LP/LIF study of the formation and consumption of mercury (I) chloride: Kinetics of mercury chlorination

Chemosphere

Volumn 61, Issue 5, 2005, Pages 685-692

  Taylor, Philip H ^a   Mallipeddi, Rajesh ^a   Yamada, Takahiro ^a  

^a UNIVERSITY OF DAYTON RESEARCH INSTITUTE   (United States)

Author keywords

Chlorination; Combustion; Kinetics; Mercury

Indexed keywords

CHLORINATION; COMBUSTION; FLUORESCENCE; HYDROCHLORIC ACID; MERCURY (METAL); PHOTOLYSIS;

KINETICS; LASER INDUCED FLUORESCENCE (LIF); LASER PHOTOLYSIS; MERCURY CHLORIDE;

MERCURY COMPOUNDS;

CARBON TETRACHLORIDE; HYDROCHLORIC ACID; MERCURY CHLORIDE;

CHLORINATION;

AIR POLLUTION CONTROL; ARTICLE; CHLORINATION; COMBUSTION; FLUORESCENCE; GAS; KINETICS; LASER; MATHEMATICAL COMPUTING; MATHEMATICAL MODEL; PHOTOLYSIS; PREDICTION; TEMPERATURE DEPENDENCE;

EID: 26444519828     PISSN: 00456535     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.chemosphere.2005.03.089     Document Type: Article

References (17)

1. P.A. Ariya, A. Khalizov, and A. Gidas Reactions of gaseous mercury with atomic and molecular halogens: kinetics, product studies, and atmospheric implications J. Phys. Chem. A 106 2002 7310 7320
2. T.D. Brown, D.N. Smith, W.J. O'Dowd, and R.A. Hargis Control of mercury emissions from coal-fired power plants: a preliminary cost assessment and the next steps for accurately assessing control costs Fuel Process. Technol. 65-66 2000 311 341
3. DeMore, W.B., Sander, S.P., Golden, D.M., Hampson, R.F., Kurylo, M.J., Howard, C.J., Ravishankara, A.R., Kolb, C.E., Molina, M.J., 1997. Chemical Kinetics and Photochemical Data for use in Stratospheric Modeling: Evaluation Number 12, JPL Publication 97-4, Jet Propulsion Laboratory.
4. Electric Power Research Institute, 2000. An Assessment of Mercury Emissions from US. Coal-Fired Power Plants; EPRI Report TR-1000608; EPRI: Palo Alto, CA.
5. D.G. Horne, R. Gosavi, and O.P. Strausz Reactions of metal atoms. I. The combination of mercury and chlorine atoms and the dimerization of HgCl J. Chem. Phys. 48 1968 4758 4764
6. A.F. Khalizov, B. Viswanathan, P. Larregaray, and P.A. Ariya A theoretical study on the reactions of Hg with halogens: atmospheric implications J. Phys. Chem. A 107 2003 6360 6365
7. Kilgroe, J.D., Srivastava, R.K., Sedman, C.B., Thorneloe, S.A., 2000. Control of Mercury Emissions from Coal-Fired Electric Utility Boilers; Technical Memorandum; US Environmental Protection Agency, NRMRL/APPCD: Research Triangle Park, NC, October.
8. R. Meij The fate of mercury in coal-fired power plants and the influence of wet flue-gas desulphurization Water, Air, Soil Pollut. 56 1991 21 33
9. NIST Chemical Kinetics Database, 2000. Standard Reference Database 17, Version 7.10 (Web Version), Release 1.2: http://kinetics.nist.gov/index.php.
10. 2O in predicting oxidation of coal-derived systems Environ. Sci. Technol. 35 2001 3701 3706
11. Sarofim, A.F., Senior, C.L., Helble, J.J., 1998. Emissions of mercury, trace elements, and fine particles from stationary combustion sources. In: Proceedings of Conference on Air Quality: Mercury, Trace Elements, and Particulate Matter, McLean, VA.
12. C.L. Senior, A.F. Sarofim, T. Zeng, J.J. Helble, and R. Mamani-Paco Gas-phase transformations of mercury in coal-fired power plants Fuel Process. Technol. 63 2000 197 213
13. R.N. Sliger, J.C. Kramlich, and N.M. Marinov Towards the development of a chemical kinetic model for the homogeneous oxidation of mercury by chlorine species Fuel Process. Technol. 65-66 2000 423 438
14. US Environmental Protection Agency, 1990. The Clean Air Act Amendments of 1990, Section 114; Government Printing Office: Washington, DC.
15. N.C. Widmer, J. West, and J.A. Cole Practical limitation of mercury speciation in simulated municipal waste incinerator flue gas Combust. Sci. Technol. 134 1998 315 326
16. T. Yamada, M. Siraj, P.H. Taylor, J. Peng, X. Hu, and P. Marshall Rate coefficients and mechanistic analysis for reaction of OH with vinyl chloride between 293 and 73 K J. Phys. Chem. A 105 2001 9436 9444
17. 6 from 298 to 832 K: rate coefficients and mechanism J. Chem. Phys. 119 2003 10600 10606