Solvent extraction of copper from nitrate media with chelating LIX-reagents: Comparative equilibrium study

Solvent Extraction and Ion Exchange

Volumn 23, Issue 5, 2005, Pages 695-711

  Lazarova, Zdravka ^a   Lazarova, Madlena ^b  

^a ARC SEIBERSDORF RESEARCH GMBH   (Austria)

^b INSTITUTE OF CHEMICAL ENGINEERING   (Bulgaria)

Author keywords

Copper; Extraction equilibrium; LIX reagents; Solvent extraction; Water purification

Indexed keywords

AGENTS; CHELATION; COPPER; HYDROCARBONS; MASS TRANSFER; NITRATES; POSITIVE IONS; PURIFICATION; THERMODYNAMICS;

EXTRACTION EQUILIBRIUM; LIQUID HYDROCARBON UNDECANE; LIX REAGENTS; WATER PURIFICATION;

SOLVENT EXTRACTION;

COPPER; NITRATE; PURIFICATION; SOLVENT EXTRACTION; WATER TREATMENT;

EID: 27144514380     PISSN: 07366299     EISSN: 15322262     Source Type: Journal    
DOI: 10.1080/07366290500230701     Document Type: Article

References (39)

1. Whewell, R.J.; Hanson, C. Metal extraction with hydroxyoximes. In Ion Exchange and Solvent Extraction; Marinsky, J., Marcus, Y., Eds.; Marcel Dekker: New York, 1981; Vol. 8, 1-93.
2. Szymanowski, J. Hydroxyoximes and Copper Hydrometallurgy; CRC Press: Boca Raton, Fl, 1993.
3. Yang, J. Development of copper extraction technology in China. Kuangye: (Beijing, China), 1994, 3 (2), 51-3, 41.
4. Szymanowski, J.; Sobczynska, A. Industrial processes for copper extraction. Part I. extractants for copper recovery from aqueous solutions polish. J. Appl. Chem. 1996, 39 (3), 357-373.
5. Davenport, W.G. Copper extraction from the 60's into the 21st century, Proceedings of the COPPER 99-COBRE 99 international conference, 4th, Phoenix, oct. 10-13, 1999; Eltringham, G.A., Piret, Norbert L., Sahoo, Mahi, Eds.; Minerals, Metals & Materials Society: Warrendale, PA1; 55-79.
6. Davenport, W.G.L.; King, M.; Schlesinger, M.; Biswas, A.K. Extractive Metallurgy of Copper, 4th ed.; Elsevier Science: July 2002.
7. Yoshizuka, K.; Arita, H.; Baba, Y.; Inoue, K. Equilibria of solvent extraction of copper (II) with 5-DodecylSalicylaldoxime. Hydrometallurgy 1990, 23, 247-261.
8. Espinola, A.; Oliveira, L.F.M.; Ayres, F.L. Flow Electrolysis for Decontaminating Plate Industries Waste Water, Extr.and Proc. for Treat. and Minim. of Waste, 1994, TMS, San Francisco, USA.
9. Tani, K.; Ohta, T.; Nii, S.; Takahashi, K. Copper removal from diluent aqueous solution by extraction with counter-current multi-stage column. J. Chem. Eng. Jpn. 1998, 31 (3), 398-406.
10. The Chemistry of Metals Recovery using LIX® Reagents. MCT Redbook. Solvent Extraction using Cognis Corporation Liquid Ion Exchanger Reagents. Eds. Mining Chemical Technology Division, 1998.
11. Mendes, F.D.; Martins, A.H. Sulfuric acid leaching of Igarape Bahia gold-copper ore for copper extraction - an ore pretreatment for gold recovery by cyanidation. Minerals & Metallurgical Processing 2002, 19 (3), 165-168.
12. Russell, J.H.; Rickel, R.L. Modelling copper extraction from acidic solutions using P5100, PT5050, and LIX 84. Solv. Extr.Ion Exch. 1990, 8 (6), 855-73.
13. Szymanowski, J.; Olszanowski, A.; Cierpiszewski, R. Effect of hydrophobicity and interfacial activity of 2-hydroxy-5-alkylbenzophenone oximes upon the rate of copper extraction from acidic sulfate solution. Sep.Sci.Technol. 1993, 28 (13-14), 2211-27.
14. Lazarova, Z.; Sapundzhiev, T.; Boyadzhiev, L. Kinetics and mechanism of copper transfer by hydroxy-oximes in three-phase liquid systems. Sep.Sci.Technol. 1992, 27 (4), 493-508.
15. Lazarova, Z.; L. Boyadziev, L. Kinetic aspects of copper(II) transport across liquid membrane containing LIX-860 as a carrier. J. Membr. Sci. 1993, 78, 239-245.
16. Ali, A.I.; Daoud, J.A.; Aly, H.F. Recovery of copper from sulphate medium by LIX-84 in kerosene. J. Chem. Tech. Biotechnol. 1996, 67, 137-142.
17. Hu, S.B.; Wiencek, J.M. Copper-LIX 84 extraction equilibrium. Sep.Sci.Technol. 2000, 35 (4), 469-481.
