The effect of the components of the PdCl2/Fe/I2/Py catalytic system on nitrobenzene carbonylation to ethyl N-phenylcarbamate

Central European Journal of Chemistry

Volumn 3, Issue 1, 2005, Pages 28-39

  Skupińska, Jadwiga ^a   Karpińska, Monika ^a   Ołówek, Maria ^a   Kasprzycka Guttman, Teresa ^a  

^a UNIVERSITY OF WARSAW   (Poland)

Author keywords

Nitrobenzene carbonylation; Palladium catalysts; Urethanes

Indexed keywords

EID: 27444439830     PISSN: 16443624     EISSN: 16443624     Source Type: Journal    
DOI: 10.2478/bf02476235     Document Type: Article

References (19)

1. S. Cenini, M. Pizzotti and C. Crotti: "Metal catalysed deoxygenation reactions by carbon monoxide of nitroso and nitro compounds", Aspects of Homogeneous Catalysis, Vol. 6, (1988), pp. 97-198.
2. F. Ragaini and S. Cenini: "Mechanistic studies of palladium- catalysed carbonylation reaction of nitro compounds to isocyanates, carbamates and ureas", J. Mol. Catal. A: Chem., Vol. 109, (1996), pp. 1-25.
3. F. Paul: "Catalytic synthesis of isocyanates or carbamates from nitroaromatics using Group VIII transition metal catalysts", Coord. Chem. Rev., Vol. 203, (2000), pp. 269-323.
4. 2", J. Mol. Catal. A: Chem., Vol. 142, (1999), pp. 169-181.
5. T. Mizuno and H. Alper: "Reductive carbonylation of nitrobenzenes catalyzed by a new binuclear rhodium complex", J. Mol. Catal. A: Chem., Vol. 121, (1997), pp. 119-122.
6. 12/chloride catalyzed carbonylation reactions of nitroarenes to carbamates and ureas; the role of the alkylammonium cation", J. Mol. Catal. A: Chem., Vol. 161, (2000), pp. 31-38.
7. S.J. Skoog and W.L. Gladfelter: "Activation of nitroarenes in the homogenous catalytic carbonylation of nitroaromatics via an oxygen-atom-transfer mechanism induced by inner-sphere electron transfer", J. Amer. Chem. Soc., Vol. 119, (1997), pp. 11049-11060.
8. S.B. Halligudi, N.H. Khan, R.I. Kureshy, E. Suresh and K. Venkatsubramanian: "Synthesis, structural characterization and catalytic carbonylation of nitrobenzene to phenylurethane using palladium(II) 1,10-phenanthroline diacetato complex", J. Mol. Catal. A: Chem., Vol. 124, (1997), pp. 147-154.
9. P. Wehman, H.M.A. van Donge, A. Hagos, P.C.J. Kamer and P.W.N.M. van Leeuwen: "Influence of various P/N and P/P ligands on the palladium-catalysed reductive carbonylation of nitrobenzene", J. Organomet. Chem., Vol. 535, (1997), pp. 183-193.
10. R. Santi, A.M. Romano, F. Panella and C. Santini: "Palladium and silver reductive catalyzed carbonylation of nitrobenzene to methyl N-phenylcarbamate", J. Mol. Catal. A: Chem., Vol. 127, (1997), pp. 95-99.
11. J. Mei, Y. Yang, Y. Xue and S. Lu: "Selective formation of unsymmetric ureas by selenium-catalyzed oxidative-reductive carbonylation with CO", J. Mol. Catal. A: Chem., Vol. 191, (2003), pp. 135-139.
12. V. Macho, M. Kralik, J. Hudec and J. Cingelova: "One stage preparation of Schiff's bases from nitroarenes, aldehydes and carbon monoxide at presence of water", J. Mol. Catal. A: Chem., Vol. 209, (2004), pp. 69-73.
13. V. Macho, M. Kralik and F. Halmo: "New catalytic system of N,N'-diphenylurea synthesis from nitrobenzene, carbon monoxide and water or aniline", J. Mol. Catal. A: Chem., Vol. 109, (1996), pp. 119-125.
14. 2 systems", J. Mol. Catal. A: Chem., Vol. 161, (2000), pp. 69-73.
15. 2/Py Catalyst System", Appl. Catal., Vol. 267, (2004), pp. 59-66.
16. 2/Py catalytic system", submitted for publication.
17. 2/Py catalytic systems", React. Kinet. Catal. Lett., Vol. 82, (2004), pp. 311-316.
18. Gmelins Handbuch der Anorganischen Chemie, Vol. 59 Fe, Springer-Verlag, New York, 1979, p. 337.
19. 1-C) carbamoyl-palladium complexes. New efficient palladium-catalyzed routes to carbamoyl chlorides: Key intermediates to isocyanates, carbamic esters, and ureas", Organometallics, Vol. 19, (2000), pp. 3879-3889.