Insights into a multifunctional hybrid catalyst composed of Co/SiO 2 and Pd/Beta for isoparaffin production from syngas

Industrial and Engineering Chemistry Research

Volumn 44, Issue 19, 2005, Pages 7329-7336

  Liu, Zhong Wen ^a,b   Li, Xiaohong ^a   Asami, Kenji ^a   Fujimoto, Kaoru ^a  

^a UNIVERSITY OF KITAKYUSHU   (Japan)

^b NANJING TECH UNIVERSITY   (China)

Author keywords

[No Author keywords available]

Indexed keywords

CARBON MONOXIDE; CATALYST ACTIVITY; COBALT; CRACKING (CHEMICAL); GASOLINE; HYDROGENATION; INTERFACES (MATERIALS); SILICON COMPOUNDS; SYNTHESIS (CHEMICAL); SYNTHESIS GAS;

HYBRID CATALYSTS; ISOPARAFFINS; REACTION CONDITIONS; SYNERGISTIC EFFECT;

PARAFFINS;

CHEMICAL ENGINEERING; SYNTHESIS GAS;

EID: 25844514800     PISSN: 08885885     EISSN: None     Source Type: Journal    
DOI: 10.1021/ie050645d     Document Type: Article

References (34)

1. Schulz, H. Short History and Present Trends of Fischer-Tropsch Synthesis. Appl. Catal., A 1999, 186, 3.
2. Iglesia, E. Design, Synthesis, and use of Cobalt-based Fischer-Tropsch Synthesis Catalysts. Appl. Catal., A 1997, 161, 59.
3. 2: Catalytic Tests and Surface Analysis of Adsorbed Hydrocarbons. Catal. Lett. 1998, 52, 131.
4. Tsubaki, N.; Yoneyama, Y.; Michiki, K.; Fujimoto, K. Three-component Hybrid Catalyst for Direct Synthesis of Isoparaffin via Modified Fischer-Tropsch Synthesis. Catal. Commun. 2003, 4, 108.
5. Jothimurugesan, K.; Gangwal, S. K. Titania-supported Bimetallic Catalysts Combined with HZSM-5 for Fischer-Tropsch Synthesis. Ind. Eng. Chem. Res. 1998, 37, 1181.
6. Tsubaki, N.; Michiki, K.; Yoneyama, Y.; Fujimoto, K. Direct Isoparaffin Synthesis from Syngas by Hybrid Catalysts System. J. Pet. Inst. Jpn. 2001, 44, 338.
7. 2 Catalysts. Can. J. Chem. Eng. 2003, 81, 230.
8. Li, X.; Luo, M.; Asami, K. Direct Synthesis of Middle Isoparaffins from Synthesis Gas on Hybrid Catalysts. Catal. Today 2004, 59, 439.
9. Li, X.; Asami, K.; Luo, M.; Michiki, K.; Tsubaki, N.; Fujimoto, K. Direct Synthesis of Middle Iso-paraffins from Synthesis Gas. Catal. Today 2003, 84, 59.
10. Bessell, S. Investigation of Bifunctional Zeolite Supported Cobalt Fischer-Tropsch Catalysts. Appl. Catal., A 1995, 126, 235.
11. Nijs, H. H.; Jacobs, P. A. New Evidence for the Mechanism of the Fischer-Tropsch Synthesis of Hydrocarbons. J. Catal. 1980, 66, 401.
12. Koh, D. J.; Chung, J. S.; Kim, Y. G. Selective Synthesis and Chain Growth of Linear Hydrocarbons in the Fischer-Tropsch Synthesis over Zeolite-Entrapped Cobalt Catalysts. Ind. Eng. Chem. Res. 1995, 34, 1969.
13. Song, X.; Sayari, A. Sulfated Zirconia as a Cocatalyst in Fischer-Tropsch Synthesis. Energy Fuels 1996, 10, 561.
14. Dzikh, I. P.; Lopes, J. M.; Lemos, F.; Ribeiro, F. R. Temperature Dependence of the HUSY+HZSM-5 Mixing Effect on the n-Heptane Transformation. Catal. Today 2001, 65, 143.
