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Volumn 55, Issue 4, 2005, Pages 251-258

Synthesis of poly(alcohol)s by hydroboration/oxidation of poly(methylallene) prepared by π-allylnickel-catalyzed living coordination polymerization

Author keywords

[No Author keywords available]

Indexed keywords

ALCOHOLS; CATALYSIS; LIVING POLYMERIZATION; MICROSTRUCTURE; MOLECULAR WEIGHT; NICKEL COMPOUNDS; OXIDATION; SYNTHESIS (CHEMICAL); THERMODYNAMIC PROPERTIES;

EID: 25444441073     PISSN: 01700839     EISSN: None     Source Type: Journal    
DOI: 10.1007/s00289-005-0435-9     Document Type: Article
Times cited : (11)

References (29)
  • 6
    • 0002770914 scopus 로고
    • Hydrogels for medical and related applications
    • American Chemical Society, Washington DC
    • (b) Andrade JD (1976) Hydrogels for Medical and Related Applications. ACS Symp Ser vol 31. American Chemical Society, Washington DC
    • (1976) ACS Symp ser , vol.31
    • Andrade, J.D.1
  • 24
    • 25444480351 scopus 로고    scopus 로고
    • note
    • The microstructure of the polymers from substituted allenes is controllable by the anionic ligands (X), neutral ligands (L), and the polymerization solvents. We would like to report the details in the forth-coming paper.
  • 25
    • 25444502454 scopus 로고    scopus 로고
    • note
    • If the polymer was isolated by precipitation without washing carefully by permeable membrane, the polymer became barely soluble in organic solvents probably by the cross-linking reaction between the hydroxy groups in the polymer and boric acid derivatives.
  • 26
    • 0000861153 scopus 로고
    • 3THF is known to give the anti-Markovnikov adducts in more than 98 % selectivity. Thus, the present polymer reactions are believed to proceed in an analogous selectivity, resulting in the preferential formation of less substituted alcohol units. See: Brown HC and Zweifel G (1960) J Am Chem Soc 82:4708.
    • (1960) J Am Chem Soc , vol.82 , pp. 4708
    • Brown, H.C.1    Zweifel, G.2
  • 27
    • 0000926031 scopus 로고
    • The result obtained here is in good accordance with the fact that α,α-disubstituted olefins are more susceptible than trisubstituted ones to the selective hydroboration reagents such as 9-BBN. See: (a) Brown HC, Liotta R, Scouten CG (1976) J Am Chem Soc 98:5297
    • (1976) J Am Chem Soc , vol.98 , pp. 5297
    • Brown, H.C.1    Liotta, R.2    Scouten, C.G.3


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.