Contribution to the Chemistry in Clouds: A Laboratory Study on the Kinetics and Mechanism of the Oxidation of Sulfur and Nitrogen Compounds by Hydroperoxides in Aqueous Phase

Dynamics and Chemistry of Hydrometeors

Volumn , Issue , 2006, Pages 468-527

  Wannowius, Klaus J ^a  

^a DARMSTADT UNIVERSITY OF TECHNOLOGY   (Germany)

Author keywords

Atmospheric relevance; Chemistry; Chemistry in clouds; Dynamics; General reaction pattern; Hydrometeors; Hydroperoxides in aqueous phase; Kinetics; Laboratory experiments; Mechanism; Oxidation of nitrogen compounds; Oxidation of sulfur compounds

Indexed keywords

ATMOSPHERIC CHEMISTRY; CHEMISTRY; DYNAMICS; ENZYME KINETICS; MECHANISMS; NITROGEN COMPOUNDS; OXIDATION; REACTION KINETICS;

AQUEOUS PHASE; HYDROMETEORS; HYDROPEROXIDES; KINETICS AND MECHANISM; LABORATORY EXPERIMENTS; LABORATORY STUDIES; REACTION PATTERNS;

SULFUR COMPOUNDS;

EID: 26444478469     PISSN: None     EISSN: None     Source Type: Book    
DOI: 10.1002/9783527609802.ch26     Document Type: Chapter

References (67)

