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Volumn 109, Issue 39, 2005, Pages 8785-8793

Enolate structure and electron affinity

Author keywords

[No Author keywords available]

Indexed keywords

CONTINUOUS WAVES (CW); DIPOLE-BOUND STATES; ELECTRON AFFINITIES; ION CYCLOTRON RESONANCE;

EID: 26844508845     PISSN: 10895639     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp050024y     Document Type: Article
Times cited : (8)

References (26)
  • 13
    • 26844573434 scopus 로고    scopus 로고
    • note
    • N2 reaction (eq 3) must involve an unprecedented intramolecular rearrangement. It is possible that the wrong isomer was synthesized. This hypothesis, however, is not consistent with the NMR. Nevertheless, the 2-methylcyclohexanone enolate anion and the 6-methylcyclohexanone enolate anion have very similar principal moments of inertia. Therefore, if the photodetachment spectrum were indeed measured for the 2-methylcyclohexanone enolate anion instead of the 6-methylcyclohexanone enolate anion, the arguments that have been made regarding the shortened lifetimes of the dipole-bound state would remain the same.
  • 24
    • 26844438742 scopus 로고    scopus 로고
    • note
    • Previously obtained results from our research group show a dipolebound state at 817 nm. Although that spectrum does not match up perfectly with the data presented here, the presence of the resonance at 817 nm gives us additional confidence that we are correct in our assignment of the electron affinity. The absence of a dipole-bound state resonance in the spectrum reported here may be due to the low signal-to-noise ratio in this experiment.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.