"Paradox of heterogeneous catalysis": Paradox or regularity?

Industrial and Engineering Chemistry Research

Volumn 43, Issue 12, 2004, Pages 3113-3126

  Ostrovskii, Victor E ^a  

^a KARPOV INSTITUTE OF PHYSICAL CHEMISTRY   (Russian Federation)

Author keywords

[No Author keywords available]

Indexed keywords

CATALYSIS; CHEMISORPTION; ISOTHERMS;

HETEROGENOUS CATALYTIC REACTIONS; POWER-LAW KINETIC EQUATIONS; SURFACE HETEROGENEITY;

CHEMICAL ENGINEERING;

CARBON DIOXIDE; CHROMIUM DERIVATIVE; METAL OXIDE; SULFUR DIOXIDE; ZINC OXIDE;

CATALYST; CHEMICAL ENGINEERING;

ADSORPTION; ARTICLE; CATALYSIS; CHEMICAL REACTION; HEAT; KINETICS; OXIDATION; REACTION ANALYSIS;

EID: 2642538526     PISSN: 08885885     EISSN: None     Source Type: Journal    
DOI: 10.1021/ie049923j     Document Type: Article

References (102)

1. Boudart, M. Kinetics on Ideal and Real Surfaces. AIChE J. 1956, 2, 62.
2. Kiperman, S. L.; Kumbilieva, K. E.; Petrov, L. A. Classical Catalytic Kinetics: What is the Point of the Matter? Ind. Eng. Chem. Res. 1989, 28, 376.
3. Boudart, M. Response to "Classical Catalytic Kinetics: What is the Point of the Matter?" Ind. Eng. Chem. Res. 1989, 28, 379.
4. Weller, S. W. Kinetics of Heterogeneous Catalyzed Reactions. Catal. Rev. 1992, 34 (3), 227.
5. Boudart, M.; Djéga-Mariadassou, G. Cinétique des Réactions en Catalyse Hétérogène; Masson et Cie: Paris, 1982. Boudart, M.; Djéga-Mariadassou, G. Kinetics of Heterogeneous Catalytic Reactions; Princeton University Press: Princeton: NJ, 1984.
6. Boudart, M.; Djéga-Mariadassou, G. Cinétique des Réactions en Catalyse Hétérogène; Masson et Cie: Paris, 1982. Boudart, M.; Djéga-Mariadassou, G. Kinetics of Heterogeneous Catalytic Reactions; Princeton University Press: Princeton: NJ, 1984.
7. Ostrovskii, V. E.; Karpovich, I. R.; Kul'kova, N. V.; Temkin, M. I. The Microcalorimeter for Measurements of Heats of Adsorption at Elevated Temperatures. Zh. Fiz. Khim. 1963, 37, 2596.
8. Ostrovskii, V. E. Calibration of Differential Microcalorimeters with Resistance Thermometers. Study of Catalytic Processes (Problems of the Methodology of Calorimetric Measurements; NIITEKhIM, Karpov Institute of Physical Chemistry: Moscow, 1977; p 3 (in Russian).
9. Ostrovskii, V. E. Differential Microcalorimeter for Isothermal Measurements of Heat Effects in Two-Phase Systems and Examples of its Application. Rev. Sci. Instrum. 2002, 73, 1304.
10. Roginskii, S. Z.; Zeldovich, Ya. B. The Catalytic Oxidation of Carbon Monoxide at Manganin Dioxide. Acta Physicochim. URSS 1934, 1, 554.
11. Langmuir, I. The Adsorption of Gases on Plane Surfaces of Glass, Mica, and Platinum. J. Am. Chem. Soc. 1918, 40, 1361.
12. Rideal, E. K.; Taylor, H. S. Catalysis in Theory and Practice; Macmillan and Co.: London, 1926.
13. Langmuir, I. Vapor Pressures, Evaporation, Condensation, and Adsorption. J. Am. Chem. Soc. 1932, 54, 2798.
14. Langmuir, I. Thoriated Tungsten Filaments. Acta Physicochim. URSS 1934, 1, 371.
15. Heyward, D. O.; Trapnell, B. M. W. Chemisorption, 2nd ed.; Butterworth: Washington, DC, 1964.
16. Ostrovskii, V. E. Progress in the Methods of Description of Adsorption in the Context of Principal Postulates of the Langmuir Theory. Usp. Khim. 1976, 45, 849.