1. Adewuyi, Y. G., and G.R. Carmichael, 1986: Kinetics of oxidation of dimethyl sulfide by hydrogen peroxide in acidic and alkaline medium. Environ. Sci. Technol. 20, 1017-1022.
2. Amels, P., H. Elias, and K.J. Wannowius, 1997: Kinetics and mechanism of the oxidation of dimethyl sulfide by hydroperoxides in aqueous medium: A study on the potential contribution of liquid phase oxidation of dimethyl sulfide in the atmosphere. J. Chem. Soc., Faraday Trans. 93, 2537-2544.
3. 2): A novel synthesis and some chemical and spectroscopic properties. Inorg. Chem. 34, 787-791.
4. Bai, C., M. Huang, Z. Shen, J. Shen, and R. Ma, 1992: Kinetics of hydrogen peroxide-sulfur(IV) reaction in atmospheric precipitation. J. Environ. Sci. (China) 5, 351-366.
5. Barth, S., 1991: Zur Kinetik der S(IV)-Oxidation durch Peroxoacetylnitrat (= PAN) und Peroxocarbonsäuren in wäßriger Lösung. Diplomarbeit, Technische Hochschule Darmstadt.
6. Bell, R. P., F. R. S. Evans, and P. G. Evans, 1966: Kinetics of the dehydration of methylene glycol in aqueous solution. Proc. Royal Soc. London Ser. A 291, 297-323.
7. Benton, D.J., and P.J. Moore, 1970: Kinetics and mechanism of the formation and decay of peroxynitrous acid in perchloric acid solutions. J. Chem. Soc. A 3178-3182.
8. Betterton, E.A., 1992: Oxidation of alkylsulfides by aqueous peroxymonosulfate. Environ. Sci. Technol. 26, 527-532.
9. Bhattacharyya, R., and R. Veerarghavan, 1977: Int. J. Kinetics 9, 629.
10. Blackadder, D. A. and C. Hinshelwood, 1958: The kinetics of the decomposition of the addition compounds formed by sodium bisulphite and a series of aldehydes and ketones. Part I. J. Chem. Soc. 2720-2734.
11. Boyce, S.D., and M.R. Hoffmann, 1984: Kinetics and mechanism of the formation of hydroxymethanesulfonic acid at low pH. J. Phys. Chem. 88, 4740-4746.
12. Brandt, C., and R. van Eldik, 1995: Transition metal-catalyzed oxidation of sulfur(IV) oxides. Atmospheric-relevant processes and mechanisms. Chem. Rev. 95, 119-190.
13. Breytenbach, L., W. van Pareen, J.J. Pienaar, and R. van Eldik, 1994: The influence of organic acids and metal ions on the kinetics of the oxidation of sulfur(IV) by hydrogen peroxide. Atmos. Environ. 28, 2451-2459.
14. Brice, K. A., and S. A. Penkett, 1978: Report No. AERE-R 9260 of Atomic Energy Research Est., Harwell, England.
15. 3- by HSO-f. Inorg. Chem. 32, 565-571.
16. D'Ans, J., and W. Frey, 1914: Z. Anorg. Chem. 84, 145.
17. D'Ans, J., and W. Friederich, 1911: Z. Anorg. Chem. 73, 325.
18. 2O in aqueous solution. J. Phys. Chem. 90, 3213-3217.
19. Drexler, C., 1993: Kinetik und Mechanismus der S(IV) Oxidation mit Peroxosäuren des Stickstoffs und salpetriger Säure. Dissertation, Technische Hochschule Darmstadt.
20. Drexler, C., H. Elias, B. Fecher, and K.J. Wannowius, 1991: Kinetic investigation of sulfur(IV) oxidation by peroxo-compounds ROOH in aqueous solution. Fresenius J. Anal. Chem., 340, 605-615.
21. Drexler, C., H. Elias, B. Fecher, and K.J. Wannowius, 1992: Kinetics and mechanism of sulfur(IV) oxidation by hydrogen peroxide in aqueous phase: The non-linear parts of the pH-profile. Ber. Bunsenges. Phys. Chem. 96, 481-485.
22. Edwards, J. O., and J. J. Mueller, 1962: Rate of oxidation of nitrite ion by peroxides. Inorg. Chem. 1, 696-699.
23. Elias, H., and K.J. Wannowius, 1994: Sonderforschungsbereich 233: "Dynamik und Chemie der Hydrometeore" Arbeitsbericht für den Zeitraum 1991-1993, 481-504.
24. Elias, H., U. Götz, and K.J. Wannowius, 1994: Kinetics and mechanism of the oxidation of sulfur(IV) by peroxomonosulfuric acid anion. Atmos. Environ. 28, 439-448.
25. Fecher, B., 1995: Kinetik und Mechanismus der S(IV) Oxidation mit Wasserstoffperoxid und organischen Peroxiden in wässriger Lösung. Dissertation Technische Hochschule Darmstadt.
26. Ghiron, A. F., and R. C. Thompson, 1989: Comparative kinetic study of oxygen atom transfer reactions of oxohydroxodiperoxomolybdenum(VI) and oxo(oxalato)diperoxo-molybdenum(VI) in aqueous solution. Inorg. Chem. 28, 3647-3650.
27. Götz, U., 1996: Kinetische Untersuchung von Reaktionen der Peroxosalpetersäure in wässriger Lösung. Dissertation Technische Hochschule Darmstadt.
28. Golding, R. M., 1960: Ultraviolet absorption studies of the bisulphite-pyrosulphite equilibrium. J. Am. Chem. Soc. 82, 3711-3716.
29. Goldman, A., F.J. Murcray, R.D. Blatherwick, and J.J. Kosters, 1989: New spectral features of stratospheric trace gases identified from high-resolution infrared balloon-borne and laboratory spectra. J. Geophys. Res. 94, 14945-14955.
30. Goldstein, S., and G. Czapski, 1996: Formation of peroxynitrite from the nitrosation of hydrogen peroxide by an oxygenated nitric oxide solution. Inorg. Chem. 35, 59355940.
31. 2NOOH): A pulse radiolysis study. Inorg. Chem. 36, 4156-4162.
32. Halfpenny, E., and P. L. Robinson, 1952: Pernitrous acid. The reaction between hydrogen peroxide and nitrous acid, and the properties of an intermediate product. J. Chem. Soc., 929-938.
33. Halperin, J., and H. Taube, 1952: The transfer of oxygen atoms in oxidation-reduction reactions. IV. The reaction of hydrogen peroxide with sulfite and thiosulfate, and of oxygen, manganese dioxide and of permanganate with sulfate. J. Am. Chem. Soc. 74, 380-382.
