Multifunctional dithiocarbamates as ligands towards the rational synthesis of polymetallic arrays: An example based on a piperizine-derived dithiocarbamate ligand

European Journal of Inorganic Chemistry

Volumn , Issue 20, 2005, Pages 4027-4030

  Wilton Ely, James D E T ^a   Solanki, Dina ^a   Hogarth, Graeme ^a  

^a UNIVERSITY COLLEGE LONDON   (United Kingdom)

Author keywords

Coordination chemistry; Dithiocarbamates; Multimetallic arrays; Piperazine; Ruthenium complexes

Indexed keywords

CHELATION; LIGANDS; SYNTHESIS (CHEMICAL); TRANSITION METALS;

AS-LIGANDS; CO-ORDINATION CHEMISTRIES; DITHIOCARBAMATE LIGANDS; DITHIOCARBAMATES; EXAMPLE BASED; MULTIMETALLIC ARRAY; PIPERAZINE; POLYMETALLIC; RATIONAL SYNTHESIS; RUTHENIUM COMPLEXES;

RUTHENIUM COMPOUNDS;

EID: 27544504341     PISSN: 14341948     EISSN: None     Source Type: Journal    
DOI: 10.1002/ejic.200500430     Document Type: Article

References (20)

1. G. Hogarth, Prog. Inorg. Chem. 2005, 53, 71-561.
2. A. M. Bond, R. L. Martin, Coord. Chem. Rev. 1984, 54, 23-98.
3. a) P. D. Beer, N. G. Berry, A. R. Cowley, E. J. Hayes, E. C. Oates, W. W. H. Wong, Chem. Commun. 2003, 2408-2409;
4. b) W. W. H. Wong, D. Curiel, A. R. Cowley, P. D. Beer, Dalton Trans. 2005, 359-364;
5. c) P. D. Beer, A. G. Cheetham, M. G. B. Drew, O. D. Fox, E. J. Hayes, T. D. Rolls, Dalton Trans. 2003, 603-611;
6. d) P. D. Beer, N. Berry, M. G. B. Drew, O. D. Fox, M. E. Padilla-Tosta, S. Patell, Chem. Commun. 2001, 199-200;
7. e) M. E. Padilla-Tosta, O. D. Fox, M. G. B. Drew, P. D. Beer, Angew. Chem. Int. Ed. 2001, 40, 4235-4239;
8. f) O. D. Fox, M. G. B. Drew, P. D. Beer, Angew. Chem. Int. Ed. 2000, 39, 135-140.
9. a) T. Trindade, P. O'Brien, J. Mater. Chem. 1996, 6, 343-347;
10. b) M. Green, P. O'Brien, Chem. Commun. 1999, 2235-2241;
11. c) T. Trindade, P. O'Brien, N. L. Pickett, Chem. Mater. 2001, 13, 3843-3858.
12. J. Dunderdale, T. A. Watkins, Chem. Ind. (London) 1956, 174-175 and references cited therein.
13. Some metal complexes of piperazine dithiocarbamates have been reported: a) K. S. Siddiqi, F. R. Zaidi, S. A. A. Zaidi, Synth. React. Inorg. Met.-Org. Chem. 1980, 10, 569-578;
14. b) G. Marcotrigiano, G. C. Pellacani, C. Preti, G. Tosi, Bull. Chem. Soc. Jpn. 1975, 48, 1018-1020;
15. c) A. Hulanicki, L. Shishkova, Chem. Anal. (Warsaw) 1965, 10, 837-845.
16. B. P. Sullivan, T. J. Meyer, Inorg. Chem. 1982, 21, 1037-1040.
17. 2] (86 mg, 0.083 mmol) was added as a dichloromethane solution (10 mL) and the reaction was stirred for 1 h. All solvent was removed and the residue was taken up in a minimum amount of dichloromethane and filtered through diatomaceous earth. Addition of ethanol (30 mL) and reduction of solvent volume by rotary evaporation yielded complex 5 (121 mg, 71%).
18. 2), 4.64, 4.96
19. w = 0.1675. Data reduction and refinement were carried using the SHELXTL PLUS V6.10 program package. The supplementary crystallographic data for this structure, CCDC-266476 contains the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/data_request/cif.
20. I. Kovács, A.-M. Lebuis, A. Shaver, Organometallics 2001, 20, 35-41.