Alkylation of toluene with isopropyl alcohol catalyzed by Ce-exchanged NaX zeolite

Chemical Engineering Journal

Volumn 114, Issue 1-3, 2005, Pages 39-45

  Barman, Sanghamitra ^a   Maity, Sunil K ^a   Pradhan, Narayan C ^a  

^a INDIAN INSTITUTE OF TECHNOLOGY   (India)

Author keywords

Alkylation; Ce exchanged zeolite; Cymene; Kinetics; NaX zeolite; Toluene

Indexed keywords

ALCOHOL FUELS; CATALYST ACTIVITY; CERIUM; ISOMERS; REACTION KINETICS; TOLUENE; ZEOLITES;

CE-EXCHANGED ZEOLITES; CYMENE; KINETICS; NAX ZEOLITE;

ALKYLATION;

ZEOLITE;

EID: 27644433659     PISSN: 13858947     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.cej.2005.08.014     Document Type: Article

References (22)

1. K. Ito Hydrocarb. Process. 52 8 1973 89
2. W.J. Welstead Jr. Kirth-Orthmer Encyclopedia Chem. Technol. 9 1978 544
3. J.M. Derfer, and M.M. Derfer Kirth-Orthmer Encyclopedia Chem. Technol. 22 1978 709
4. B.D. Flockhart, K.Y. Liew, and R.C. Pink Alkylation of toluene with propene using zeolite catalysts J. Catal. 72 2 1981 314 321
5. D. Fraenkel, and M. Levy Comparative study of shape-selective toluene alkylation over HZSM-5 J. Catal. 118 1989 10 21
6. P.A. Parikh, N. Subrahmanyam, Y.S. Bhat, and A.B. Halgeri Toluene isopropylation over zeolite beta and metallosiliates of MFI structure Appl. Catal. A 90 1 1992 1 10
7. P.A. Parikh, N. Subrahmanyam, Y.S. Bhat, and A.B. Halgeri Kinetics of zeolite-catalyzed toluene isopropylation Chem. Eng. J. 54 1994 79 85
8. J. Cejka, G.A. Kapustin, and B. Wichterlova Factor controlling iso-/n- and para-selectivity in the alkylation of toluene with isopropyl alcohol on molecular sieves Appl. Catal. A 108 2 1994 187 204
9. 3 alkylation of toluene: the effect of zeolite structural type J. Catal. 146 2 1994 523 529
10. K.S.N. Reddy, B.S. Rao, and V.P. Shiralkar Selective formation of cymenes over large pore zeolites Appl. Catal. A 121 2 1995 191 201
11. B. Wichterlova, J. Cejka, and N. Zilkova Selective synthesis of cumene and p-cymene over Al and Fe silicates with large and medium pore structures Microporous Mater. 6 1996 405 414
12. 3 catalyst Appl. Catal. A 158 1-2 1997 L1 L6
13. J.A. Rabo, P.E. Pickert, D.N. Stamires, and J.E. Boyle Molecular sieve catalysts in hydrocarbon reactions Chem. Abstr. 55 1961 130652
14. P.B. Venuto, L.A. Hamilton, P.S. Landis, and J.J. Wise Organic reactions catalyzed by crystalline aluminosilicates. I. Alkylation reactions J. Catal. 5 1 1966 81 98
15. J.A. Rabo, C.L. Angell, and V. Schomaker Catalytic and structural properties of rare-earth exchanged forms of type Y zeolite Proceedings of the Fourth International Congress on Catalyst Moscow 1968 96 113
16. F.D. Hunter, and J. Scherzer Cation positions in cerium X zeolites J. Catal. 20 2 1971 246 259
17. C.J. Plank, E.J. Rosinski, and W.P. Hawthorne Acidic crystalline aluminosilicates. New superactive, superselective cracking catalysts Ind. Eng. Chem. Prod. Res. Dev. 3 3 1964 165 169
18. C.L. Wilson, and D.W. Wilson Comprehensive Analytical Chemistry, vol. IC 1971 Elsevier NY
19. J. Cejka, and B. Wichterlova Acid catalyzed synthesis of mono and dialkyl benzenes over zeolites: activities, zeolite topology, and reaction mechanisms Catal. Rev. Sci. Eng. 44 3 2002 375 421
20. D.W. Marquardt An algorithm for the least square estimation of non-linear parameters J. Soc. Ind. Appl. Math. 11 1963 471 481
21. Y.S. Bhat, A.B. Halgeri, and T.S.R. Prasada Rao Kinetics of toluene alkylation with methanol on HZSM-8 zeolite catalyst Ind. Eng. Chem. Res. 28 7 1989 890 894
22. B. Lee, and I. Wang Kinetic analysis of ethylation of toluene on HZSM-5 Ind. Eng. Chem. Prod. Res. Dev. 24 1985 201 205