Organometallics versus P4 complexes of group 11 cations: Periodic trends and relativistic effects in the involvement of (n-1)d, ns, and np orbitals in metal-ligand interactions

Organometallics

Volumn 23, Issue 10, 2004, Pages 2343-2349

  Tai, Hui Chung ^a   Krossing, Ingo ^b   Seth, Michael ^c   Deubel, Dirk V ^d  

^a ACADEMIA SINICA   (Taiwan)

^b UNIVERSITY OF KARLSRUHE   (Germany)

^c UNIVERSITY OF CALGARY   (Canada)

^d ETH ZURICH   (Switzerland)

Author keywords

[No Author keywords available]

Indexed keywords

BONDING; CARRIER CONCENTRATION; CHEMICAL BONDS; COMPLEXATION; ELECTROSTATICS; EXTRAPOLATION; OPTIMIZATION; PHOSPHORUS; POSITIVE IONS; PROBABILITY DENSITY FUNCTION; SYNTHESIS (CHEMICAL);

BOND ENERGIES; ISOLOBALITY PRINCIPLES; LIGAND ORBITALS; METAL-LIGAND INTERACTIONS;

ORGANOMETALLICS;

EID: 2542436867     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om034246z     Document Type: Article

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78. Recent examples: (a) Diefenbach, A.; Bickelhaupt, F. M.; Frenking, G. J. Am. Chem. Soc. 2000, 122, 6449. (b) Bickelhaupt, F. M.; DeKock, R. L.; Baerends, E. J. J. Am. Chem. Soc. 2002, 124, 1500. (c) Deubel, D. V. J. Am. Chem. Soc. 2002, 124, 5834. (d) Guerra, C. F.; Bickelhaupt, F. M. Angew. Chem., Int. Ed. 2002, 41, 2012. (e) Deubel, D. V.; Ziegler, T. Organometallics 2002, 21, 1603. (f) Cases, M.; Frenking, G.; Duran, M.; Solà, M. Organometallics 2002, 21, 4182. (g) Deubel, D. V. Organometallics 2002, 21, 4303. (h) Deubel, D. V.; Ziegler, T. Organometallics 2002, 21, 4432. (i) Nemcsok, D. S.; Kovács, A.; Rayón, V. M.; Frenking, G. Organometallics 2002, 21, 5803. (j) Pandey, K. K.; Lein, M.; Frenking, G. J. Am. Chem. Soc. 2003, 125, 1660. (k) Lein, M.; Frunzke, J.; Frenking, G. Angew. Chem., Int. Ed. 2003, 42, 1303. (l) Esterhuysen, C.; Frenking, G. Chem. Eur. J. 2003, 9, 3518. (m) Massera, C.; Frenking, G. Organometallics 2003, 22, 2758. (n) Rayón, V. M.; Frenking, G. Organometallics 2003, 22, 3304. (o) Lein, M.; Frunzke, J.; Frenking, G. Inorg. Chem. 2003, 42, 2504. (p) Dietz, O.; Rayón, V. M.; Frenking, G. Inorg. Chem. 2003, 42, 4977.
79. Recent examples: (a) Diefenbach, A.; Bickelhaupt, F. M.; Frenking, G. J. Am. Chem. Soc. 2000, 122, 6449. (b) Bickelhaupt, F. M.; DeKock, R. L.; Baerends, E. J. J. Am. Chem. Soc. 2002, 124, 1500. (c) Deubel, D. V. J. Am. Chem. Soc. 2002, 124, 5834. (d) Guerra, C. F.; Bickelhaupt, F. M. Angew. Chem., Int. Ed. 2002, 41, 2012. (e) Deubel, D. V.; Ziegler, T. Organometallics 2002, 21, 1603. (f) Cases, M.; Frenking, G.; Duran, M.; Solà, M. Organometallics 2002, 21, 