Acid-catalyzed alcoholysis of soybean oil

JAOCS, Journal of the American Oil Chemists' Society

Volumn 81, Issue 4, 2004, Pages 415-420

  Goff, Michael J ^a   Bauer, Nicholas S ^a   Lopes, Shailesh ^a   Sutterlin, William R ^a   Suppes, Galen J ^a  

^a University of Missouri   (United States)

Author keywords

Acid catalysis; Biodiesel; Methyl esters; Soybean oil alcoholysis; Trigylceride

Indexed keywords

ACIDS; ALCOHOLS; CATALYSIS; ESTERIFICATION; HIGH TEMPERATURE EFFECTS; SAPONIFICATION; STOICHIOMETRY;

BIODIESELS; METHYL ESTERS; TRIGLYCERIDES;

VEGETABLE OILS;

GLYCINE MAX;

EID: 2642528569     PISSN: 0003021X     EISSN: None     Source Type: Journal    
DOI: 10.1007/s11746-004-0915-6     Document Type: Article

References (19)

1. Suppes, G.J., M.J. Goff, and S. Lopes, Latent Heat Characteristics of Fatty Acid Derivatives Pursuant Phase Change Material Applications, Chem. Eng. Sci. 55:1751-1763 (2003).
2. Bradshaw, G.B., and W.C. Meuly, Preparation of Detergents, U.S. Patent 2,360,844 (1944).
3. Feuge, R.O., and T. Gros, Modification of Vegetable Oils. VII. Alkali-Catalyzed Interesterification of Peanut Oil with Ethanol, J. Am. Oil Chem. Soc. 26:97-102 (1949).
4. Freedman, B., and E.H. Pryde, Fatty Esters from Vegetable Oils for Use as a Diesel Fuel, in Vegetable Oil Fuels - Proceedings of the International Conference on Plant and Vegetable Oils as Fuels (Fargo, North Dakota, 2-4 August, 1982), American Society of Agricultural Engineers, St. Joseph, MI, 1982, pp. 117-122.
5. Kusy, P.G., Transesterification of Vegetable Oils for Fuels, in Ibid., pp. 127-137.
6. Knothe, G., R.O. Dunn, and M.O. Bagby, The Use of Vegetable Oils and Their Derivatives as Alternative Diesel Fuels, in Fuels and Chemicals from Biomass, edited by B.C. Sana and J. Woodward, American Chemical Society, Washington DC, 1997, pp. 172-208.
7. Suppes, G.J., K. Bockwinkel, S. Lucas, J.B. Botts, M.H. Mason, and J.A. Heppert, Calcium Carbonate Catalyzed Alcoholysis of Fats and Oils, J. Am. Oil Chem. Soc. 75:139-145 (2001).
8. Bayense, C.R., H. Hinnekens, and J. Marten, Process for Transesterification of Carboxylic Acid Esters Using a Heterogeneous Catalyst, European Patent 94-19941109 (1994).
9. Suppes, G.J., M.A. Dasari, E.J. Doskocil, P.J. Mankidy, and M.J. Goff. Transesterification of Soybean Oil with Zeolite and Metal Catalysts, Appl. Catal. A 257:213-223 (2004).
10. Canakci, M., and J. Van Gerpen, Biodiesel Production from Oils and Fats with High FFAs, Trans. ASAE 44:1429-1436 (2001).
11. Kawahara, Y., and T. Ono, Process for Producing Lower Alcohol Esters of Fatty Acids, U.S. Patent 4,164,506 (1979).
12. Markley, K.S., Esters and Esterification, in Fatty Acids: Their Chemistry, Properties, Production, and Uses, edited by K.S. Markley, Interscience Publishers, New York, 1961, p. 775.
13. Schwab, A.W., M.O. Bagby, and B. Freedman, Preparation and Properties of Diesel Fuels from Vegetable Oils, Fuel 66:1372-1378 (1987).
14. Liu, K., Preparation of Fatty Acid Methyl Esters for Gas Chromatographic Analysis of Lipids in Biological Materials, J. Am. Oil Chem. Soc. 71: 179-1187 (1994).
15. Freedman, B., E.H. Pryde, and T.L. Mounts, Variables Affecting the Yields of Fatty Esters from Transesterified Vegetable Oils, Ibid. 67:1638-1643 (1984).
16. Haas, M.J., P.J. Michalski, S. Runyon, A. Nuñez, and K.M. Scott, Production of FAME from Acid Oil, a By-product of Vegetable Oil Refining. Ibid. 50:97-102 (2003).
17. Dasari, M.A., M.J. Goff, and G.J. Suppes, Non-catalytic Alcoholysis Kinetics of Soybean Oil, Ibid. 80: 189-192 (2003).
18. Dean, J.A., Lange's Handbook of Chemistry, 13th edn., McGraw-Hill, New York, 1985, pp. 5-14-5-39.
19. Kulkarni, A.S., R.R. Khotpal, R.L. Mehta, and H.A. Bhakare, Studies in Sulfation and Sulfonation of Some Semi-drying Oils, PaintIndia 41:41-42(1991).