Analysis of the effects of protic, aprotic, and multi-component solvents on the fluorescence emission of naphthalene and its exciplex with triethylamine

Journal of Fluorescence

Volumn 15, Issue 4, 2005, Pages 475-483

  Xie, Guobin ^a   Sueishi, Yoshimi ^a   Yamamoto, Shunzo ^a  

^a OKAYAMA UNIVERSITY   (Japan)

Author keywords

Exciplex; Fluorescence; Hydrogen bonding; Polar effect; Solvent effect

Indexed keywords

ACETIC ACID; ALCOHOLS; ELECTROMAGNETIC WAVE EMISSION; EMISSION SPECTROSCOPY; FLUORESCENCE; FURAN RESINS; HYDROGEN BONDS; MIXTURES; ORGANIC SOLVENTS;

EXCIPLEX; MULTI-COMPONENT SOLVENTS; POLAR EFFECT; SOLVENT EFFECT;

NAPHTHALENE;

EID: 25444462463     PISSN: 10530509     EISSN: None     Source Type: Journal    
DOI: 10.1007/s10895-005-2820-z     Document Type: Article

References (22)

1. H. Knibbe, D. Rehm, and A. Weller (1968). Intermediates and kinetics of fluorescence quenching by electron transfer. Ber: Bunsen-Ges, Phys. Chem. 72, 257-263.
2. E. A. Chandross and H. T. Thomas (1971). Intramolecular exciplex formation in naphthylalkylamines. Chem. Phys. Lett. 9, 393-396.
3. M. M. Hui and W. R. Ware (1976). Exciplex photophysics. IV Effect of diffusion-controlled quenching on exciplex photokinetics. J. Am. Chem. Soc. 98, 4712-4717.
4. A.M. Halpern (1984). Energetics of intramolecular photoassociation in 3-phenyl-1-(dimethylamino)propane in the vapor phase. J. Am. Chem. Soc. 106, 6484-6489.
5. A. M. Swinnen, M. Van der Auweraer, and F. C. De Schryver (1985). On the electronic structure of exciplexes in d-(1- or 2-naphthyl)-ω-N,N- dialkylaminoalkanes. J. Photochem. 28, 315-327.
6. S. Matsuzawa, M. Lamotte, P. Garrigues, and Y. Shimizu (1994). Naphthalene-amines exciplex formation promoted by phase transition in crystallized cycrohexane. J. Phys. Chem. 98, 7832-7836.
7. D. P. Andrews, G. S. Beddard, and B. J. Whitaker (2000). Charge-transfer formation and geometry of the naphthalene-trimethylamine van der Waals complex. J. Phys. Chem. A 104, 7785-7792.
8. S. P. Van and G. S. Hammond (1978). Amine quenching of aromatic fluorescence and fluorescent exciplexes. J. Am. Chem. Soc. 100, 3895-3902.
9. A. T. Amos and B. L. Burroughs (1973). Solvent-shift effects on electronic spectra and excited-state dipole moments and polarizabilities. Adv. Quan. Chem. 7, 289-313.
10. A. M. Halpern and S. L. Frye (1988). Solvent and substituent effects on intermolecular electronic energy transfer between saturated amines and benzene; Evidence of exciplex intermediates. J. Phys. Chem. 92, 6620-6625.
11. S. Oh and Y. Shirota (1995). The effect of intermolecular hydrogen bonding on the photoinduced electron transfer reaction of a naphthalene- triethylamine-alcohol system: estimation of the equilibrium constant for hydrogen bond formation from fluorescence quenching and reaction pathways. J. Photochem. Photobiol., A 92, 79-83.
12. S. Oh, Y. Shirota, H. Mikawa, and S. Kusabayashi (1986). The effect of the hydrogen bonding on the photoinduced electron transfer reaction of a naphthalene-triethylamine system in the presence of alcohols. Chem. Lett. 12, 2121-2124.
13. S. Yamamoto, G. Xie, M. Nakamura, and Y. Sueishi (2002). Effects of 1-butanol on emission spectrum of 4-phenyl-1-N,N-dimethylaminobutane in THF: Separation into polar and hydrogen-bonding interactions. Chem. Lett. 7, 760-761.
14. G. Xie, M. Nakamura, Y. Sueishi, and S. Yamamoto (2004). Separation into polar and hydrogen-bonding factors of the effects of alcohols on the emission spectrum of 4-phenyl-1-N,N-dimethylaminobutane. J. Photochem. Photobiol., A 162, 73-79.
15. G. Xie, Y. Sueishi, and S. Yamamoto (2004). Effects of alcohols on emission spectra of toluene-triethylamine mixtures in THF: separation into polar and hydrogen-bonding interactions. J. Photochem. Photobiol., A 162, 449-456.
16. M. Van der Auweraer, F. C. De Schryver, A. Gilbert, and S. Eilson (1979). Intramolecular exciplex formation in d-N-dialkylamino-ω-arylalkanes. Bull. Soc. Chem., Belg. 88, 227-232.
17. H. Knibbe, K. Rollig, and F. P. Schafer (1967). Charge-transfer complex and solvent-shared ion pair in fluorescence quenching. J. Chem. Phys. 47, 1184-1185.
18. G. Grabner, K. Rechthaler, B. Mayer, G. Kohler, and K. Rotkiewicz (2000). Solvent influences on the photophysics of naphthalene: Fluorescence and triplet state properties in aqueous solutions and in cyclodextrin complexes. J. Phys. Chem. A 104, 1365-1376.
19. C. Reichardt (2002). Solvents and solvent effects in organic chemistry, 3rd ed., Weinheim, Ch. 5.
20. J. G. Kirkwood (1934). Theory of solutions of molecules containing widely separated charges with special application to amphoteric ion. J. Chem. Phys. 2, 351-361.
21. M. G. Kuzmin and L. N. Guseva (1969). Donor-acceptor complexes of singlet excited states of aromatic hydrocarbons with aliphatic amines. Chem. Phys. Lett. 3, 71-72.
22. A. Weller (1982). Photoinduced electron transfer in solutions: Exciplex and radical ion pair formation free ebthalpies and their solvent dependence. Z. Phys. Chem., N. F. 133, 93-98.