A series of hydrido(vinyl)iridium(III) complexes that are thermodynamically more stable than their olefin iridium(I) isomers

Organometallics

Volumn 24, Issue 21, 2005, Pages 5127-5139

  Dirnberger, Thomas ^a   Werner, Helmut ^a  

^a UNIVERSITY OF WÜRZBURG   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

ACRYLICS; ACTIVATION ANALYSIS; IRIDIUM COMPOUNDS; ISOMERS; KETONES; MIXTURES; ORGANIC ACIDS; REACTION KINETICS; THERMODYNAMICS;

INTRAMOLECULAR ACTIVATION; IRIDIUM COMPLEXES; MICHAEL SYSTEMS; VINYL KETONES;

COMPLEXATION;

EID: 27144512334     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om0505099     Document Type: Article

References (58)

1. Reviews: (a) Bergman, R. G. Science 1984, 223, 902-908.
2. (b) Jones, W. D.; Feher, F. J. Acc. Chem. Res. 1989, 22, 91-100.
3. (c) Perutz, R. N. Chem. Soc. Rev. 1993, 22, 361-369.
4. (d) Arndtsen, B. A.; Bergman, R. G.; Mobley, T. A.; Peterson, T. H. Acc. Chem. Res. 1995, 28, 154-162.
5. (e) Shilov, A. E.; Shul'pin, G. B. Chem. Rev. 1997, 97, 2879-2932.
6. (f) Guari, Y.; Sabo-Etienne, S.; Chaudret, B. Eur. J. Inorg. Chem. 1999, 1047-1055.
7. (g) Jia, C.; Kitamura, T.; Fujiwara, Y. Acc. Chem. Res. 2001, 34, 633-639.
8. (h) Crabtree, R. H. Dalton Trans. 2001, 2437-2450.
9. (a) Stoutland, P. O.; Bergman, R. G. J. Am. Chem. Soc. 1985, 107, 4581-4582.
10. (b) Stoutland, P. O.; Bergman, R. G. J. Am. Chem. Soc. 1988, 110, 5732-5744.
11. Silvestre, J.; Calhorda, M. J.; Hoffmann, R.; Stoutland, P. O.; Bergman, R. G. Organometallics 1986, 5, 1841-1851.
12. (a) Haddleton, D. M.; Perutz, R. N. J. Chem. Soc., Chem. Commun. 1986, 1734-1736.
13. (b) Bell, T. W.; Haddleton, D. M.; McCamley, A.; Partridge, M. G.; Perutz, R. N.; Willner, H. J. Am. Chem. Soc. 1990, 112, 9212-9226.
14. (a) Baker, M. V.; Field, L. D. J. Am. Chem. Soc. 1986, 108, 7433-7434.
15. (b) Bell, T. W.; Brough, S.-A.; Partridge, M. G.; Perutz, R. N.; Rooney, A. D. Organometallics 1993, 12, 2933-2941.
16. (c) Bianchini, C.; Barbaro, P.; Meli, A.; Peruzzini, M.; Vacca, A.; Vizza, F. Organometallics 1993, 12, 2505-2514.
17. (d) Siegbahn, P. E.; Blomberg, M. R. A.; Svenson, M. J. Am. Chem. Soc. 1993, 115, 1952-1958.
18. (a) Ghosh, C. K.; Hoyano, J. K.; Kreutz, R.; Graham, W. A. G. J. Am. Chem. Soc. 1989, 111, 5480-5481.
19. (b) Fernández, M. J.; Rodriguez, M. J.; Oro, L. A.; Lahoz, F. J. J. Chem. Soc., Dalton Trans. 1989, 2073-2076.
20. (c) Gutiérrez, E.; Monge, A.; Nicasio, M. C.; Poveda, M. L.; Carmona, E. J. Am. Chem. Soc. 1994, 116, 791-792.
21. (d) Alvarado, Y.; Daff, P. J.; Pérez, P. J.; Poveda, M. L.; Sánchez-Delgado, R.; Carmona, E. Organometallics 1996, 15, 2192-2194.
22. (e) Alvarado, Y.; Boutry, O.; Gutiérrez, E.; Monge, A.; Nicasio, M. C.; Poveda, M. L.; Pérez, P. J.; Ruíz, C.; Bianchini, C.; Carmona, E. Chem. Eur. J. 1997, 3, 860-873.
23. (f) Gutiérrez-Puebla, E.; Monge, A.; Nicasio, M. C.; Pérez, P. J.; Poveda, M. L.; Rey, L.; Ruíz, C.; Carmona, E. Inorg. Chem. 1998, 37, 4538-4546.
24. (a) Schulz, M.; Werner, H. Organometallics 1992, 11, 2790-2795.