4182. (g) Deubel, D. V. Organometallics 2002, 21, 4303. (h) Deubel, D. V.; Ziegler, T. Organometallics 2002, 21, 4432. (i) Nemcsok, D. S.; Kovács, A.; Rayón, V. M.; Frenking, G. Organometallics 2002, 21, 5803. (j) Pandey, K. K.; Lein, M.; Frenking, G. J. Am. Chem. Soc. 2003, 125, 1660. (k) Lein, M.; Frunzke, J.; Frenking, G. Angew. Chem., Int. Ed. 2003, 42, 1303. (l) Esterhuysen, C.; Frenking, G. Chem. Eur. J. 2003, 9, 3518. (m) Massera, C.; Frenking, G. Organometallics 2003, 22, 2758. (n) Rayón, V. M.; Frenking, G. Organometallics 2003, 22, 3304. (o) Lein, M.; Frunzke, J.; Frenking, G. Inorg. Chem. 2003, 42, 2504. (p) Dietz, O.; Rayón, V. M.; Frenking, G. Inorg. Chem. 2003, 42, 4977.
80. Recent examples: (a) Diefenbach, A.; Bickelhaupt, F. M.; Frenking, G. J. Am. Chem. Soc. 2000, 122, 6449. (b) Bickelhaupt, F. M.; DeKock, R. L.; Baerends, E. J. J. Am. Chem. Soc. 2002, 124, 1500. (c) Deubel, D. V. J. Am. Chem. Soc. 2002, 124, 5834. (d) Guerra, C. F.; Bickelhaupt, F. M. Angew. Chem., Int. Ed. 2002, 41, 2012. (e) Deubel, D. V.; Ziegler, T. Organometallics 2002, 21, 1603. (f) Cases, M.; Frenking, G.; Duran, M.; Solà, M. Organometallics 2002, 21, 4182. (g) Deubel, D. V. Organometallics 2002, 21, 4303. (h) Deubel, D. V.; Ziegler, T. Organometallics 2002, 21, 4432. (i) Nemcsok, D. S.; Kovács, A.; Rayón, V. M.; Frenking, G. Organometallics 2002, 21, 5803. (j) Pandey, K. K.; Lein, M.; Frenking, G. J. Am. Chem. Soc. 2003, 125, 1660. (k) Lein, M.; Frunzke, J.; Frenking, G. Angew. Chem., Int. Ed. 2003, 42, 1303. (l) Esterhuysen, C.; Frenking, G. Chem. Eur. J. 2003, 9, 3518. (m) Massera, C.; Frenking, G. Organometallics 2003, 22, 2758. (n) Rayón, V. M.; Frenking, G. Organometallics 2003, 22, 3304. (o) Lein, M.; Frunzke, J.; Frenking, G. Inorg. Chem. 2003, 42, 2504. (p) Dietz, O.; Rayón, V. M.; Frenking, G. Inorg. Chem. 2003, 42, 4977.
81. Recent examples: (a) Diefenbach, A.; Bickelhaupt, F. M.; Frenking, G. J. Am. Chem. Soc. 2000, 122, 6449. (b) Bickelhaupt, F. M.; DeKock, R. L.; Baerends, E. J. J. Am. Chem. Soc. 2002, 124, 1500. (c) Deubel, D. V. J. Am. Chem. Soc. 2002, 124, 5834. (d) Guerra, C. F.; Bickelhaupt, F. M. Angew. Chem., Int. Ed. 2002, 41, 2012. (e) Deubel, D. V.; Ziegler, T. Organometallics 2002, 21, 1603. (f) Cases, M.; Frenking, G.; Duran, M.; Solà, M. Organometallics 2002, 21, 4182. (g) Deubel, D. V. Organometallics 2002, 21, 4303. (h) Deubel, D. V.; Ziegler, T. Organometallics 2002, 21, 4432. (i) Nemcsok, D. S.; Kovács, A.; Rayón, V. M.; Frenking, G. Organometallics 2002, 21, 5803. (j) Pandey, K. K.; Lein, M.; Frenking, G. J. Am. Chem. Soc. 2003, 125, 1660. (k) Lein, M.; Frunzke, J.; Frenking, G. Angew. Chem., Int. Ed. 2003, 42, 1303. (l) Esterhuysen, C.; Frenking, G. Chem. Eur. J. 2003, 9, 3518. (m) Massera, C.; Frenking, G. Organometallics 2003, 22, 2758. (n) Rayón, V. M.; Frenking, G. Organometallics 2003, 22, 3304. (o) Lein, M.; Frunzke, J.; Frenking, G. Inorg. Chem. 2003, 42, 2504. (p) Dietz, O.; Rayón, V. M.; Frenking, G. Inorg. Chem. 2003, 42, 4977.
