Sulfur-bridged linkage of [Ni(thiolato)2(amine) 2]-type complexes with linear gold(I) ions assisted by aurophilic interaction

Chemistry Letters

Volumn 34, Issue 8, 2005, Pages 1146-1147

  Konno, Takumi ^a   Usami, Masafumi ^a   Toyota, Atsushi ^a   Hirotsu, Masakazu ^b   Kawamoto, Tatsuya ^a  

^a OSAKA UNIVERSITY   (Japan)

^b Osaka Prefecture University   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 26844567144     PISSN: 03667022     EISSN: None     Source Type: Journal    
DOI: 10.1246/cl.2005.1146     Document Type: Article

References (29)

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21. -1)]: 19.88 (2.28), 37.5 (4.1 sh), 42.48 (4.43). This complex is sparingly soluble in water.
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26. 4: C, 17.64; H, 2.59; N, 5.14%. Found: C, 17.47; H, 2.50; N, 5.19%.
27. w) = 0.050 (0.130) for 6757 reflections with >2.0σ(I).
28. 4+ are very similar to those found in the mononuclear [Ni(L)]. Q. Fernando and P. J. Wheatley, Inorg. Chem., 4, 1726 (1965).
29. 2 proton signals at 20°C. The signals appear as four distinct signals (δ 2.94, 3.26, 3.58, and 3.95) at -50°C, implying the conformational fixation of N,S-chelate rings. See Supporting Information.