25. (b) Papenfuhs, B.; Mahr, N.; Werner, H. Organometallics 1993, 12, 4244-4246.
26. Werner, H.; Papenfuhs, B.; Steinert, P. Z. Anorg. Allg. Chem. 2001, 627, 1807-1814.
27. Werner, H.; Dirnberger, T.; Schulz, M. Angew. Chem. 1988, 100, 993-994;
28. Angew. Chem., Int. Ed. Engl. 1988, 27, 948-950.
29. (a) Schulz, M. Diploma Thesis, Universität Würzburg, 1988.
30. (b) Dziallas, M. Ph.D. Thesis, Universität Würzburg, 1988.
31. Nesmeyanov, A. N.; Rybinskaya, M. I.; Rybin, L. V.; Kaganovich, V. S.; Petrovskii, P. V. J. Organomet. Chem. 1971, 31, 257-267.
32. Castarlenas, R.; Esteruelas, M. A.; Martín, M.; Oro, L. A. J. Organomet. Chem. 1998, 564, 241-247.
33. Dirnberger, T.; Werner, H. Chem. Ber. 1992, 125, 2007-2014.
34. Werner, H.; Wolf, J.; Höhn, A. J. Organomet. Chem. 1985, 287, 395-407.
35. (a) Schrauzer, G. N. J. Am. Chem. Soc. 1959, 81, 5310-5312.
36. (b) Fritz, H. P.; Schrauzer, G. N. Chem. Ber. 1961, 94, 650-659.
37. (c) Weiss, E.; Stark, K.; Lancaster, J. E.; Murdoch, H. D. Helv. Chim. Acta 1963, 46, 288-297.
38. (d) Tate, D. P.; Buss, A. A.; Augl, J. M.; Ross, B. L.; Grasselli, J. G.; Ritchey, W. M.; Knoll, F. J. Inorg. Chem. 1965, 4, 1323-1328.
39. (e) Kawaguchi, S.; Ogura, T. Inorg. Chem. 1966, 5, 844-846.
40. Bianchini, C.; Meli, A.; Peruzzini, M.; Ramirez, J. A.; Vacca, A.; Vizza, F.; Zanobini, F. Organometallics 1989, 8, 337-345.
41. Schulz, M. Ph.D. Thesis, Universität Würzburg, 1991.
42. (a) Robinson, S. D.; Uttley, M. F. J. Chem. Soc., Dalton Trans. 1973, 1912-1920.
43. (b) Deacon, G. B.; Phillips, R. J. Coord. Chem. Rev. 1980, 33, 227-250.
44. (c) Oldham, C. In Comprehensive Coordination Chemistry; Wilkinson, G., Gillard, R. D., McCleverty, J. A., Eds.; Pergamon: New York, 1987; Vol. 2, pp 435-459.
45. Komiya, S.; Ito, T.; Cowie, M.; Yamamoto, A.; Ibers, J. A. J. Am. Chem. Soc. 1976, 98, 3874-3884.
46. Clerici, M. G.; di Gioacchino, S.; Maspero, F.; Perrotti, E.; Zanobi, A. J. Organomet. Chem. 1975, 84, 379-388.
47. Goldman, A. S.; Halpern, J. J. Organomet. Chem. 1990, 382, 237-253.
48. van Baar, J. F.; Klerks, J. M.; Overbosch, P.; Stufkens, D. J.; Vrieze, K. J. Organomet Chem. 1976, 112, 95-103.
49. Alaimo, P. J.; Arndtsen, B. A.; Bergman, R. G. J. Am. Chem. Soc. 1997, 119, 5269-5270.
50. Leigh, G. J.; Richards, R. L. In Comprehensive Organometallic Chemistry; Wilkinson, G., Stone, F. G. A., Abel, E. W., Eds.; Pergamon: New York, 1982; Vol. 5, Chapter 36.2.
51. van der Ent, A.; Onderdelinden, A. L. Inorg. Synth. 1973, 14, 92-95.
52. Collman, J. P.; Kang, J. W. J. Am. Chem. Soc. 1967, 89, 844-851.
53. Fild, M.; Stelzer, O.; Schmutzler, R. Inorg. Synth. 1973, 14, 4-9.
54. (a) Strohmeier, W.; Onoda, T. Z. Naturforsch., B 1968, 23, 1377-1379.
55. (b) Werner, H.; Höhn, A. Z. Naturforsch., B 1984, 39, 1505-1509.
56. Hietkamp, S.; Stufkens, D. J.; Vrieze, K. J. Organomet. Chem. 1978, 152, 347-357.
57. Hesse, M.; Meier, H.; Zeeh, B. Spektroskopische Methoden in der organischen Chemie, 2nd ed.; Thieme Verlag: Stuttgart, New York, 1984.
58. Mann, B. E.; Masters, C.; Shaw, B. L.; Stainbank, R. E. J. Chem. Soc., Chem. Commun. 1971, 1103-1104.