82. Recent examples: (a) Diefenbach, A.; Bickelhaupt, F. M.; Frenking, G. J. Am. Chem. Soc. 2000, 122, 6449. (b) Bickelhaupt, F. M.; DeKock, R. L.; Baerends, E. J. J. Am. Chem. Soc. 2002, 124, 1500. (c) Deubel, D. V. J. Am. Chem. Soc. 2002, 124, 5834. (d) Guerra, C. F.; Bickelhaupt, F. M. Angew. Chem., Int. Ed. 2002, 41, 2012. (e) Deubel, D. V.; Ziegler, T. Organometallics 2002, 21, 1603. (f) Cases, M.; Frenking, G.; Duran, M.; Solà, M. Organometallics 2002, 21, 4182. (g) Deubel, D. V. Organometallics 2002, 21, 4303. (h) Deubel, D. V.; Ziegler, T. Organometallics 2002, 21, 4432. (i) Nemcsok, D. S.; Kovács, A.; Rayón, V. M.; Frenking, G. Organometallics 2002, 21, 5803. (j) Pandey, K. K.; Lein, M.; Frenking, G. J. Am. Chem. Soc. 2003, 125, 1660. (k) Lein, M.; Frunzke, J.; Frenking, G. Angew. Chem., Int. Ed. 2003, 42, 1303. (l) Esterhuysen, C.; Frenking, G. Chem. Eur. J. 2003, 9, 3518. (m) Massera, C.; Frenking, G. Organometallics 2003, 22, 2758. (n) Rayón, V. M.; Frenking, G. Organometallics 2003, 22, 3304. (o) Lein, M.; Frunzke, J.; Frenking, G. Inorg. Chem. 2003, 42, 2504. (p) Dietz, O.; Rayón, V. M.; Frenking, G. Inorg. Chem. 2003, 42, 4977.
83. Recent examples: (a) Diefenbach, A.; Bickelhaupt, F. M.; Frenking, G. J. Am. Chem. Soc. 2000, 122, 6449. (b) Bickelhaupt, F. M.; DeKock, R. L.; Baerends, E. J. J. Am. Chem. Soc. 2002, 124, 1500. (c) Deubel, D. V. J. Am. Chem. Soc. 2002, 124, 5834. (d) Guerra, C. F.; Bickelhaupt, F. M. Angew. Chem., Int. Ed. 2002, 41, 2012. (e) Deubel, D. V.; Ziegler, T. Organometallics 2002, 21, 1603. (f) Cases, M.; Frenking, G.; Duran, M.; Solà, M. Organometallics 2002, 21, 4182. (g) Deubel, D. V. Organometallics 2002, 21, 4303. (h) Deubel, D. V.; Ziegler, T. Organometallics 2002, 21, 4432. (i) Nemcsok, D. S.; Kovács, A.; Rayón, V. M.; Frenking, G. Organometallics 2002, 21, 5803. (j) Pandey, K. K.; Lein, M.; Frenking, G. J. Am. Chem. Soc. 2003, 125, 1660. (k) Lein, M.; Frunzke, J.; Frenking, G. Angew. Chem., Int. Ed. 2003, 42, 1303. (l) Esterhuysen, C.; Frenking, G. Chem. Eur. J. 2003, 9, 3518. (m) Massera, C.; Frenking, G. Organometallics 2003, 22, 2758. (n) Rayón, V. M.; Frenking, G. Organometallics 2003, 22, 3304. (o) Lein, M.; Frunzke, J.; Frenking, G. Inorg. Chem. 2003, 42, 2504. (p) Dietz, O.; Rayón, V. M.; Frenking, G. Inorg. Chem. 2003, 42, 4977.
