Hydrolysis and Condensation Reactions of Transition Metal Alkoxides: Calorimetric Study and Evaluation of the Extent of Reaction

European Journal of Inorganic Chemistry

Volumn , Issue 8, 1998, Pages 1115-1127

  Blanchard, Juliette ^a   In, Martin ^a   Schaudel, Barbara ^a   Sanchez, Clément ^a  

^a UNIVERSITÉ PIERRE ET MARIE CURIE   (France)

Author keywords

17O NMR spectroscopy; Polymers, inorganic; Sol gel process; Transition metal alkoxides

Indexed keywords

CALORIMETRY; CONDENSATION; CONDENSATION REACTIONS; HYDROLYSIS; SILICON COMPOUNDS; SOL-GEL PROCESS; SOL-GELS; TITANIUM COMPOUNDS; TRANSITION METALS; ZIRCONIUM COMPOUNDS;

17O-NMR SPECTROSCOPY; HYDROLYSIS AND CONDENSATION; NMR-SPECTROSCOPY; OH-GROUPS; SOL STATE; TITANIUM ALKOXIDES; TITANIUM AND ZIRCONIUMS; TRANSITION METAL ALKOXIDES; WATER ADDITION; ZIRCONIUM ALKOXIDES;

NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY;

EID: 2742607108     PISSN: 14341948     EISSN: None     Source Type: Journal    
DOI: 10.1002/(SICI)1099-0682(199808)1998:8<1115::AID-EJIC1115>3.0.CO;2-N     Document Type: Review

References (32)

1. C. J. Brinker; G. W. Scherrer, Sol-Gel Science, the Physics and Chemistry of Sol-Gel Processing, Academic Press, San Diego, 1990.
2. J. Livage, M. Henry, C. Sanchez, Prog. in Solid-State Chem. 1988, 18, 259-341.
3. C. Sanchez, F. Ribot, New J. Chem. 1994, 18, 1007-1047.
4. C. J. Brinker, G. W. Scherrer, Sol-Gel Science, the Physics and Chemistry of Sol-Gel Processing, Academic Press, San Diego, 1990, 109-108; 136-137; 150-152.
5. D. C. Bradley, R. C. Mehrotra, D. P. Gaur, Metal Alkoxides, Academic Press, London-New-York-San Francisco, 1978.
6. L. C. Klein, Ed., Sol-Gel Technology, Noyes Publications, New Jersey. 1988.
7. L. W. Kelts, N. J. Effinger, S. M. Melpolder, J. Non-Cryst. Solids 1989, 83, 354-374.
8. B. E. Yoldas, J. Mater Sci. 1986, 21, 1086-1092.
9. C. Sanchez, J. Livage, M. Henry, F. Babonneau, J. Non-Cryst. Solids 1988, 100, 65-76.
10. B. K. Coltrain, C. Sanchez, D. W. Schaefer, G. L Wilkes, Eds., Better Ceramics Through Chemistry VII: Organic!Inorganic Hybrid Materials, Materials Research Society, Pittsburg, 1996, 435.
11. F. Ribot, P. Toledano, C. Sanchez, Chem Mater. 1991, 3, 759-764.
12. D. M. Antonelli, J. Y. Ying, Angew. Chem. Int. Ed. Engl. 1995, 34, 2014-2017.
13. D. M. Antonelli, J. Y. Ying, Chem Mater. 1996, 8, 874-881.
14. U. Schubert, Private communication.
15. M. Kallala, C. Sanchez, B. Cabane, Phys. Rev. E 1993, 48, 3692-3704.
16. [19a] J Blanchard, Thèse de l'Université Pierre et Marie Curie, (Chimie Inorganique), 1997. [19b] J. Blanchard, C. Sanchez, forthcoming papers.
17. [19a] J Blanchard, Thèse de l'Université Pierre et Marie Curie, (Chimie Inorganique), 1997. [19b] J. Blanchard, C. Sanchez, forthcoming papers.
18. J. R. Bartlett, J. L. Woolfrey, Chemical Processing of Advanced Materials (Eds.: L. L. Hench, J. K. West), Wiley, New York, 1992, 247-256.
19. F. Babonneau, Better Ceramics Through Chemistry VI (Eds.: A. K. Cheetham, C. J. Brinker, M. L. Mecartney, C. Sanchez), Materials Research Society, Pittsburg, 1994, 346, 949-960.
20. S. Chabarek, A. E. Martell, Organic Sequestering Agents, Wiley, New York, 1959.
21. J. V. Silverton, J. L. Hoard, Inorg. Chem. 1963, 2, 243-249.
22. J. D. Cox, G. Pilcher, Thermochemistry of Organic and Inorganic Compounds, Academic Press, London, 1965.
23. H. Weingarten, J. R. Van Wazer, J. Am. Chem. Soc. 1965, 87, 724-730.
24. R. L. Martin, G. Winter, J. Chem. Soc. 1961, 2947-2952.
25. M. Kallala, C. Sanchez, Private communication: XANES experiments have been performed at the titanium K-edge on hydrolyzed titanium butoxide under acidic conditions and at low hydrolytic ratios H=I and 2. The XANES prc-pcak exhibits a low intensity triplet centered at about 4968 eV, which is characteristic of a titanium atom in an octahedral oxygen ligand field.
26. L. Armelao, F. O. Ribot, C. Sanchez, Better Ceramics Through Chemistry VII: Organicl Inorganic Hybrid Materials (Eds.: B. K. Coltrain, C. Sanchez, D. W. Schaefer, G. L. Wilkes), Materials Research Society, Pittsburg, 1996, 435, 387-393.
27. T. Hiemtra, W. H. Van Riemsdjik, G. H. Bolt, J. Coll. Interf. Sci. 1989, 133, 91, 104.
28. R. Aelion, A. Loebel, F. Eirich, J. Am Chem Soc 1950, 72, 5705.
29. J. Blanchard, S. Barboux-Doeuff, J. Maquet, C. Sanchez, New J. Chem. 1995, 19, 929-941.
30. V. W. Day, T. A. Eberspacher, W. G. Klemperer, C. W. Park, F. S. Rosenberg, J. Am. Chem. Soc. 1991, 113, 8190-8192.
31. T. J. Bastow, S. N. Stuart, Chem. Phys. 1990, 143, 459-467.
32. A. Leaustic, F. Babonneau, J. Livage, Chem. Mater. 1989, I-2, 240-247.