17. Bond, G. C. Heterogeneous Catalysis: Principles and Applications, 2nd ed.; Clarendon Press: Oxford, 1987.
18. Temkin, M. I. Kinetics of Ammonia Synthesis at Promoted Iron Catalysts. Zh. Fiz. Khim. 1939, 13, 851.
19. Boreskov, G. K. Kataliz v proizvodstve sernoi kisloty (Catalysis in the Sulfuric Acid Industry); Goskhimisdat: Moscow, 1954 (in Russian).
20. Kul'kova, N. V.; Temkin, M. I. Kinetics of the Reaction of Conversion of Carbon Monoxide by Water Vapors (Shift-Reaction). Zh. Fiz. Khim. 1949, 23, 695.
21. Pomerantsev, V. M.; Mukhlenov, I. P.; Traber, D. G. Synthesis of Methanol in a Fluidized Catalyst. Zh. Prikl. Khim. 1963, 36, 754.
22. Cherednichenko, V. M.; Temkin, M. I. Kinetics of Catalytic Synthesis of Methanol. Zh. Fiz. Khim. 1972, 31, 1072.
23. Kulkova, N. V.; Kuznets, E. V.; Temkin, M. I. Exchange by Oxygen Isotopes between Carbon Monoxide and Carbon Dioxide at Iron Oxide Catalyst. Dokl. Akad. Nauk SSSR 1953, 90, 1067.
24. Kiperman, S. L. Introduction to the Kinetics of Heterogeneous Catalytic Reactions; Nauka: Moscow, 1964 (in Russian).
25. Temkin, M. I. Theoretical Models of Kinetics of Heterogeneous Catalytic Processes. Kinet. Katal. 1972, 13, 555.
26. Temkin, M. I. The Kinetics of Some Industrial Heterogegeous Catalytic Reactions. Adv. Catal. 1979, 28, 173.
27. Temkin, M. I. About the Reaction Ability and the Mutual Affect of the Adsorbed Atoms and Radicals Each to Other. Voprocy chimicheskoi kinetiki, kataliza i reaktsionnoi sposobnosti (Questions on Chemical Kinetics, Catalysis, and Reaction Ability); Akademii Nauk SSSR: Moscow, 1955; p 484.
28. Temkin, M. I. Kinetics and Mechanism of Ammonia Synthesis. Khim. Prom. (Chem. Ind.) 1990, No. 5, 36 (volumes are not numerated).
29. Shakhovskaya, L. I.; Rudnitskii, L. A.; Kul'kova, N. V.; Temkin, M. I. The Reaction Ability of Oxygen Chemisorbed at Silver and the Electron Work Function. Kinet. Katal. 1970, 11, 467.
30. Eley, D. D. Molecular Hydrogen and Metallic Surfaces. J. Phys. Chem. 1951, 55, 1017.
31. Fedianin, V. K. The Effect of Intermolecular Interaction in Problems of Adsorption and Absorption. Zh. Fiz. Khim. 1971, 45, 2867.
32. Boudart, M. Heterogeneity of Metal Surfaces. J. Am. Chem. Soc. 1952, 74, 3556.
33. de Boer, J. H. Chemisorption; Butterworth: London, 1957; p 27.
34. de Boer, J. H. Adsorption Phenomena. Adv. Catal. 1956, 8, 17. de Boer, J. H. Structure and Texture of Catalysts. Adv. Catal. 1957, 9, 131.
35. de Boer, J. H. Adsorption Phenomena. Adv. Catal. 1956, 8, 17. de Boer, J. H. Structure and Texture of Catalysts. Adv. Catal. 1957, 9, 131.
36. Culver, R. V.; Tompkins, F. C. Surface Potentials and Adsorption Processes on Metals. Adv. Catal. 1959, 11, 79.
37. Guandry, P. M.; Tompkins, F. C. Chemisorption of Gases on Metals. Quart. Rev. 1960, 14, 257.
38. Boeva, O. A.; Zhavoronkova, K. N.; Smutek, M.; Černý, S. Measurements of the Interaction of Hydrogen with Films of Lantanides at Room Temperature. J. Less-Common Met. 1986, 18, 1.
39. Kobozev, N. I.; Gol'dfel'd, Yu. M. On a Specific Kind of Interaction between Molecules of Adsorbed Layers. Zh. Fiz. Khim. 1937, 10, 261.