84. Recent examples: (a) Diefenbach, A.; Bickelhaupt, F. M.; Frenking, G. J. Am. Chem. Soc. 2000, 122, 6449. (b) Bickelhaupt, F. M.; DeKock, R. L.; Baerends, E. J. J. Am. Chem. Soc. 2002, 124, 1500. (c) Deubel, D. V. J. Am. Chem. Soc. 2002, 124, 5834. (d) Guerra, C. F.; Bickelhaupt, F. M. Angew. Chem., Int. Ed. 2002, 41, 2012. (e) Deubel, D. V.; Ziegler, T. Organometallics 2002, 21, 1603. (f) Cases, M.; Frenking, G.; Duran, M.; Solà, M. Organometallics 2002, 21, 4182. (g) Deubel, D. V. Organometallics 2002, 21, 4303. (h) Deubel, D. V.; Ziegler, T. Organometallics 2002, 21, 4432. (i) Nemcsok, D. S.; Kovács, A.; Rayón, V. M.; Frenking, G. Organometallics 2002, 21, 5803. (j) Pandey, K. K.; Lein, M.; Frenking, G. J. Am. Chem. Soc. 2003, 125, 1660. (k) Lein, M.; Frunzke, J.; Frenking, G. Angew. Chem., Int. Ed. 2003, 42, 1303. (l) Esterhuysen, C.; Frenking, G. Chem. Eur. J. 2003, 9, 3518. (m) Massera, C.; Frenking, G. Organometallics 2003, 22, 2758. (n) Rayón, V. M.; Frenking, G. Organometallics 2003, 22, 3304. (o) Lein, M.; Frunzke, J.; Frenking, G. Inorg. Chem. 2003, 42, 2504. (p) Dietz, O.; Rayón, V. M.; Frenking, G. Inorg. Chem. 2003, 42, 4977.
85. Recent examples: (a) Diefenbach, A.; Bickelhaupt, F. M.; Frenking, G. J. Am. Chem. Soc. 2000, 122, 6449. (b) Bickelhaupt, F. M.; DeKock, R. L.; Baerends, E. J. J. Am. Chem. Soc. 2002, 124, 1500. (c) Deubel, D. V. J. Am. Chem. Soc. 2002, 124, 5834. (d) Guerra, C. F.; Bickelhaupt, F. M. Angew. Chem., Int. Ed. 2002, 41, 2012. (e) Deubel, D. V.; Ziegler, T. Organometallics 2002, 21, 1603. (f) Cases, M.; Frenking, G.; Duran, M.; Solà, M. Organometallics 2002, 21, 4182. (g) Deubel, D. V. Organometallics 2002, 21, 4303. (h) Deubel, D. V.; Ziegler, T. Organometallics 2002, 21, 4432. (i) Nemcsok, D. S.; Kovács, A.; Rayón, V. M.; Frenking, G. Organometallics 2002, 21, 5803. (j) Pandey, K. K.; Lein, M.; Frenking, G. J. Am. Chem. Soc. 2003, 125, 1660. (k) Lein, M.; Frunzke, J.; Frenking, G. Angew. Chem., Int. Ed. 2003, 42, 1303. (l) Esterhuysen, C.; Frenking, G. Chem. Eur. J. 2003, 9, 3518. (m) Massera, C.; Frenking, G. Organometallics 2003, 22, 2758. (n) Rayón, V. M.; Frenking, G. Organometallics 2003, 22, 3304. (o) Lein, M.; Frunzke, J.; Frenking, G. Inorg. Chem. 2003, 42, 2504. (p) Dietz, O.; Rayón, V. M.; Frenking, G. Inorg. Chem. 2003, 42, 4977.
