메뉴 건너뛰기




Volumn 127, Issue 41, 2005, Pages 14200-14201

Total synthesis of (±)-garsubellin A

Author keywords

[No Author keywords available]

Indexed keywords

ACETYLCHOLINE; GARSUBELLIN A; PLANT EXTRACT; UNCLASSIFIED DRUG; TERPENE;

EID: 26844495771     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja055301t     Document Type: Article
Times cited : (134)

References (20)
  • 14
    • 26844443449 scopus 로고    scopus 로고
    • note
    • Attempted alkylation of the enolate failed on substrates in which the prenyl group had been dihydroxylated.
  • 15
    • 26844463895 scopus 로고    scopus 로고
    • note
    • Using AD-mix-β retarded the reaction without changing the selectivity. Prenyl group-selective dihydroxylation was not possible after cleavage of the TIPS group.
  • 16
    • 26844525847 scopus 로고    scopus 로고
    • note
    • (a) Ethylene carbonate was added to prevent undesired carbonate hydrolysis.
  • 17
    • 26844551644 scopus 로고    scopus 로고
    • note
    • (b) Although the regioselectivity of this enolization/O-allylation was not rigorously determined, either of the two possible products (5 or C-27 allyl ether) can stereoselectively give 4 via Claisen rearrangement.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.