Synthesis and characterization of hexaazamacrocyclic complexes with Co(II), Ni(II), Cu(II), and Zn(II) derived from phthalaldehyde and 2,6-diaminopyridine

Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry

Volumn 34, Issue 4, 2004, Pages 809-818

  Shakir, Mohammad ^a   Chishti, Hamida Tun Nisa ^a   Azim, Yasser ^a   Begum, Nishat ^a  

^a ALIGARH MUSLIM UNIVERSITY   (India)

Author keywords

2,6 Diaminopyridine; Hexaazamacrocyclic complexes; Methanol; Phthalaldehyde

Indexed keywords

2,6 DIAMINOPYRIDINE; COBALT COMPLEX; COPPER COMPLEX; MACROCYCLIC COMPOUND; METHANOL; NICKEL COMPLEX; PHTHALALDEHYDE; SOLVENT; ZINC COMPLEX;

ARTICLE; CHEMICAL ANALYSIS; CHEMICAL STRUCTURE; COMPLEX FORMATION; CONDUCTANCE; ELECTRON SPIN RESONANCE; GEOMETRY; INFRARED SPECTROMETRY; MAGNETISM; POLYMERIZATION; PROTON NUCLEAR MAGNETIC RESONANCE; ROOM TEMPERATURE; STRUCTURE ANALYSIS; SYNTHESIS; TEMPERATURE DEPENDENCE; ULTRAVIOLET SPECTROPHOTOMETRY;

EID: 2542572599     PISSN: 00945714     EISSN: None     Source Type: Journal    
DOI: 10.1081/SIM-120035959     Document Type: Article

References (33)