40. Vol'kenshtein, F. F. To the Problem on Interaction between Adsorbed Molecules in the Context of the Theory of Adsorption at Heterogeneous Surfaces. Zh. Fiz. Khim. 1947, 21, 163.
41. Breger, A. Kh.; Zhukhovitskii, A. A. On the Possible Mechanism of Interaction between Adsorbed Atoms. Zh. Fiz. Khim. 1947, 21, 423.
42. Stoltze, P.; Nørskov, I. K. An Interpretation of the High-Pressure Kinetics of Ammonia Synthesis Based on a Microscopic Model. J. Catal. 1988, 110, 1.
43. Dumesic, J. A.; Trevino, A. A. Kinetic Simulation of Ammonia Synthesis Catalysis. J. Catal. 1989, 116, 119.
44. Keroglu, E. V. Homogeneity of the Active Centers and the Adsorption States of Nitrogen and Hydrogen at the Surface of Porous Platinum. Thesis, Chemistry Department, Moscow State University, Moscow, 1989.
45. Corma, A.; Llopsis, F.; Monton, J. B.; Weller, S. Comparison of Models in Heterogeneous Catalysis for Ideal and Non-Ideal Surfaces. Chem. Eng. Sci. 1988, 43, 785.
46. Boreskov, G. K. Heterogeneous Catalysis; Khimiya: Moscow, 1973 (in Russian).
47. Auroux, A.; Gravell, P. C. Comparative Study of the Bond Energy of Oxygen at the Surface of Supported Silver Catalysts and of the Activity of These Catalysts for Ethylene Epoxidation. Thermochim. Acta 1981, 47, 333.
48. 2 Adsorption. J. Catal. 1987, 105, 342.
49. Djéga-Mariadassou, G.; Boudart, M. Classical Kinetics of Catalytic Reactions. J. Catal. 2003, 216, 289.
50. Ostrovskii, V. E. Mechanisms of Heterogeneous Catalytic Processes. Dokl. Akad. Nauk SSSR (Dokl. Phys. Chem.) 1990, 313, 645.
51. Ostrovskii, V. E. On the Mechanism of Ammonia Synthesis at Iron Catalysts and on the Kinetic Equation for This Process. Teor. Eksp. Khim. 1989, 25, 213.
52. Ostrovskii, V. E. On the Mechanism of the Ammonia Synthesis at Iron Catalysts. Zh. Fiz. Khim. 1989, 63, 2560.
53. Ostrovskii, V. E. The Mechanism of Methanol Synthesis from Hydrogen and Carbon Oxides at Copper-Zinc-Alumina Catalysts. Khim. Tverd. Topl. (Moscow) 2002, No. 1, 82 (volumes are not numerated).
54. Ostrovskii, V. E. Mechanisms of Methanol Synthesis from Hydrogen and Carbon Oxides at Cu-Zn-Containing Catalysts in the Context of Some Fundamental Problems of Heterogeneous Catalysis. Catal. Today 2002, 77, 141.
55. Ostrovskii, V. E.; Dyatlov, A. A. Calorimetric Study of the Mechanisms for Reactions of Carbon Monoxide and Hydrogen with Oxygen and of Carbon Monoxide with Water Vapor at Oxidized Copper-Chromium Catalyst. Kinet. Katal. 1979, 20, 958.
56. Temkin, M. I. Adsorption Equilibrium and Kinetics of the Processes Proceeding at Heterogeneous Surfaces and under the Condition of Interaction between Adsorbed Molecules. Zh. Fiz. Khim. 1941, 15, 296.
57. Ostrovskii, V. E.; Temkin, M. I. Application of Statistical Methods to a Calculation of a Rate of Adsorption on Heterogeneous Surfaces. Kinet. Katal. 1969, 10, 118.
58. Ostrovskii, V. E.; Temkin, M. I. Some Problems of the Theory of Adsorption on Homogeneous Surfaces. Kinet. Katal. 1971, 12, 1070.
59. Ostrovskii, V. E. On the Essence of the Logarithmic Isotherm in Adsorption and Electrochemical Studies. Dokl. Akad. Nauk SSSR (Dokl. Phys. Chem.) 1989, 307, 1165.
