Infrared spectral hole burning of 1:1 hydrogen-bonded complexes in solution

Laser Chemistry

Volumn 19, Issue 1-4, 1999, Pages 1-10

  Arrivo, S M ^a,b   Kleiman, V D ^c,d   Grubbs, W T ^e   Dougherty, T P ^a,b   Heilweil, E J ^f  

^a BEAVER COLLEGE   (United States)

^b MERCK RESEARCH LABORATORIES   (United States)

^c UNIVERSITY OF CALIFORNIA   (United States)

^d NAVAL RESEARCH LABORATORY   (United States)

^e STETSON UNIVERSITY   (United States)

^f NATIONAL INSTITUTE OF STANDARDS AND TECHNOLOGY   (United States)

Author keywords

Broadband; Complexes; Hole burning; Hydrogen bond; Infrared; Inhomogeneous

Indexed keywords

EID: 26844471448     PISSN: 02786273     EISSN: None     Source Type: Journal    
DOI: 10.1155/1999/80323     Document Type: Article

References (22)

1. Graener, H. and Laubereau, A. (1991). J. Phys. Chem., 95, 3448;
2. Graener, H. (1991). J. Phys. Chem., 95, 3450;
3. Graener, H., Losch, T. and Laubereau, A. (1990). J. Chem. Phys., 93, 5365.
4. Bonn, M., Brugmans, M. J. P., Kleyn, A. W., van Santen, R. A. and Bakker, H. J. (1996). J. Chem. Phys., 105, 3431;
5. Bonn, M., Bakker, H. J., Kleyn, A. W. and van Santen, R. A. (1996). J. Phys. Chem., 100, 15301.
6. Graener, H., Ye, T. Q. and Laubereau, A. (1989). J. Chem. Phys., 91, 1043;
7. Graener, H., Ye, T. Q. and Laubereau, A. ibid., (1989). J. chem. Phys., 90, 3413;
8. Laenen, R. and Rauscher, C. (1997). J. Chem. Phys., 106, xxx;
9. Laenen, R., Rauscher, C. and Laubereau, A. (1997). J. Phys. Chem., A101, xxx.
10. Bonn, M., Brugmans, M. J. P., Bakker, H. J., Kleyn, A. W. and van Santen, R. A. (1996). Stud. Surf. Sci. Cat., 97, 567;
11. Fujino, T., Fuauki, M., Kashitani, M., Onada, K., Kubota, J., Kondo, J. N., Wada, A., Domen, K., Hirose, C., Wakabayashi, F., Ishia, M., Goto, F. and Kano, S. S. (1996). J. Chem. Phys., 105, 279.
12. Heilweil, E. (1986). Chem. Phys. Letters, Vol. 129, 48.
13. Heilweil, E. J., Casassa, M. P., Cavanagh, R. R. and Stephenson, J. C. (1985). Chem. Phys. Lett., Vol. 117, 185.
14. Heilweil, E. J., Casassa, M. P., Cavanagh, R. R. and Stephenson, J. C. (1989). Ann. Rev. Phys. Chemistry, Vol. 40, 143.
15. Grubbs, W. T., Dougherty, T. P. and Heilweil, E. J. (1995). J. Phys. Chem., 99, 10716.
16. Grubbs, W. T., Arrivo, S. M. and Heilweil, E. J., unpublished results.
17. 8 and we have shown that THF forms homogeneously broadened complexes with triethylsilanol and pyrrole. Transient kinetics and spectra indicate homogeneous broadening to be the dominant mechanism since most of the OH (v = 0-1) absorption band bleaches after IR excitation.
18. Arrivo, S. M. and Heilweil, E. J. (1996). J. Phys. Chem., 100, 11975.
19. Arrivo, S. M., Kleiman, V. D., Dougherty, T. P. and Heilweil, E. J. (1997). Optics Letters, 22, 1488.
20. 2) = 2.1 for the Lorentzian fit.
21. Grubbs, W. T., Arrivo, S. M. and Heilweil, E. J., unpublished results.
22. -1 from self-associated NMA. This absorption profile has Gaussian character and a spectral hole was produced after IR-pumping at the peak of this absorption band.