1. Timken, M.D.; Marritt, W.A.; Hendrickson, D.N.; Gagne, R.A.; Sinn, E. Magnetic exchange interactions in binuclear transition-metal complexes of a binucleating clathrochelate ligand. Inorg. Chem. 1985, 24, 4202-4203.
2. Kim, W.D.; Hrncir, D.C.; Kiefer, G.E.; Sherry, A.D. Synthesis, crystal structure, and potentiometry of pyridine-containing tetraazamacrocyclic ligands with acetate pendant arms. Inorg. Chem. 1995, 34, 2225-2232.
3. Kim, W.D.; Kiefer, G.E.; Maton, F.; McMillan, K.; Muller, R.N.; Sherry, A.D. Relaxometry, luminescence measurements, electrophoresis, and animal biodistribution of lanthanide(III) complexes of some polyaza macroecyclic acetates containing pyridine. Inorg. Chem. 1995, 34, 2233-2243.
4. Cabbiness, D.K.; Margerum, D.W. Effect of macrocyclic structures on the rate of formation and dissociation of copper(II) complexes. J. Am. Chem. Soc. 1970, 92, 2151-2153.
5. Cabbiness, D.K.; Margerum, D.W. Macrocyclic effect on the stability of copper(II) tetramine complexes. J. Am. Chem. Soc. 1969, 97, 6540-6541.
6. Baran, Y.; Bayada, A.; Lawrance, G.A.; Lye, P.G.; Maeder, M.; Wilkes, E.N. Comparative study for metal ions with tetrazamacrocycles of various ring sizes carrying a single amine or carboxylate pendant group. Transit. Met. Chem. 2003, 28 (4), 460-463.
7. Liu, J.; Zhang, H.; Chen, C.; Deng, H.; Lu, T.; Ji, L. Interaction of macrocyclic copper(II) complexes with calf thymus DNA: effects of the side chains of the ligands on the DNA-binding behaviours. Dalton Trans. 2003, 1, 114-119.
8. 3OH synthesis, crystal structure and magnetic properties (MAC = pentaaza macrocyclic ligand). Polyhedron 2003, 22 (10), 1315-1320.
9. Zhang, L.; Tang, N.; Wu, J.C.; Tan, M.U.; Wang, Q.; Han, Y. Synthesis, characterization, and biological activities of 3.5-dibenzyloxybenzoyl hydrozone and its complexes with some transition metals. Synth. React. Inorg. Met.-Org. Chem. 2003, 33 (5), 847-856.
10. Busch, D.H. Distinctive coordination chemistry and biological significance of complexes with macrocyclic ligands. Acc. Chem. Res. 1978, 77, 392-401.
11. Lindoy, L.F. Transition metal complexes of synthetic macrocyclic ligands. Chem. Soc. Rev. 1975, 4, 421-441.
12. Christensen, J.J.; Eatough, D.J.; Izatt, R.M. The synthesis and ion binding of synthetic muttidentate macrocyclic compounds. Chem. Rev. 1974, 74, 351-384.
13. Rodgers, S.J.; Ng, C.Y.; Raymond, K.N. High-dilution synthesis of macrocyclic polycatecholates. J. Am. Chem. Soc. 1985, 707, 4094-4095.
14. Carvalho, J.F.; Kim, S.H.; Chang, C.A. Synthesis and metal complex selectivity of macrocyclic DTPA and EDTA bis(amide) ligands. Inorg. Chem. 1992, 37, 4065.
15. 6-tetradentate macrocyclic ligand. J. Indian Chem. Soc. 1989, 66 (4), 266-267.
16. Chaudhary, A.; Dave, S.; Swaroop, R.; Singh, R.V. Biologically active macrocyclic complexes of divalent tin. Indian J. Chem. 2002, 40A, 757-759.
17. Berezina, G.R.; Vorobev, Y.G.; Smirnov, R.P. Kinetics of formation of metal complexes of conjugated macrocycleshetro in pyridine. Zh. Org. Khim. 1993, 29 (2), 396-399; Chem. Abstr. 1994, 720, 201533w.
18. Berezina, G.R.; Vorobev, Y.G.; Smirnov, R.P. Kinetics of formation of metal complexes of conjugated macrocycleshetro in pyridine. Zh. Org. Khim. 1993, 29 (2), 396-399; Chem. Abstr. 1994, 720, 201533w.
19. 6 22-membered macrocyclic transition metal complexes: synthesis and characterization. Polyhedron 1996, 75 (2), 309-314.
20. Onozawaa, S.Y.; Sakakuraa, T.; Tanaka, M.; Shirob, M. Lanthanoid catalysed tischhenko reaction of mono- or di-aldehydes. Tetrahedron 1996, 52(12), 4291-4302.
21. Shakir, M.; Mohamed, A.K.; Varkey, S.P.; Nasman, O.S.M. Synthesis and structural studies of bis(macrocyclic) dimetal(II) complexes based on 14-18 membered pentaaza unit. Indian J. Chem. 1996, 35A, 935-939.
22. Colak, A.T.; Tumer, M.; Serin, S. Nickel ion as a template in the synthesis of macrocyclic imine-oxime complexes from carbonyl compounds and Q-phenylene-diamine. Transit. Met. Chem. 2000, 25 (2), 200-204.
23. Reilley, C.N.; Schmid, R.W.; Sadek, F.S. Chelon approach to analysis(II) illustrative experiments. J. Chem. Ed. 1959, 36, 619-626.
24. Vogel, A.I. A Text Book of Quantitative Inorganic Analysis, 3rd Ed.; Longmans: London, 1961; 433-434.
25. Geary, W.J. Use of conductivity measurements in organic solvents for the characterization of coordination compounds. Coord. Chem. Rev. 1971, 7(1), 81-122.
26. Rana, V.B.; Singh, P.; Singh, D.P.; Teotia, M.P. Divalent nickel, cobalt and copper complexes of tetradenatate macrocycle, dibenzo-(f,n)-2,4, 10,12-tetramethyl-1,5,9,13-tetraazacyclohexadeca-[16]-1,3,9,11-tetraene. Polyhedron 1982, 1 (4), 377-381.
27. Clark, R.J.H.; Williams, C.S. The far-infrared spectra of metal-halide complexes of pyridine and related ligands. Inorg. Chem. 1965, 4, 350-357.
28. Shakir, M.; Varkey, S.P. Synthesis and structural characterization of cobalt(II), nickel(II) and copper(II) complexes of 18-membered mixed-donor macrocycles. Polyhedron 1994, 13, 791-797.
29. Lever, A.B.P. Inorganic Electronic Spectroscopy, 2nd Ed.; Elsevier: Amsterdam, 1984; 318-357.
30. Jain, M.C.; Srivastava, A.K.; Jain, P.C. Some tetragonally distorted copper(II) complexes of 4-benzylamidothiosemicarbonide and its thiosemicarbazone. Inorg. Chim. Acta 1977, 23, 199-203.
31. Proctor, I.M.; Hathaway, B.J.; Nicholls, P. The electronic properties and stereochemistry of the copper(II) ion. Part I. Bis(ethylenediamine) copper(11) complexes. J. Chem. Soc. A 1968, 96, 1678-1684.
32. Beer, P.D.; Crane, C.G.; Drew, M.G.B. Synthesis and co-ordination chemistry of new Schiff-base bis(crown ether) ligands containing recognition sites for alkali and transition metal guest cations. Crystal structure of a copper(I)-potassium complex. J. Chem. Soc. Dalton. Trans. 1991, 96, 3235-3242.
33. Bailey, N.A.; Barbarin, R.D.; Fenton, D.E.; Hellier, P.C.; Hampstead, P.D.; Kanesato, M.; Leason, P.B. Attempted functionalization of a mononuclear barium complex of a 24-memberecd bibracchial tetraimine schiff base macrocycle derived from tris(2-aminoethyl)amine using salicylaldehyde. J. Chem. Soc. Dalton. Trans. 1995, 1, 765-770.