The effects of alpha-radiolysis on UO2 dissolution determined from batch experiments with 238Pu-doped UO2

Journal of Nuclear Materials

Volumn 346, Issue 1, 2005, Pages 5-15

  Stroes Gascoyne, S ^a   Garisto, F ^b   Betteridge, J S ^a  

^a ATOMIC ENERGY OF CANADA LIMITED   (Canada)

^b ONTARIO POWER GENERATION   (Canada)

Author keywords

[No Author keywords available]

Indexed keywords

DISSOLUTION; DOPING (ADDITIVES); HYDROGEN PEROXIDE; PLUTONIUM; RADIOISOTOPES; URANIUM DIOXIDE;

ALPHA-RADIOLYSIS; DISSOLUTION RATES; DOSE RATE; REACTION RATES;

RADIOLYSIS;

EID: 26444538482     PISSN: 00223115     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.jnucmat.2005.04.069     Document Type: Conference Paper

References (26)

1. D.W. Shoesmith, Fuel corrosion processes under waste disposal conditions. Atomic Energy of Canada Limited Report, AECL-12034, 1999.
2. S. Sunder, D.W. Shoesmith, and N.H. Miller J. Nucl. Mater. 244 1997 66
3. 2 under strongly oxidizing conditions. Ontario Power Generation, Nuclear Waste Management Division Report 06819-REP-01200-10006-R00, 1999. Toronto, Ontario.
4. 2 fuel dissolution as observed in electrochemical experiments. Ontario Power Generation, Nuclear Waste Management Division Report 06819-REP-01200-10047-R00, 2000. Toronto, Ontario.
5. 2. Ontario Power Generation, Nuclear Waste Management Division Report 06819-REP-01200-10050-R00, 2001. Toronto, Ontario.
6. 2. Ontario Power Generation, Nuclear Waste Management Division Report 06819-REP-01300- 10030-R00, 2002a. Toronto, Ontario.
7. S. Stroes-Gascoyne, F. King, J.S. Betteridge, and F. Garisto Radiochim. Acta 90 2002 603
8. V.V. Rondinella, Hj. Matzke, J. Cobos, and T. Wiss Mater. Res. Soc. Symp. Proc. 556 1999 447
9. V.V. Rondinella, Hj. Matzke, J. Cobos, and T. Wiss Radiochim. Acta 88 2000 527
10. D.W. Shoesmith, F. King, A mixed-potential model for the prediction of the effects of alpha-radiolysis, precipitation and redox processes on the dissolution of used nuclear fuel. Ontario Hydro, Nuclear Waste Management Division Report 06819-REP-01200-0038-R00, 1998.
11. L.H. Johnson, D.M. LeNeveu, F. King, D.W. Shoesmith, M. Kolar, D.W. Oscarson, S.Sunder, C. Onofrei, J.L. Crosthwaite, The disposal of Canada's nuclear fuel waste: A study of postclosure safety of in-room emplacement of used CANDU fuel in copper containers in permeable plutonic rock, vol. 2: vault model. Atomic Energy of Canada Limited Report, AECL-11494-2, COG-96-552-2, 1996.
12. 2 using the mixed-potential model of fuel dissolution (MPM version 1.1). Ontario Power Generation, Nuclear Waste Management Division Report 06819-REP-01200-10014, 1999. Toronto, Ontario.
13. F. King, M. Kolar, Analysis of the effect of cladding on the oxidative dissolution of used nuclear fuel using the mixed potential model of fuel dissolution (MPM Version 1.2). Ontario Power Generation, Nuclear Waste Management Division Report 06819-REP-01200-10022, 2000. Toronto, Ontario.
14. F. King, M. Kolar, Mixed potential model simulations of the effects of porous film formation on the dissolution of used fuel (MPM Version 1.3). Ontario Power Generation, Nuclear Waste Management Division Report 06819-REP-01300- 10019-R00, 2001a. Toronto, Ontario.
15. F. King, M. Kolar, An improved C-steel corrosion model for the mixed-potential model for used fuel dissolution (MPM Version 1.4). Ontario Power Generation, Nuclear Waste Management Division Report 06819-REP-01300-10027-R00, 2001b. Toronto, Ontario.
16. F. King, M. Kolar, Validation of the mixed-potential model for used fuel dissolution against experimental data. Ontario Power Generation, Nuclear Waste Management Division Report 06819-REP-01200-10077-R00, 2002a. Toronto, Ontario.
17. eff in the mixed-potential model for used fuel dissolution. Ontario Power Generation, Nuclear Waste Management Division Report 06819-REP-01300-10044-R00, 2002b. Toronto, Ontario.
18. 2 dissolution. Ontario Power Generation, Nuclear Waste Management Division Report 06819-REP-01200-10037-R00, 2000. Toronto, Ontario.
19. S. Sunder, N.H. Miller, and D.W. Shoesmith Corros. Sci. 46 2004 1095
20. S. Stroes-Gascoyne, and J.S. Betteridge Mater. Res. Soc. Symp. Proc. 824 2004 175
21. J. Bruno, I. Casas, and I. Puigdomenech Geochim. Cosmochim. Acta 55 1991 647
22. F. Garisto Annu. Nucl. Energy 16 1989 33
23. L.H. Johnson, P.A. Smith, The interaction of radiolysis products and canister corrosion products and the implications for spent fuel dissolution and radionuclide transport in a repository for spent fuel. NAGRA Technical Report NTB 00-04, Switzerland, 2000.
24. 2 dissolution, in: Global '99, International Conference on Future Nuclear Systems Jackson Hole, WY, 1999.
25. V.V. Rondinella, J. Cobos, H. Matzke, T. Wiss, P. Carbol, and D. Solatie Mater. Res. Soc. Symp. Proc. 663 2001 391
26. 2. Ontario Power Generation, Nuclear Waste Management Division Report 06819-REP-01200-10110-R00, 2003. Toronto, Ontario.