34. Hoffmann, M. R., and J. O. Edwards, 1975: Kinetics of the oxidation of sulfite by hydrogen peroxide in acidic solution. J. Phys. Chem. 79, 2096-2098.
35. -. Inorg. Chem. 25, 2414-2417.
36. Hoß, H., H. Elias, and K.J. Wannowius, 1991: Sulfur(IV) oxidation by hydrogen peroxide in aqueous suspensions of silica, alumina, titania, and zeolite. Atmos. Environ. 25A, 1715-1717.
37. Hughes, M. N., and H. G. Nicklin, 1968: The chemistry of pernitrites. Part I. Kinetics of decomposition of pernitrous acid. J. Chem. Soc. (A), 450-452.
38. Jacob, D. J., 1986: Chemistry of OH in remote clouds and its role in the production of formic acid and peroxymonosulfate. J. Geophys. Res. D 91, 9807-9826.
39. Kenley, R. A., P. L. Trevor, and B. Y. Lan, 1981: Preparation and thermal decomposition of pernitric acid (HOONO2) in aqueous media. J. Am. Chem. Soc. 103, 2203-2206.
40. Kielland, J., 1937: Individual Activity Coefficients of Ions in Aqueous Solution. J. Am. Chem. Soc. 59, 1675-1678.
41. Kok, G. L., S. N. Gitlin, and A. L. Lazrus, 1986: Kinetics of the formation and decomposition of hydroxymethanesulfonate. J. Geophys. Res. 91 D2, 2801-2804.
42. 2 by hydrogen peroxide. J. Geophys. Res. 88 C6, 3671-3674.
43. Lagrange, J., C. Pallares, G. Wenger, and P. Lagrange, 1993: Electrolyte effects on aqueous atmospheric oxidation of sulphur dioxide by hydrogen peroxide. Atmos. Environ. 27A, 129-137.
44. Lammel, G., D. Perner, and P. Warneck, 1990: Decomposition of pernitric acid in aqueous solution. J. Phys. Chem. 94, 6141-6144.
45. Lind, J. A., A. L. Lazrus, and G. L. Kok, 1987: Aqueous phase oxidation of sulfur(IV) by hydrogen peroxide, methylhydroperoxide, and peroxyacetic acid. J. Geophys. Res. 92, 4171-4177.
46. Logager, T., and K. Sehested, 1993: Formation and decay of peroxynitric acid: a pulse radiolysis study. J. Phys. Chem. 97, 10047-10057.
47. Maaß, F., 1995: Medium-Effekte auf die Kinetik der Oxidation von Dimethylsulfid mit Wasserstoffperoxid und Peroxotrifluoressigsäure. Diplomarbeit Technische Hochschule Darmstadt.
48. Maaß, F., 1999: Kinetik der Schwefel(IV) Oxidation mit Wasserstoffperoxid bei niedrigen Konzentrationen. Dissertation Technische Universität Darmstadt also: Maaß, F., Elias, H., and Wannowius, K. J., 1999: Kinetics of the Oxidation of Hydrogen Sulfite by Hydrogen Peroxide in aqueous Solution: Ionic Strength Effects and Temperature Dependence. Atmos. Environ. 33, 4413-4419.
49. Mader, P. M., 1958: Kinetics of the hydrogen peroxide-sulfite reaction in alkaline solution. J. Am. Chem. Soc. 80, 2634-2639.
50. McArdle, J. V., and M. R. Hoffmann, 1983: Kinetics and mechanism of the oxidation of aquated sulfur dioxide by hydrogen peroxide at low pH. J. Phys. Chem. 87, 5425-5429.
51. 4 potential energy surface. Computa-tional evidence for a new N2O4 isomer. J. Am. Chem. Soc. 117, 1629-1637.
52. Martin, L.R., and D.E. Damschen, 1981: Aqueous oxidation of sulfur dioxide by hydrogen peroxide at low pH. Atmos. Environ. 15, 1615-1621.
53. 2 in aqueous aerosols. Atmos. Environ. 15, 191-195.
54. Molina, L. T., and M. J. Molina, 1981: UV absorption cross sections of HO2,NO2. J. Photochem. 15, 97-108.
55. Oblath, S.B., S.S. Markowitz, T. Novakov, and S. G. Chang, 1981: Kinetics of the formation of hydroxylamine disulfonate by reaction of nitrite with sulfites. J. Phys. Chem. 85, 1017-1021.
56. Papee, H.M., and G.L. Petriconi, 1964: Formation and decomposition of alkaline pernitrite. Nature 204, 142-144.
57. Penkett, S. A., B. M. R. Jones, K. A. Brice, and A. E. J. Eggleton, 1979: The importance of atmospheric ozone and hydrogen peroxide in oxidising sulphur dioxide in cloud and rainwater. Atmos. Environ. 13, 123-137.
58. Reed, J. W., H. H. Ho, and W. L. Jolly, 1974: Chemical synthesis with a quenched flow reactor. Hydroxytrihydroborate and peroxynitrite. J. Am. Chem. Soc. 96, 1248-1249.
59. Rider, B. F., and M. G. Mellon, 1946: Colorimetric determination of nitrites. Ind. Eng. Chem. Anal. Ed. 18, 96-99.
60. 1 band Q branch of per-oxynitric acid in high-resolution solar absorption spectra of the stratosphere. Geo-phys. Res. Lett. 13, 761-764.
61. Schwarz, R., 1948: Peroxynitric acid. Z. Anorg. Chem. 256, 3-9.
62. Shapilov, O. D., and Y. L. Kostyukovskii, 1974a: Kinetics of the reaction of hydrogen peroxide with formic acid in aqueous solution. Kinetika i Kataliz 15, 1065-1067.
63. Shapilov, O. D., and Y. L. Kostyukovskii, 1974b: Kinetics of the reaction of hydrogen peroxide with formic acid in aqueous solution. Kinetics and Catalysis 15, 1404.
64. Smith, R.E., and A. E. Martell, 1976: Critical Stability Constants, Vol. 3 (Other Organic Ligands) and Vol. 4 (Inorganic Complexes). Plenum Press New York.
65. de Sombre, R., 1994: Kinetik und Mechanismus der Oxidation von Salpetriger Säure mit dem Anion der Peroxomonoschwefelsäure. Wissenschaftliche Hausarbeit im Rahmen des Staatsexamens für das Höhere Lehramt an Gymnasien, Technische Hochschule Darmstadt.
66. Steingens, U., 1998: Die Kinetik des Zerfalls von Peroxosalpetriger Säure in wäßriger Phase. Dissertation, Technische Universität Darmstadt, D17.
67. Sörensen, P. E., and V. S. Andersen, 1970: The formaldehyde-hydrogen sulphite system in alkaline aqueous solution. Kinetics, mechanisms and equilibria. Acta Chim. Scand. 24, 1301-1306.