Hypothetical thermodynamic properties: The boiling and critical temperatures of polyethylene and polytetrafluoroethylene

Journal of Chemical and Engineering Data

Volumn 49, Issue 3, 2004, Pages 518-526

  Chickos, James S ^a  

^a UNIVERSITY OF MISSOURI ST LOUIS   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CRITICAL PRESSURE; CRITICAL TEMPERATURE; GIBB'S EQUATION; HYPERBOLIC FUNCTIONS;

ASYMPTOTIC STABILITY; ENTHALPY; ENTROPY; EXTRAPOLATION; MATHEMATICAL MODELS; MELTING; POLYETHYLENES; POLYNOMIALS; POLYTETRAFLUOROETHYLENES; SUBLIMATION; VAPOR PRESSURE; VAPORIZATION;

THERMODYNAMICS;

EID: 2642532874     PISSN: 00219568     EISSN: None     Source Type: Journal    
DOI: 10.1021/je030211u     Document Type: Article

References (23)

1. (a) Chickos, J.; Hesse, D.; Hosseini, S.; Nichols, G.; Webb, P. Sublimation Enthalpies at 298.15 K Using Corrrelation Gas Chromatography and Differential Scanning Calorimetry Measurements. Thermochim. Acta 1998, 313, 101-110.
2. (b) Chickos, J. S.; Hillesheim, D. M.; Verevkin, S.; Roux, M. V.; Temprado, M.; Segura, M.; Notario, R. DeMasters, D. E.; Liebmam, J. F. The Energetics of the Isomeric 1- and 2-Naphthoic Acids: Context, Quantum Chemical Calculations and Thermochemical Measurements. Mol. Phys. 2003, 101, 1311-1318.
3. Allen, J. O.; Sarofim, A. F.; Smith, K. A. Thermodynamic Properties of Polyaromatic Hydrocarbons in the Subcooled Liquid State. Polycyclic Aromat. Cmpd. 1999, 13, 261-283.
4. Chickos, J. S.; Nichols, G.; Ruelle, P. The Estimation of Melting Points and Enthalpies of Fusion Using Experimental Solubilities, Estimated Total Phase Change Entropies, and Mobile Order and Disorder Theory. J. Chem. Inf. Comput. Sci. 2001, 42, 368-374.
5. Chickos, J. S.; Nichols, G. Simple Relationships for the Estimation of Melting Temperatures of Homologous Series. J. Chem. Eng. Data 2002, 46, 562-573.
6. Somayajulu, G. R. The Melting Points of Ultralong Paraffins and Their Homologues. Int. J. Thermophys. 1990, 11, 555-572.
7. Woolf, A. A. Relations between the Boiling Points of Perfluoro-Ethers, Perfluoroalkanes and Normal Alkanes. J. Fluorine Chem. 1993, 63, 19-24.
8. Kreglewski, A.; Zwolinski, B. J. A New Relation for Physical Properties of n-Alkanes and n-Alkyl Compounds. J. Phys. Chem. 1961, 65, 1050-1052.
9. Kurata, M.; Ishida, S. Theory of Normal Paraffin Liquids. J. Chem. Phys. 1955, 23, 1126-1131.
10. Wilhoit, R. C.; Zwolinski, B. J. Handbook of Vapor Pressures and Heats of Vaporization of Hydrocarbons and Related Compounds. Publication 101, Thermodynamics Research Center, Texas A & M University, College Station, TX, 1971.
11. Somayajulu. G. R. The Critical Constants of Long Chain Normal Paraffins. Int. J. Thermophys. 1991, 12, 1039-1062.
12. (a) Ambrose, D.; Tsonopoulos, C. Vapor-Liquid Critical Properties of Elements and Compounds. 2. Normal Alkanes. J. Chem. Eng. Data 1995, 40, 531-546.
13. (b) Gude, M.; Teja, A. S. Vapor-Liquid Critical Properties and Compounds. 4. Aliphatic Alkanols. J. Chem. Eng. Data 1995, 40, 1025-1036. Daubert, T. E. Vapor-Liquid Critical Properties of Elements and Compounds. 5. Branched Alkanes and Cycloalkanes. J. Chem. Eng. Data 1996, 41, 365-372.
14. (b) Gude, M.; Teja, A. S. Vapor-Liquid Critical Properties and Compounds. 4. Aliphatic Alkanols. J. Chem. Eng. Data 1995, 40, 1025-1036. Daubert, T. E. Vapor-Liquid Critical Properties of Elements and Compounds. 5. Branched Alkanes and Cycloalkanes. J. Chem. Eng. Data 1996, 41, 365-372.
15. (c) Tsonopoulos, C.; Ambrose, D. Vapor-Liquid Critical Properties of Elements and Compounds. 6. Unsaturated aliphatic Hydrocarbons. J. Chem. Eng. Data 1996, 41, 645-656.
16. (d) Kudchadker, A. P.; Ambrose, D.; Tsonopoulos, C. Vapor-Liquid Critical Properties of Elements and Compounds. 7. Organic Compounds Other Than Alkanols and Cycloalkanols. J. Chem. Eng. Data 2001, 46, 457-479.
17. Ambrose, D. NPL Report Chemistry 92, National Physical Laboratory, Teddington, Middlesex UK, 1978.
18. The use of a quintic equation in X gives an overall better fit; positions of the maximum in Figures 6 and 7 are not appreciably affected.
19. Woolf, A. A. Relationships between the Boiling Points of Perfluoro-Ethers. Perfluoroalkanes and Normal Alkanes. J. Fluorine Chem. 1993, 63, 19-25.
20. Vandana, V.; Rosenthal, D. J.; Teja, A. S. The Critical Properties of Perfluoro n-Alkanes. Fluid Phase Equilib. 1994, 99, 209-218.
21. Chickos, J. S.; Acree, W. E., Jr. Enthalpies of Vaporization of Organic and Organometallic Compounds, 1880-2002. J. Phys Chem. Ref. Data 2003, 32, 515-878.
22. Chickos, J. S.; Hesse, D. G.; Liebman, J. F. A Group Additivity Approach for the Estimation of Heat Capacities of Organic Liquids and Solids at 298 K. Struct. Chem. 1993, 4, 261-269.
23. -1. Chickos, J. S.; Hesse, D. G.; Liebman, J. F. Heat Capacity Corrections to a Standard State: A Comparison of New and Some Literature Methods for Organic Liquids and Solids. Struct. Chem. 1993, 4, 271-278.