The kinetics and mechanism of the direct fluorination of polyethylenes

Surface Coatings International Part B: Coatings Transactions

Volumn 88, Issue 3, 2005, Pages 201-212

  Kharitonov, A P ^a   Taege, R ^b   Ferrier, G ^c   Piven, N P ^a  

^a SEMENOV INSTITUTE OF CHEMICAL PHYSICS   (Russian Federation)

^b Air Products GmbH   (Germany)

^c AIR PRODUCTS AND CHEMICALS INC   (United States)

Author keywords

Direct fluorination; Fluorinated layer; Kinetics; Mechanism; Polyethylene

Indexed keywords

CHEMICAL BONDS; DIFFUSION; FLUOROCARBONS; MOLECULAR DYNAMICS; PROCESS CONTROL; REACTION KINETICS; ULTRAVIOLET RADIATION;

DIRECT FLUORINATION; FLUORINATATED OTHERS; INDUSTRIAL PROCESSES; MOLECULAR FLUORINE;

POLYETHYLENES;

EID: 25844530836     PISSN: 14764865     EISSN: None     Source Type: Journal    
DOI: 10.1007/BF02699574     Document Type: Article

References (37)

1. Kharitonov A P, 'Practical applications of the direct fluorination of polymers', J Fluorine Chem, 103, 123, 2000
2. Lagow R J and J L Margrave, 'Direct fluorination: a 'new' approach to fluorine chemistry', Progr in Inorg Chem, 26, 162, 1979
3. Jagur-Grodzinski J, 'Modification of polymers under heterogeneous conditions', Progr in Polymer Sci, 17, 361, 1992
4. Anand M, J P Hobbs and I J Brass, 'Surface fluorination of polymers', Organofluorine Chemistry: Principles and Commercial Applications, (eds) R E Banks, B E Smart and J C Tatlow, 469-81, Plenum Press, New York, 1994
5. Lagow R J and J L Margrave, 'Letters to the Editor', J Polymer Sci Polymer, 12, 177, 1974
6. Moorehead A and L Margrave, 2nd International Conference, 'Fluorine in coatings', Conference paper no 15, Salford, England, 28th to 30th September 1994
7. Hara N, H Fukumoto and M Watanabe, 'In-situ kinetic study on direct fluorination of thin polyethylene films with QCM', Bull Chem Soc Jpn, 68, 1232, 1995
8. Corbin G A, R E Cohen and R F Baddour, 'Kinetics of polymer surface fluorination: Elemental and plasma-enhanced reactions', Polymer, 23, 1546, 1982
9. Millard M, J Burns and B Sachdev, 'Mild direct fluorination of polymers studied by x-ray photoelectron spectroscopy', Proceedings of the International Symposium (ACS), 2, 773, London, 1983
10. Schonhorn H and R H Hansen, 'Surface treatment of polymers. II. Effectiveness of fluorination as a surface treatment for polyethylene', J Appl Polymer Sci, 12, 1231, 1968
11. R D Sanderson, F J du Toit, P A B Carstens, J B Wagener, 'Fluorination rates of polyolefins as a function of structure and gas atmosphere', J of Thermal Analysis, 41, 563, 1994
12. Shinohara H, M Iwasaki, S Tsujimura, K Watanabe and S Okazaki, 'Fluorination of polyhydro-fluoroethylenes. I. Direct fluorination of poly(vinyl fluoride) film', J Polymer Sci A-1, 10, 2129, 1972
13. Scherer G G, P Pfluger, H Braun, J Klein and H Widdecke, 'Elemental fluorination of poly(vinylidene fluoride)', Macromol Chem Rapid Commun, 5, 611, 1984
14. Blackwell C S, P J Degen and F D Osterholtz, 'Internal reflectance spectroscopy of reacted surfaces: Fluorinated polyethylene and polypropylene', Appl Spectr, 32, 480, 1978
15. Nazarov V G, V P Stolyarov, L A Evlampieva and A F Fokin, 'Heterogeneous fluorinaton of polymers', Doklady Academii Nauk, 350, 639, 1996 (in Russian)
16. Florin R E, 'Electron-spin resonancespectra of polymers during fIuorination', J Fluorine Chem, 14, 253, 1979
17. Florin R E and L A Wall, 'Radicals detected by electron spin resonance during fluorination of polymers', J Chem Phys, 57, 1791, 1972
