Nucleophilic cleavage of crosslinked polysiloxanes to cyclic siloxane monomers: Mild catalysis by a designed polar solvent system

Journal of Polymer Research

Volumn 12, Issue 6, 2005, Pages 433-438

  Chang, Cheng Liang ^a   Lee, Howard Shih Jen ^b   Chen, Cheng Kwo ^a  

^a TAMKANG UNIVERSITY   (Taiwan)

^b China Development Industrial Bank   (Taiwan)

Author keywords

Alcoholysis; Aminolysis; Base catalyst; Polydimethylsiloxane networks

Indexed keywords

CATALYSIS; CATALYSTS; CROSSLINKING; HYDROPHOBICITY; MONOMERS; OLIGOMERS; RATE CONSTANTS; VULCANIZATION;

ALCOHOLYSIS; AMINOLYSIS; BASE CATALYSTS; POLYDIMETHYLSILOXANE NETWORKS;

SILICONES;

EID: 25444503981     PISSN: 10229760     EISSN: None     Source Type: Journal    
DOI: 10.1007/s10965-004-1871-1     Document Type: Article

References (7)

1. M. G. Voronkov, V. P. Mileshkevich and Yu. A. Yuzhelevskii, The Siloxane Bond, Consultants Bureau, New York, 1978.
2. Y. C. Hsiao, L. W. Hill and S. P. Pappas, J. Appl. Polym. Sci., 19, 2817 (1975).
3. S. P. Pappas and R. L. Just, J. Polym. Sci.: Polym. Chem. Ed., 18, 527 (1980).
4. K. H. Schimmel, Acta Polymerica, 38, 495 (1987).
5. K. H. Schimmel and J. Schulz, Acta Polymerica, 38, 536 (1987).
6. K. H. Schimmel, E. Schroder, J. Schulz and J. Souvimonh, Acta Polymerica, 39, 310 (1988).
7. C. L. Chang, H. S. Lee and C. K. Chen, Polym. Degrad. Stab., 65, 1 (1999).