Kinetics of the chemical oxidation of polysulfide anions in aqueous solution

Water Research

Volumn 39, Issue 17, 2005, Pages 4093-4100

  Kleinjan, Wilfred E ^a   De Keizer, Arie ^a   Janssen, Albert J H ^a  

^a WAGENINGEN UNIVERSITY   (Netherlands)

Author keywords

Elemental sulfur hydrolysis; Hydrogen sulfide; Kinetics; Oxidation; Polysulfide

Indexed keywords

HYDROGEN SULFIDE; HYDROLYSIS; IONIC STRENGTH; NEGATIVE IONS; OXIDATION; PH EFFECTS; POLYSULFIDES; RATE CONSTANTS; SOLUTIONS; THERMAL EFFECTS;

BUFFER SOLUTIONS; CHEMICAL STABILITY; ELEMENTAL SULFUR HYDROLYSIS; POLYSULFIDE ANIONS;

REACTION KINETICS;

INORGANIC COMPOUND; PHOSPHATE; SULFIDE; SULFUR;

AQUEOUS SOLUTION; KINETICS; OXIDATION;

AQUEOUS SOLUTION; ARTICLE; COLLOID; HYDROLYSIS; IONIC STRENGTH; MOLECULAR STABILITY; OXIDATION KINETICS; OXYGEN CONCENTRATION; OXYGEN CONSUMPTION; PH; PRIORITY JOURNAL; REACTION TIME; TEMPERATURE;

EID: 26444589081     PISSN: 00431354     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.watres.2005.08.006     Document Type: Article

References (30)

1. H. Banciu, D.Y. Sorokin, R. Kleerebezem, G. Muyzer, E.A. Galinski, and J.G. Kuenen Growth kinetics of haloalkaliphilic, sulfur-oxidizing bacterium Thioalkalivibrio versutus strain ALJ 15 in continuous culture Extremophiles 8 3 2004 185 192
2. C. Buisman, P. IJspeert, A. Janssen, and G. Lettinga Kinetics of chemical and biological sulfide oxidation in aqueous solutions Water Res. 24 5 1990 667 671
3. C.J.N. Buisman, B.G. Geraats, P. IJspeert, and G. Lettinga Optimization of sulphur production in a biotechnological sulphide-removing reactor Biotechnol. Bioeng. 35 1 1990 50 56
4. Buisman, C.J.N., Janssen, A.J.H., van Bodegraven, R.J., 2000. Method for desulphurization of gases. International patent PCT/NL00/00155.
5. J.E. Burgess, S.A. Parsons, and R.M. Stuetz Developments in odour control and waste gas treatment biotechnology: a review Biotechnol. Adv. 19 1 2001 35 63
6. 2 Environ. Sci. Technol. 6 6 1972 529 537
7. 2S removal from gas streams. The Shell-Paques/Thiopaq gas desulfurization process. In: Proceedings of the Laurance Reid Gas Conditioning Conference. University of Oklahoma, Norman, OK.
8. L.G. Danielsson, X.S. Chai, M. Behm, and L. Renberg UV characterization of sulphide-polysulphide solutions and its application for process monitoring in the electrochemical production of polysulphides J. Pulp Paper Sci. 22 6 1996 J187 J191
9. H. Fischer, G. Schulz-Ekloff, and D. Wöhrle Oxidation of aqueous sulfide solutions by dioxygen. Part I: autoxidation reaction Chem. Eng. Technol. 20 7 1997 462 468
10. C.A. Hammond The Dow Stretford chemical recovery process Environ. Prog. 5 1 1986 1 4
11. A.J.H. Janssen, R. Sleyster, C. van der Kaa, A. Jochemsen, J. Bontsema, and G. Lettinga Biological sulphide oxidation in a fed-batch reactor Biotechnol. Bioeng. 47 3 1995 327 333
12. A.J.H. Janssen, S. Meijer, J. Bontsema, and G. Lettinga Application of the redox potential for controlling a sulfide oxidizing bioreactor Biotechnol. Bioeng. 60 2 1998 147 155
13. A.J.H. Janssen, G. Lettinga, and A. de Keizer Removal of hydrogen sulphide from wastewater and waste gases by biological conversion to elemental sulphur. Colloidal and interfacial aspects of biologically produced sulphur particles Colloids Surf. A - Physicochem. Eng. Aspects 151 1-2 1999 389 397
14. W.E. Kleinjan, A. de Keizer, and A.J.H. Janssen Biologically produced sulfur Top. Curr. Chem. 230 2003 167 188
15. W.E. Kleinjan, A. de Keizer, and A.J.H. Janssen Equilibrium of the reaction between dissolved sodium sulfide and biologically produced sulfur Colloids Surf. B - Biointerfaces 43 3-4 2005 228 237
16. W.E. Kleinjan, A. de Keizer, and A.J.H. Janssen Kinetics of the reaction between dissolved sodium sulfide and biologically produced sulfur Ind. Eng. Chem. Res. 44 2 2005 309 317
17. S. Licht, and J. Davis Disproportionation of aqueous sulfur and sulfide: kinetics of polysulfide decomposition J. Phys. Chem. B 101 14 1997 2540 2545
18. 2S in seawater as a function of temperature, pH, and ionic strength Environ. Sci. Technol. 21 5 1987 439 443
19. A.H. Nielsen, J. Vollertsen, and T. Hvitved-Jacobsen Determination of kinetics and stoichiometry of chemical sulfide oxidation in wastewater of sewer networks Environ. Sci. Technol. 37 17 2003 3853 3858
20. Pasiuk-Bronikowska, W., Ziajka, J., Bronikowski, T., 1992. In: Brimblecombe, P. (Transl. Ed.), Autoxidation of Sulphur Compounds. Ellis Horwood Limited, Chichester.
21. W.A. Pryor Mechanisms of Sulfur Reactions 1962 McGraw-Hill Book Company Inc. New York
22. A.B. Roy, and P.A. Trudinger The Biochemistry of Inorganic Compounds of Sulphur 1970 Cambridge University Press Cambridge, London
23. R. Steudel Mechanism for the formation of elemental sulfur from aqueous sulfide in chemical and microbiological desulfurization processes Ind. Eng. Chem. Res. 35 4 1996 1417 1423
24. R. Steudel The chemical sulfur cycle P. Lens L. Hulshoff Pol Environmental Technologies to Treat Sulfur Pollution. Principles and Engineering 2000 IWA Publishing London 1 31
25. R. Steudel Aqueous sulfur sols Top. Curr. Chem. 230 2003 153 166
26. ·- Top. Curr. Chem. 231 2003 127 152
27. R. Steudel, G. Holdt, and R. Nagorka On the autoxidation of aqueous sodium polysulfide Z. Naturforsch. B 41 12 1986 1519 1522
28. A. Teder Spectrophotometric determination of polysulphide excess sulfur in aqeuous solutions Svensk Papperst. 70 6 1967 197 200
29. A. Teder The equilibrium between elementary sulfur and aqueous polysulfide ions Acta Chem. Scand. 25 5 1971 1722 1728
30. H.G. Trüper, and H.G. Schlegel Sulphur metabolism in Thiorhodaceae I: quantitative measurements on growing cells of Chromatium okenii Antonie van Leeuwenhoek 30 3 1964 225 238