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27144523118
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note
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The UV-VIS spectra shown in figure l have been deconvoluted. As a result, the spectrum of a sample with vanadium loading of 7.2 wt% can be described by three bands with absorption maxima at 250, 292 and 362 nm, respectively, A more detailed description is given elsewhere [19].
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43
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27144476056
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note
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Vanadia was deposited at the colder parts of the reactor during catalytic runs at lower temperatures. This is probably due to methanol-mediated volatilization of surface vanadium oxide. A similar behavior has been reported previously [11].
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0037137451
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45
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27144450465
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note
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2O.
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46
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0039539764
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47
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27144477625
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note
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Spectra b (c)and d (e)were obtained after methanol oxidation within 200-240°C (400-460°C)for ∼14 h (∼10 h). Starting at 200°C (400°C), the temperature was kept constant for 200 min and subsequently increased by 30°C (30°C). It was kept constant for 200 min and then increased by 10°C (30°C). After the final temperature had been reached, it was kept constant for the residual duration of the experiment.
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