Observation of the symmetry-forbidden 5σu → kσu CS2 transition: A vibrationally driven photoionization resonance

Physical Review Letters

Volumn 92, Issue 14, 2004, Pages

  Rathbone, G J ^a,d   Poliakoff, E D ^a   Bozek, John D ^b   Lucchese, R R ^c  

^a LOUISIANA STATE UNIVERSITY   (United States)

^b LAWRENCE BERKELEY NATIONAL LABORATORY   (United States)

^c TEXAS A AND M UNIVERSITY   (United States)

^d UNIVERSITY OF COLORADO   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

DEGREES OF FREEDOM (MECHANICS); ELECTRON TRANSITIONS; LATTICE VIBRATIONS; MOLECULAR STRUCTURE; PHOTOELECTRON SPECTROSCOPY; PHOTOIONIZATION; RESONANCE; X RAY SPECTROSCOPY;

ANTISYMMETRIC STRETCHING VIBRATIONS; FRANCK-CONDON BREAKDOWN; ORBITALS; SCHWINGER CALCULATIONS;

CESIUM COMPOUNDS;

EID: 2542448585     PISSN: 00319007     EISSN: None     Source Type: Journal    
DOI: 10.1103/PhysRevLett.92.143002     Document Type: Article

References (29)

1. J. L. Dehmer, J. Chem. Phys. 56, 4496 (1972).
2. J. L. Dehmer, D. Dill, and S. Wallace, Phys. Rev. Lett. 43, 1005 (1979).
3. J. B. West, A. C. Parr, B. E. Cole, D. L. Ederer, R. Stockbauer, and J. L. Dehmer, J. Phys. B 13, L105 (1980).
4. M. N. Piancastelli, D. W. Lindle, T. A. Ferrett, and D. A. Shirley, J. Chem. Phys. 86, 2765 (1987).
5. J. A. Sheehy, T. J. Gil, C. L. Winstead, R. E. Farren, and P.W. Langhoff, J. Chem. Phys. 91, 1796 (1989).
6. J. Stohr, F. Sette, and A. L. Johnson, Phys. Rev. Lett. 53, 1684 (1984).
7. L. A. Kelly, L. M. Duffy, B. Space, E. D. Poliakoff, P. Roy, S. H. Southworth, and M. G. White, J. Chem. Phys. 90, 1544 (1989).
8. J. S. Miller, E. D. Poliakoff, T. F. Miller, A. P. P. Natalense, and R. R. Lucchese, J. Chem. Phys. 114, 4496 (2001).
9. G. J. Rathbone, E. D. Poliakoff, J. D. Bozek, and R. R. Lucchese, J. Chem. Phys. 114, 8240 (2001).
10. G. J. Rathbone, E. D. Poliakoff, J. D. Bozek, R. R. Lucchese, and P. Lin, J. Chem. Phys. 120, 612 (2004).
11. J. Stohr, NEXAFS Spectroscopy (Springer-Verlag, Berlin, 1992).
12. G. Ohrwall, J. Bozek, and P. Baltzer, J. Electron Spectrosc. Relat. Phenom. 104, 209 (1999).
13. D. M. Chase, Phys. Rev. 104, 838 (1956).
14. H.-J. Werner and P. J. Knowles, MOLPRO (University of Birmingham, Birmingham, 2000).
15. T. H. Dunning, J. Chem. Phys. 90, 1007 (1989).
16. R. A. Kendall, T. H. Dunning, and R. J. Harrison, J. Chem. Phys. 96, 6796 (1992).
17. D. E. Woon and T. H. Dunning, J. Chem. Phys. 98, 1358 (1993).
18. R. E. Stratmann and R. R. Lucchese, J. Chem. Phys. 102, 8493 (1995).
19. R. E. Stratmann, R. W. Zurales, and R. R. Lucchese, J. Chem. Phys. 104, 8989 (1996).
20. A. P. P. Natalense and R. R. Lucchese, J. Chem. Phys. 111, 5344 (1999).
21. L. S. Wang, J. E. Reutt, Y. T. Lee, and D. A. Shirley, J. Electron Spectrosc. Relat. Phenom. 47, 167 (1988).
22. J. B. Liu, M. Hochlaf, and C. Y. Ng, J. Chem. Phys. 118, 4487 (2003).
23. P. Roy, R. J. Bartlett, W. J. Trela, T. A. Ferrett, A. C. Parr, S. H. Southworth, J. E. Hardis, V. Schmidt, and J. L. Dehmer, J. Chem. Phys. 94, 949 (1991).
24. R. E. Stratmann and R. L. Lucchese, J. Chem. Phys. 101, 9548 (1994).
25. T. A. Carlson, M. O. Krause, F. A. Grimm, J. D. Allen, D. Mehaffy, P. R. Keller, and J. W. Taylor, J. Chem. Phys. 75, 3288 (1981).
26. F. A. Gianturco and R. R. Lucchese, J. Chem. Phys. 111, 6769 (1999).
27. E. D. Poliakoff, J. L. Dehmer, D. Dill, A. C. Parr, K. H. Jackson, and R. N. Zare, Phys. Rev. Lett. 46, 907 (1981).
28. G. J. Rathbone, E. D. Poliakoff, J. D. Bozek, and R. R. Lucchese (to be published).
29. 10~ M. Braunstein and V. McKoy, J. Chem. Phys. 92, 4887 (1990).