18. Yang, X.J.; Fane, A.G. Facilitated transport of copper in bulk liquid membranes containing LIX 984N. Sep.Sci.Technol. 1999, 34 (9), 1873-1890.
19. Jakubiak, A.; Borowiak-Resterna, A.; Szymanowski, J. Copper extraction from chloride media. Hydrometallurgy, Proceedings of 3rd Intern. Conf., Kunming, China, Nov. 3-5, 1998Intern. Acad. Publ.: Beijing, Peop. Rep. China, 1998.
20. Cierpiszewski, R. Kinetics of Copper Extraction from Chloride Solutions with Model and Commercial Dialkyl Pyridine-Dicarboxylates. Solv. Extr. Ion Exch. 2000, 18 (1), 93-108.
21. Borowiak-Resterna, A.; Szymanowski, J. Copper extraction from chloride solutions with mixtures of solvating and chelating reagents. Solv. Extr. Ion Exch. 2000, 18 (1), 77-91.
22. Kyuchoukov, G.; Zhivkova, S. Options for the separation of copper(II) and zinc(II) from chloride solutions by kelex100®. Solv. Extr. and Ion Exch. 2000, 18 (2), 239-305.
23. Bogacki, M.; Zhivkova, S.; Kyuchoukov, G.; Szymanowski, J. Modeling of copper (II) and zink (II) extraction from chloride media with kelex100®. Ind. Eng. Chem. Res. 2000, 39, 740-745.
24. Kyuchoukov, G.; Zhivkova, S.; Borowiak - Resterna, A.; Szymanowski, J. Separation of copper(II) and zinc(II) from chloride solutions with alkyl -8 -hydroxyquinoline in various stages of extraction: stripping process. Ind. Eng. Chem. Res. 2000, 39, 3896-3900.
25. Cierpiszewski, R.; Szymanowski, J. Copper extraction from chloride solution by solvating and chelating extractants. Solv.Extr.Ion Exch. 2001, 19 (3), 441-456.
26. Szymanowski, J.; Kyuchoukov, G. Extraction of copper(II) from chloride systems with individual and mixed extractants. Canadian Metallurgical Quarterly, 2002, 41 (4), 399-408.
27. Alguacil, F.J.; Cobo, A. Solvent extraction with LIX 973N for the selective separation of copper and nickel. J.Chem.Technol. Biotechnol. 1999, 74, 467-471.
28. Alguacil, F.J. Mechanistic study of active transport of copper(II) from ammoniacal/ammonium carbonate medium using LIX 974N as a carrier across a liquid membrane. Hydrometallurgy 2001, 61, 177-183.
29. Alguacil, F.J.; M.Alonso, M. Recovery of copper from ammoniacal/ammonium sulphate medium by LIX54. J.Chem.Technol. & Biotechnol. 1999, 74, 1171-1175.
30. Kyuchoukov, G.; Bogacki, M.B.; Szymanowski, J. Copper extraction from ammoniacal solutions with commercial chelating extractants and their mixtures, Solvent Extraction for the 21st Century, proceedings of ISEC '99, Barcelona, Spain, July 11-16, 1999; Cox, M., Hidalgo, M., Valiente, M., Eds.; 2001, Meeting Date, 1999, 2, 1193-1196.
31. Kyuchoukov, G.; Bogacki, M.B.; Szymanowski, J. Copper extraction from ammoniacal solutions with LIX 84 and LIX 54. Ind. & Eng. Chem. Res. 1998, 37 (10), 4084-4089.
32. Szymanowski, J.; Sobczynska, A. Industrial processes for copper extraction Part III. Recovery of copper and separation from nickel and cobalt. Polish J. of Appl. Chem. 1998, 41 (3), 123-143.
33. Lazarova, Z. Study on the kinetics of copper/LIX54 system using a rotating diffusion cell. Solv. Extr.Ion Exch. 1995, 13 (3), 525-540.
34. Bart, H.J.; Marr, R.; Bauer, A.; Schein, R.; Marageter, E. Copper extraction in nitrate media. Hydrometallurgy 1990, 23, 281-295.
35. Alguacil, F.J.; Cobo, A.; Alonso, M. Copper separation from nitrate/ nitric acid media using acorga M5640 extractant. Part I: Solvent Extraction Study. Chem. Eng. J. 2002, 85, 259-263.
36. Zapatero, M.J.; Elizade, M.P.; Castresana, J.M. Copper distribution equilibria with 5,8-diethyl-7-hydroxydodecan-6-oxime dissolved in toluene. Solv Extr.Ion Exch. 1987, 5, 83.
37. Tanaka, A Modelling of solvent extraction equilibria of Cu(II) from nitric and hydrochloric acid solutions with β-hydroxyoxime. Hydrometallurgy 1990, 24, 317-331.
38. Schwarzenbach, G.; Flaschka, H. Die komplexometrische titration. Ferdinand Enke Verlag: Stuttgart. 1965; 203.
39. Rice, N.M.; Medved, M. The extraction of nickel from ammoniacal media and its separation from copper, cobalt and zinc using hydroxyme extractants. Hydrometallurgy 1978, 3, 35-54.