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Volumn 38, Issue 21, 2005, Pages 8611-8613

Experimental reconsideration of radical entry into latex particles

Author keywords

[No Author keywords available]

Indexed keywords

CHEMICAL REACTIONS; CHROMATOGRAPHY; EMULSIONS; OLIGOMERS;

EID: 27344442437     PISSN: 00249297     EISSN: None     Source Type: Journal    
DOI: 10.1021/ma0510385     Document Type: Article
Times cited : (16)

References (23)
  • 7
    • 27344438729 scopus 로고    scopus 로고
    • note
    • All seeded polymerizations were carried out at in the absence of a free monomer phase at 70°C until complete conversion. For KPS the polystyrene seed latex was swollen with a solution of BDB in styrene. The polymerizations with PEGA200 and AIBN were carried out with poly(methyl methacrylate) seed latexes swollen with PhEDB solution in styrene. To start the polymerizations, aqueous and methanolic solutions of KPS or PEGA200 and AIBN were added after equilibration of the reaction mixture.
  • 9
    • 27344455883 scopus 로고    scopus 로고
    • note
    • -4 mol of BDB in either 0.74 g of styrene, or 0.77 g of methyl methacrylate, or 0.71 g of ethylbenzene was placed on top of the dispersion inside the reactor. Before depositing the solution the dispersion was heated to 70°C, and the absorption baseline was measured after thermal equilibration and before adding the initiator (43 mg of KPS or 46 mg of VA-086 dissolved in 2 g of water).


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.