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Volumn 127, Issue 40, 2005, Pages 13784-13785

The α-helix folds more rapidly at the C-terminus than at the N-terminus

Author keywords

[No Author keywords available]

Indexed keywords

ALANINE; CARBONYL DERIVATIVE; SYNTHETIC PEPTIDE;

EID: 26444460186     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja054500+     Document Type: Article
Times cited : (33)

References (22)
  • 1
    • 26444505676 scopus 로고    scopus 로고
    • note
    • The prime indicates deuterated amides.
  • 14
    • 26444571552 scopus 로고    scopus 로고
    • note
    • -1, where no peptide absorbance is found, and calibrated by temperature-dependent FTIR spectra.
  • 15
    • 26444538140 scopus 로고    scopus 로고
    • note
    • -1 (see ref 6). The corrected data after 60 ns were then fitted to a single exponential using nonlinear least-squares fitting. For each peptide, at least 25 600 single measurements were taken and analyzed in groups of 2560; time constants and their errors in Table 1 and Figure 2 are the average and standard deviation of the results of these separate fits. We have found that this method yields realistic error estimates, with repeat measurements reproducing results within the error bars (compare Figure 2 and ref 6).
  • 16
    • 26444437877 scopus 로고    scopus 로고
    • note
    • We restrict our discussion to the middle sections, since the outer sections will be affected by the previously reported capping group effects.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.