Asymmetric fluoro-alkynyl mercurials: The synthesis and solid state structures of RHgC=CCF3 (R = Ph, Fc)

Organometallics

Volumn 24, Issue 22, 2005, Pages 5487-5490

  Brisdon, Alan K ^a   Crossley, Ian R ^a,b   Pritchard, Robin G ^a  

^a UNIVERSITY OF MANCHESTER   (United Kingdom)

^b AUSTRALIAN NATIONAL UNIVERSITY   (Australia)

Author keywords

[No Author keywords available]

Indexed keywords

COMPLEXATION; CRYSTALLOGRAPHY; MOLECULAR DYNAMICS; ORGANOMETALLICS; SYNTHESIS (CHEMICAL);

INTERMOLECULAR INTERACTIONS; MERCURIALS; MERCUROPHILIC INTERACTION;

MERCURY COMPOUNDS;

EID: 27544468743     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om050366q     Document Type: Article

References (38)

1. 10 interactions see for example: (a) Grohmann, A.; Schmidbaur, H. In Comprehensive Organometallic Chemistry II; Wilkinson, G., Stone, F. G. A., Abel, E. W., Eds.; Pergamon: Oxford, 1995.
2. (b) Schmidbaur, H. Chem. Soc. Rev. 1996, 24, 391.
3. (c) Mingos, D. M. P. J. Chem. Soc., Dalton Trans. 1996, 561.
4. (d) Pyykkö, P. Chem. Rev. 1997, 97, 597.
5. See for example: (a) Omary, M. A.; Kassab, R. M.; Haneline, M. R.; Elbjeurami, O.; Gabbai, F. P. Inorg. Chem. 2003, 42, 2176.
6. (b) Tschinkl, M.; Schier, A.; Riede, J.; Gabbai, F. P. Organometallics 1999, 18, 2040.
7. (c) King, J. B.; Gabbai, F. P. Organometallics 2003, 22, 1275.
8. (d) Haneline, M. R.; Tsunoda, M.; Gabbai, F. P. J. Am. Chem. Soc. 2002, 124, 3737.
9. See for example: Long, N. J.; Williams, C. K. Angew. Chem., Int. Ed. 2003, 42, 2586.
10. (a) Yamazaki, T.; Mizutani, K.; Kitazume, T. J. Org. Chem. 1995, 60, 6046.
11. (b) Katritzky, A. R.; Qi, M.; Wells, A. P. J. Fluorine Chem. 1996, 80, 145.
12. (c) Konno, T.; Chae, J.; Kanda, M.; Nagai, G.; Tamura, K.; Ishihara, T.; Yamanaka, H. Tetrahedron 2003, 59, 7571.
13. (d) Konno, T.; Daitoh, T.; Noiri, A.; Chae, J.; Ishihara, T.; Yamanaka, H. Org. Lett. 2004, 6, 933.
14. (a) Brisdon, A. K.; Crossley, I. R. Chem. Commun. 2002, 2420.
15. (b) Brisdon, A. K.; Crossley, I. R.; Pritchard, R. G.; Sadiq, G.; Warren, J. E. Organometallics 2003, 22, 5534.
16. 1H} NMR spectrum, in the region 145-88 ppm.
17. Schumann, H.; Seuss, T. D.; Just, G.; Wetmann, R.; Hemlin, H.; Görlitz, F. J. Organomet. Chem. 1994, 479, 171.
18. Lide, R. Handbook of Chemistry and Physics, 76th ed.; CRC Press: New York, 1995.
19. Faville, S. J.; Henderson, W.; Mathieson, T. J.; Nicholson, B. K. J. Organomet. Chem. 1999, 580, 363.
20. Deacon, G. B.; Field, L. D.; Forsyth, C. M.; Kay, D. L.; Masters, A. F. Manuscript in preparation.
21. See for instance: (a) Wong, W.-Y.; Choi, K.-H.; Lu, G.-L. Organometallics 2002, 21, 4475.
22. (b) Hartbaum, C.; Roth, G.; Fischer, H. Eur. J. Inorg. Chem. 1999, 191.
23. (c) Hoskins, B. F.; Robson, R.; Sutherland, E. EJ J. Organomet. Chem. 1996, 515, 259.
24. (d) Wong, W.-Y.; Choi, K.-H.; Lu, G.-L.; Shi, J.-X.; Lai, P.-Y. Organometallics 2001, 20, 5448.
25. Weak packing forces have been suggested as the basis for these "small" deviations from linearity, rather than intrinsic electronic effects. But it is questionable whether such packing forces alone would be sufficient to account for the observed (10°) distortion from linearity.
26. (a) Pyykkö, P.; Straka, M. Phys. Chem. Chem. Phys. 2000, 2, 2489.
27. (b) Canty, A. J.; Deacon, G. B. Inorg. Chim. Acta 1980, 45, L225.
28. (c) Caillet, C.; Claverie, P. Acta Crystallogr. Sect. A 1975, 31, 448.
29. (a) Casa, J. S.; Garcia-Tasende, M. S.; Sardo, J. Coord. Chem. Rev. 1999, 195, 283.
30. (b) Flower, K. R.; Howard, V. J.; Naguthney, S.; Pritchard, R. G.; Warren, J. E. Inorg. Chem. 2002, 41, 1907.
31. Batsanov, S. S. J. Chem. Soc., Dalton Trans. 1998, 1541.
32. Haneline, M. R.; Gabbai, F. P. Angew. Chem., Int. Ed. 2004, 43 5471
33. Tsunoda, M.; Gabbai, F. P. J. Am. Chem. Soc. 2000, 122, 8335.
34. Wang, X.; Andrews, L. Inorg. Chem. 2004, 43, 7146.
35. Pickett, N. L.; Just, O.; VanDerveer, D. G.; Rees, W. S., Jr. Acta Crystallogr. Sect. C 2000, 56, 412.
36. Sheldrick, G. M. SHELX-97; Institut fur Anorganische Chenue der Universitat Gottingen: Gottingen, Germany, 1998.
37. Spek, A. L. Acta Crystallogr. Sect. A 1990, 46, C34.
38. ORTEP 3 for Windows: Farrugia, L. J. J. Appl. Crystallogr. 1997, 30, 565.