN; PALLADIUM COMPLEX;

ARTICLE; CATALYSIS; CONJUGATION; REACTION ANALYSIS; ROOM TEMPERATURE; SYNTHESIS;

EID: 27644449531     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.tetlet.2005.09.169     Document Type: Article

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24. 3 at 80°C resulted in decomposition of the compound.
25. N-Cyclohexylidenecyclohexanamine 7 was detected by GC-MS analysis at the end of the reactions.