60. Pomanushkina, F. E.; Kiperman, S. L.; Temkin, M. I. Equilibrium in the Course of Reaction Between Hydrogen and Nitrogen Adsorbed at Iron. Zh. Fiz. Khim. 1953, 28, 1181.
61. Pomanushkina, F. E. Equilibrium of the Reaction of Gas Hydrogen and Nitrogen Adsorbed at Catalysts of Ammonia Synthesis. Thesis, Karpov Institute of Physical Chemistry, Moscow, 1950.
62. Bronstad, G. N. The Theory of Acid and Basic Catalysis. Trans. Faraday Soc. 1928, 24, 630.
63. Gravelle, P. C. Calorimetry in Adsorption and Heterogeneous Catalysis Studies. Catal. Rev. 1977, 16, 37.
64. Černý, S. Adsorption Calorimetry on Filaments, Vacuum-Evaporated Films and Single Crystals of Metals. Thermochim. Acta 1998, 312, 3.
65. Chornet, E.; Goughlin, R. W. Chemisorption of Hydrogen on Iron. J. Catal. 1972, 27, 246.
66. Zommer, L.; Dus, R.; Randzio, S. L. A Modified Adsorption Microcalorimeter with Computerized Collection and Reduction of the Data. Appl. Surf. Sci. 1990, 45, 93.
67. Ward, C. A.; Elmoselhi, M. B. The Coverage Dependence of the Heat of Adsorption and the Predicted Wavelength of Surface Luminescence. Surf. Sci. 1988, 203, 463.
68. Artamonov, S. V.; Zakumbaeva, G. D. Adsorption of Hydrogen, Oxygen, and Water at Platinum. The 7th All-Union Conference on Calorimetry, Chernogolovka, 1977; Izd. AN SSSR: Moscow, 1977; p 288 (in Russian).
69. 2. Kinet. Katal. 1978, 19, 1543.
70. Brennan, D.; Hayward, D. O.; Trapnell, B. M. W. The Calorimetric Determination of the Heats of Adsorption of Oxygen at Evaporated Metal Films. Proc. R. Soc. London A 1960, 256, 81.
71. Ostrovskii, V. E. Heats of Oxygen Chemisorption by Cobalt and the Influence of Inert Gases on the Rate of Chemisorption, Zh. Fiz. Khim. 1988, 62, 674.
72. Dell, R. M.; Stone, F. S.; Tiley, P. F. Adsorption of Oxygen and Other Gases on Copper. Trans. Faraday Soc. 1953, 49, 195.
73. Ostrovskii, V. E. Combined Use of Calorimetric and Adsorption Kinetic Methods for the Study of the Mechanisms of Catalytic Processes. J. Therm. Anal. 1978, 14, 27.
74. Ostrovskii, V. E.; Medvedkova, E. A. Calorimetric and Adsorption Study of the Interaction of Oxygen, Hydrogen, and Water with the Silver Catalyst Surface. Kinet. Katal. 1979, 20, 966.
75. Czanderna, A. W. Isosteric Heat of Adsorption of Oxygen on Silver. J. Vac. Sci. Technol. 1977, 14, 408.
76. 2 Catalysts. Dependence on Support and on Metal Particle Size. Thermochim. Acta 1998, 312, 115.
77. 2 Adsorption on Ni/100/. Surf. Sci. 1984, 141, 455.
78. Ostrovskii, V. E.; Igranova, E. G. Calorimetric Study of Heats of Nitrogen Chemisorption at the Catalyst of Ammonia Synthesis. Kinet. Katal. 1978, 19, 681.
79. Spiewak, B. E.; Dumesic, J. A. Applications of Adsorption Microcalorimetry for the Characterization of Metal-Based Catalysts. Thermochim. Acta 1998, 312, 95.
80. Černý, S.; Pientka, Z. Heats of Interaction of Carbon Monoxide with Dysprosium. Surf. Sci. 1987, 191, 449.
81. Bondareva, V. M.; Andrushkevich, T. V.; Pankratiev, Yu. D.; Turkov, V. M. Adsorption Heats of Acrolein and Acrylic Acid on Promoted V-Mo-O Catalysts. React. Kinet. Catal. 1986, 32, 371.
82. Palfi, S.; Lisowski, W.; Smutek, M.; Černý, S. Calorimetric Studies of Hydrocarbon Adsorption on Metal Films: Hydrocarbons on Platinum. J. Catal. 1984, 88, 300.
