Formation of coordinated nitrosamines by reaction of K[IrCl5NO] with primary amines

Organometallics

Volumn 24, Issue 20, 2005, Pages 4707-4709

  Doctorovich, Fabio ^a   Di Salvo, Florencia ^a   Escola, Natalia ^a   Trápani, Cecilia ^a   Shimon, Linda ^b  

^a Instituto de Quimica Fisica de los Materiales Medio Ambiente y Energia   (Argentina)

^b WEIZMANN INSTITUTE OF SCIENCE   (Israel)

Author keywords

[No Author keywords available]

Indexed keywords

COMPLEXATION; COORDINATION REACTIONS; CRYSTAL STRUCTURE; ORGANOMETALLICS; POTASSIUM COMPOUNDS; X RAY DIFFRACTION ANALYSIS;

COORDINATED NITROSAMINES; LIGANDS; METAL CENTER; P-TOLUIDINE;

NITROSAMINES;

EID: 26444484866     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om050457n     Document Type: Article

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16. -1.
17. 1/2 = -0.33 V vs ferrocene in butyronitrile. Sieger, M.; Sarkar, B.; Zališ, S.; Fiedler, J.; Escola, N.; Doctorovich, F.; Olabe, J.; Kaim, W. Dalton Trans. 2004, 1797-1800.
18. 5(NO)] in 0.25 mL of acetonitrile. In both cases the orange product which precipitated immediately was separated from the solution by centrifugation (in both cases the counterions are the ammonium salt of the corresponding amine and a potassium ion; 98% yield in the case of 1 and 80% yield in the case of 2). The tetraphenylphosphonium salts were obtained by adding a saturated aqueous solution of the crude product to an acetonitrile saturated solution of tetraphenylphosphonium bromide. After slow evaporation of the supernatant, the orange crystals so produced were separated by centrifugation and carefully dried. For more details see the Supporting Information.
19. w = 0.0652 (observed data with I > 2σ(I)).
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22. 3