18. Kuzina S I, A P Kharitonov, Yu L Moskvin and A I Mikhailov, 'Formation of free radicals in the low-temperature fluorination of polymers', Russ Chem Bull, 45, 1623, 1996
19. Taege R, G Ferrier and A P Kharitonov, Proceedings from the 16th European Symposium on Fluorine Chemistry, A34, Durham, UK, 16th to 21st July 2000
20. Kharitonov A P, N P Piven, R Taege and G Ferrier, Proceedings from the first international Siberian Workshop Intersibfluorine 2003 (Advanced Inorganic Fluorides), 253, Novosibirsk, Russia, 2nd to 4th April 2003
21. Kharitonov A P, N P Piven, R Taege and G Ferrier, Proceedings from the 5th international Fluorine in Coatings conference, Paper no 8, Orlando, Florida, USA, 21st to 22nd January 2003
22. Shamir J and J Binenboym, 'Photochemical synthesis of dioxygenyl salts', Inorganica Chimica Acta, 2, 37, 1968
23. Kharitonov A P, Yu L Moskvin and G A Kolpakov, Application of the interference spectroscopy method to study the kinetics of chemical reactions in optically transparent films', Polymer Science USSR, 27, 739, 1985
24. Kharitonov A P, Yu L Moskvin and G A Kolpakov, The direct fluorination of polyethylene terephthalate films', Sov J Chem Phys, 4, 877, 1987
25. Kharitonov A P, Yu L Moskvin, L N Kharitonova, M N Tulskii and A A Kotenko, 'An investigation into the direct fluorination kinetics of polymeric membranes', Mendeleev Communications, N3, 91, 1994
26. Kharitonov A P, Yu L Moskvin, L N Kharitonova, A A Kotenko and M N Tulskii, 'Kinetics of gas-phase fluorination of homogeneous films and composite membranes based on polycarbonate siloxane and block-copolymer of polysulfone and polybutadiene', Kinetics and Catalysis, 35, 792, 1994
27. Kharitonov A P, Yu L Moskvin, L N Kharitonova, A A Kotenko and M N Tulskii, 'Use of interference methods for study of the fIuorination kinetics of homogeneous and composite polymeric membranes', Polymer Science, B37, 307, 1995
28. Kharitonov A P and Yu L Moskvin, 'Direct fluorination of polystyrene films', J Fluorine Chem, 91, 87, 1998
29. Kharitonov A P, Yu L Moskvin, V V Teplyakov and J D Le Roux, 'Direct fluorination of poly(vinyl trimethylsilane) and poly(phenylene oxide)', J Fluorine Chem, 93, 129, 1999
30. Kharitonov A P and Yu L Moskvin, Proceedings from the 2nd international Fluorine in Coatings conference, Paper no 13, Salford, England, 28th to 30th September 1994
31. Socrates G, Infrared Characteristic Group Frequencies, 34-51, 62-7, 80-118, 155-60, (2nd edition), John Wiley & Sons, Chichester, NY, Brisbane, Toronto, 1994, ISBN 0 471 94230 8
32. Willbourn A H, J Polymer Science, 34, 569, 1959
33. Milinchuk V K, E R Klinshpont and S Ya Pshejeckii, 'Chemistry' edition, Makroradikaly, Moscow, 1980 (in Russian)
34. Kolpakov G A, S I Kuzina, A P Kharitonov, Yu L Moskvin and A I Mikhailov, 'Free radical accumulation during direct fluorination of polystyrene', Sov J Chem Phys, 9, 2283, 1992
35. Dole M, D C Milner and T F Williams, 'Irradiation of polyethylene. II. Kinetics of unsaturation effects', J Amer Chem Soc, 80, 1580, 1958
36. Dekhant J, R Danz, V Kimmer and R Schmolke, Ultrarotspektroskopische Untersuchungen an Polymeren, Chapter 5.2, Academie-Verlag, Berlin, 1972 (in German)
37. Kharitonov A P and Yu L Moskvin, 'Kinetics of the direct gas phase fluorination and the gaspermeability of polystyrene films', Chemical Physics Reports, 13, 818, 1994 (formerly the Sov J Chem Phys)