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25844509828
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A(t) process obtained from the G(t) line-shape analysis (i.e., eq 8) has been used when the J(t) line-shape analysis over the whole range is being made, whose results are shown in Figures 1 and 2.
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25844518975
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Note: The polydispersity of the sample, even though nearly monodisperse, has an effect on the detailed line shape of J(t) in the rubber-like-to-fluid region. This effect, as can be easily accounted for by convolution with the Schulz distribution, virtually does not affect the obtained K value. See section 3.4.
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30
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25844492411
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note
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p) are proportional to K′, which is in turn proportional to K through eq 8.
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25844500797
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note
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The uncertainty ±0.4 in temperature is estimated from the standard deviation of K as shown in Table 1 and the temperature dependence of viscosity as given in ref 29; this uncertainty is an overestimate as the standard deviation of K includes the errors in molecular weight of the samples.
-
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35
-
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25844515598
-
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note
-
In the visual superposition to obtain a good fit, both the calculated and measured curves are first displayed in separate figures using the same scales. The figures are stored in a graphic software (CorelDRAW), which allows the superposition to be done under a large magnification on a monitor and at the same time allows the data points being plotted onto the calculated curve. The finished figures can be adjusted to any suitable size. In this procedure, logical steps can be followed to ensure that the comparison between the theory and experiments is accurate.
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37
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25844434678
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S of sample A as defined in ref 31 (i.e., equivalent to the temperature dependence of the product of K and s) and that of J(t) in the recoverable region determined by Plazek through data reduction, as shown in Figure 5 of ref 31. The agreement in temperature dependence between the obtained K values and the viscosity results of Plazek is also shown in the same figure. These agreements support the consistency between the composition of the J(t) curves measured at different temperatures as shown in Figure 1 and that shown in Figure 2 of ref 19; the former is guided by the fittings to eqs 1, 4, and 5, while the latter was done through the data reduction by Plazek.
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25844452678
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e, which can be regarded as a solvent as far as entanglement is concerned. The details can be found in refs 4 and 5.
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25844463601
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g value, the value of sample A should be close to 97 °C, while that of sample B should be around 98.5 °C. (see refs 42 and 43).
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Note: One may also calculate the shift Δ log t using eq 3 of ref 44.
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25844458183
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n of the sample has gone significantly beyond 1.1. See refs 5 and 88 for details.
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98
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25844530742
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See page 182 of ref 5
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See page 182 of ref 5.
-
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