15. 3 for the Isomerization of n-Hexane. Catal. Lett. 2002, 79, 133.
16. Mao, D.; Yang, W.; Xia, J.; Zhang, B.; Song, Q.; Chen, Q. Highly Effective Hybrid Catalyst for the Direct Synthesis of Dimethyl Ether from Syngas with Magnesium Oxide-modified HZSM-5 as a Dehydration Component. J. Catal. 2005, 230, 140.
17. 4 Paraffins from Synthesis Gas. J. Catal. 1985, 94, 16.
18. 2 and Pd/β Hybrid Catalysts. Catal. Commun., 2005, 8, 503.
19. Ono, Y. A Survey of the Mechanism in Catalytic Isomerization of Alkanes. Catal. Today 2003, 81, 3.
20. Weisz, P. B.; Swegler, E. W. Stepwise Reaction on Separate Catalytic Centers: Isomerization of Saturated Hydrocarbons. Science 1957, 126, 31.
21. Fujimoto, K. Hydrogen Spillover and Hydrocracking, Hydroisomerization. In Hydrotreatment and Hydrocracking of Oil Fractions; Delmon, B., Froment, G. F., Grange P., Eds.; Elsevier Science B. V.: Amsterdam, 1999, p37.
22. Chu, H.; Rosynek, M. P.; Lunsford, J. H. Skeletal Isomerization of Hexane over Pt/H-Beta Zeolites: Is the Classical Mechanism Correct? J. Catal. 1998, 178, 352.
23. Duchet, J.-C.; Guillaume, D.; Monnier, A.; Gestel, J. van; Szabo, G.; Nascimento, P.; Decker, S. Mechanism for Isomerization of n-Hexane over Sulfated Zirconia: Role of Hydrogen. J. Chem. Soc., Chem. Commun. 1999, 1819.
24. Fujimoto, K.; Adachi, M.; Tominaga, H. Direct Synthesis of Isoparaffm from Synthesis Gas. Chem. Lett. 1985, 783.
25. Nakamura, I.; Sunada, K.; Fujimoto, K. Low-Temperature Hydrocracking of Paraffinic Hydrocarbons over Hybrid Catalysts. Stud. Surf. Sci. Catal. 1997, 105, 1005.
26. Ueda, R.; Tomishige, K.; Fujimoto, K. Promoting Effect of Hydrogen Spillover on Pyridine Migration Adsorbed on Lewis Acid Sites in USY Zeolite. Catal. Lett. 1999, 57, 145.
27. Zhang, A.; Nakamura, I.; Aimoto, K.; Fujimoto, K. Isomerization of n-Pentane and Other Light Hydrocarbons on Hybrid Catalyst. Effect of Hydrogen Spillover. Ind. Eng. Chem. Res. 1995, 34, 1074.
28. Ueda, R.; Kusakari, K.; Tomishige, K.; Fujimoto, K. Nature of Spilt-over Hydrogen on Acid Sites in Zeolites: Observation of the Behavior of Adsorbed Pyridine on Zeolite Catalysts by Means of FTIR. J. Catal. 2000, 194, 14.
29. 2 + H-Beta. Appl. Catal. A 2002, 224, 219.
30. 7-Hydroconversion Selectivities on Y, β, ZSM-22, ZSM-23, and EU-1 Zeolites. J. Catal. 2001, 197, 98.
31. Kuhn, W. K.; Szanyi, J.; Goodman, D. W. CO Adsorption on Pd(111): the Effects of Temperature and Pressure. Surf. Sci. 1992, 274, L611.
32. Rupprechter, G.; Morkel, M.; Freund, H.; Hirschl, R. Sum Frequency Generation and Density Functional Studies of CO-H Interaction and Hydrogen Bulk Dissolution on Pd(l 11). Surf. Sci. 2004, 554, 43.
33. Huang, Y.-Y.; Anderson, J. R. On the Reduction of Supported Iron Catalysts Studied by Mössbauer Spectroscopy. J. Catal. 1975, 40, 143.
34. 2+ in NaY. Catal. Lett. 1989, 2, 395.