Preparation and reactions of highly functionalized bis-arylzinc reagents using a Li(acac)-catalyzed iodine-zinc exchange

Synthesis

Volumn , Issue 15, 2005, Pages 2625-2629

  Kneisel, Florian F ^a   Leuser, Helena ^a   Knochel, Paul ^a  

^a UNIVERSITY OF MUNICH   (Germany)

Author keywords

Cross coupling; Functionalized zinc reagents; Halogen metal exchange; Nucleophilic catalysis

Indexed keywords

ALDEHYDES; CATALYSTS; IODINE; KETONES; LITHIUM; REACTION KINETICS;

CROSS-COUPLING; FUNCTIONALIZED ZINC REAGENTS; HALOGEN-METAL EXCHANGE; NUCLEOPHILIC CATALYSIS;

ZINC;

FUNCTIONAL GROUP; IODINE DERIVATIVE; LITHIUM; POLYCYCLIC AROMATIC HYDROCARBON DERIVATIVE; ZINC DERIVATIVE;

ARTICLE; CATALYSIS; CHEMICAL STRUCTURE; CROSS COUPLING REACTION; METALLATION; REACTION ANALYSIS; REPRODUCIBILITY; ROOM TEMPERATURE;

EID: 26844550306     PISSN: 00397881     EISSN: None     Source Type: Journal    
DOI: 10.1055/s-2005-872097     Document Type: Article

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40. 2O (1.3 equiv) in pyridine in the presence of DMAP (0.1 equiv).