83. Černý, S.; Smutek, M.; Buzek, S. The Calorimetric Heats of Adsorption of Hydrogen on Platinum Films. J. Catal. 1975, 38, 245.
84. Igranova, E. G.; Ostrovskii, V. E.; Temkin, M. I. Calorimetric Study of Adsorbed Products of Incomplete Hydrogenation of Nitrogen on Iron Catalyst, in the Context of the Mechanisms of Ammonia Synthesis. Kinet. Katal. 1976, 17, 1257.
85. Igranova, E. G.; Ostrovskii, V. E. Calorimetric Study of Hydrogen Sorption at Iron Catalysts of Ammonia Synthesis. Dokl. Akad. Nauk SSSR 1975, 221, 1351.
86. Emmett, P. H.; Brunauer, S. The Adsorption of Nitrogen by Iron Synthetic Ammonia Catalyst. J. Am. Chem. Soc. 1934, 56, 35.
87. Ostrovskii, V. E.; Diatlov, A. A. Mechanisms and Kinetic Equation of the Methanol Synthesis. Dokl. Akad. Nauk SSSR 1982, 264, 363.
88. Ostrovskii, V. E.; Diatlov, A. A.; Ogneva, T. P. Study of Carbon Monoxide Adsorption at the Catalyst of Low-Temperature Methanol Synthesis. Kinet. Katal. 1978, 19, 514.
89. 2 at the Oxide Copper-Zinc-Aluminum Catalyst of Methanol Synthesis. Kinet. Katal. 1984, 25, 159.
90. Diatlov, A. A.; Ostrovskii, V. E. Identification of the Surface Substances Desorbed under Vacuum from the Copper-Zinc-Aluminum Catalyst Covered Preliminary with Carbon Dioxide and Hydrogen. Kinet. Katal. 1985, 26, 1154.
91. Ostrovskii, V. E.; Diatlov, A. A. Study of Copper-Zinc-Aluminum Catalysts in Oxidized and Reduced States: Chemisorption and Absorption of Hydrogen and Water. Kinet. Katal. 1985, 26, 938.
92. 2 Grading. Int. J. Mod. Phys. B 2002, 16, 42.
93. Beeck, O.; Cole, W. A.; Wheeler, A. Determination of Heats of Adsorption Using Metal Films. Discuss. Faraday Soc. 1950, 8, 314.
94. Wahba, M.; Kemball, C. Heats of Adsorption of Ammonia and Hydrogen on Metal Films. Trans. Faraday Soc. 1953, 49, 1351.
95. Rideal, E.; Sweett, F. The Chemisorption of Hydrogen on Nickel. Proc. Roc. Soc. London A 1960, 257, 291.
96. Brennan, D.; Hayes, F. H. Heats of Adsorption of Hydrogen on Evaporated Films of Tungsten and of Nickel. Trans. Faraday Soc. 1964, 60, 589.
97. Bröcker, F. I.; Wedler, G. Calorimetric Studies of the Chemisorption and Desorption of Hydrogen on Nickel Films under Ultra High Vacuum Conditions. Discuss. Faraday Soc. 1966, 41, 87.
98. Beeck, O. Hydrogenation Catalysts. Discuss. Faraday Soc. 1950, 8, 118.
99. Porter, A. S.; Tompkins, F. C. The Kinetics of Chemisorption of Hydrogen and Carbon Monoxide on Evaporated Iron Films. Proc. R. Soc. London A 1953, 217, 529. Porter, A. S.; Tompkins, F. C. The Sorption of Hydrogen and Other Gases by Evaporated Iron Films. Proc. R. Soc. London A 1953, 217, 574.
100. Porter, A. S.; Tompkins, F. C. The Kinetics of Chemisorption of Hydrogen and Carbon Monoxide on Evaporated Iron Films. Proc. R. Soc. London A 1953, 217, 529. Porter, A. S.; Tompkins, F. C. The Sorption of Hydrogen and Other Gases by Evaporated Iron Films. Proc. R. Soc. London A 1953, 217, 574.
101. Wedler, G.; Geuss, K.-P.; Kolb, K. G.; McElhinei, G. Heats of Adsorption of Hydrogen on Polycrystalline Iron Films. Appl. Surf Sci. 1978, 1, 471.
102. Ostrovskii, V. E.; Temkin, M. I. Heats of Oxygen Chemisorption at Silver. Kinet. Katal. 1966, 7, 529.