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All values denoted as free space in this work refer to molecular fluorescence emission in a microcavity of the same type as that reported in the Experimental Section, but without silver mirrors.
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It should be remarked that single-molecule fluorescence was also observed for higher interference orders up to m = 3. Since the observation volume increases with the cavity length L, the ratio of single molecule to background fluorescence signal decreases for a given dye concentration and spatial addressing of single molecules becomes impossible for larger orders of interference.
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35
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27144506339
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note
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0 of PI molecules solved in dichloromethane as well as embedded in the cured polymer was measured by applying standard methods using Rhodamin 6 G dye as a reference.
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27144469649
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note
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2 = 0.91 at λ = 532 nm calculated for the thickness of our silver films measured by AFM.
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27144543327
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2 = 0.9 at λ = 532 nm calculated for the thickness of our silver films measured by AFM.
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SpE could also be modelled assuming parallel dipole orientation (θ = 0°) and emitter displacements of ± 30 nm from the z = 0 plane in the center of the microcavity.
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