86. Recent examples: (a) Diefenbach, A.; Bickelhaupt, F. M.; Frenking, G. J. Am. Chem. Soc. 2000, 122, 6449. (b) Bickelhaupt, F. M.; DeKock, R. L.; Baerends, E. J. J. Am. Chem. Soc. 2002, 124, 1500. (c) Deubel, D. V. J. Am. Chem. Soc. 2002, 124, 5834. (d) Guerra, C. F.; Bickelhaupt, F. M. Angew. Chem., Int. Ed. 2002, 41, 2012. (e) Deubel, D. V.; Ziegler, T. Organometallics 2002, 21, 1603. (f) Cases, M.; Frenking, G.; Duran, M.; Solà, M. Organometallics 2002, 21, 4182. (g) Deubel, D. V. Organometallics 2002, 21, 4303. (h) Deubel, D. V.; Ziegler, T. Organometallics 2002, 21, 4432. (i) Nemcsok, D. S.; Kovács, A.; Rayón, V. M.; Frenking, G. Organometallics 2002, 21, 5803. (j) Pandey, K. K.; Lein, M.; Frenking, G. J. Am. Chem. Soc. 2003, 125, 1660. (k) Lein, M.; Frunzke, J.; Frenking, G. Angew. Chem., Int. Ed. 2003, 42, 1303. (l) Esterhuysen, C.; Frenking, G. Chem. Eur. J. 2003, 9, 3518. (m) Massera, C.; Frenking, G. Organometallics 2003, 22, 2758. (n) Rayón, V. M.; Frenking, G. Organometallics 2003, 22, 3304. (o) Lein, M.; Frunzke, J.; Frenking, G. Inorg. Chem. 2003, 42, 2504. (p) Dietz, O.; Rayón, V. M.; Frenking, G. Inorg. Chem. 2003, 42, 4977.
87. Recent examples: (a) Diefenbach, A.; Bickelhaupt, F. M.; Frenking, G. J. Am. Chem. Soc. 2000, 122, 6449. (b) Bickelhaupt, F. M.; DeKock, R. L.; Baerends, E. J. J. Am. Chem. Soc. 2002, 124, 1500. (c) Deubel, D. V. J. Am. Chem. Soc. 2002, 124, 5834. (d) Guerra, C. F.; Bickelhaupt, F. M. Angew. Chem., Int. Ed. 2002, 41, 2012. (e) Deubel, D. V.; Ziegler, T. Organometallics 2002, 21, 1603. (f) Cases, M.; Frenking, G.; Duran, M.; Solà, M. Organometallics 2002, 21, 4182. (g) Deubel, D. V. Organometallics 2002, 21, 4303. (h) Deubel, D. V.; Ziegler, T. Organometallics 2002, 21, 4432. (i) Nemcsok, D. S.; Kovács, A.; Rayón, V. M.; Frenking, G. Organometallics 2002, 21, 5803. (j) Pandey, K. K.; Lein, M.; Frenking, G. J. Am. Chem. Soc. 2003, 125, 1660. (k) Lein, M.; Frunzke, J.; Frenking, G. Angew. Chem., Int. Ed. 2003, 42, 1303. (l) Esterhuysen, C.; Frenking, G. Chem. Eur. J. 2003, 9, 3518. (m) Massera, C.; Frenking, G. Organometallics 2003, 22, 2758. (n) Rayón, V. M.; Frenking, G. Organometallics 2003, 22, 3304. (o) Lein, M.; Frunzke, J.; Frenking, G. Inorg. Chem. 2003, 42, 2504. (p) Dietz, O.; Rayón, V. M.; Frenking, G. Inorg. Chem. 2003, 42, 4977.
88. Recent examples: (a) Diefenbach, A.; Bickelhaupt, F. M.; Frenking, G. J. Am. Chem. Soc. 2000, 122, 6449. (b) Bickelhaupt, F. M.; DeKock, R. L.; Baerends, E. J. J. Am. Chem. Soc. 2002, 124, 1500. (c) Deubel, D. V. J. Am. Chem. Soc. 2002, 124, 5834. (d) Guerra, C. F.; Bickelhaupt, F. M. Angew. Chem., Int. Ed. 2002, 41, 2012. (e) Deubel, D. V.; Ziegler, T. Organometallics 2002, 21, 1603. (f) Cases, M.; Frenking, G.; Duran, M.; Solà, M. Organometallics 2002, 21, 4182. (g) Deubel, D. V. Organometallics 2002, 21, 4303. (h) Deubel, D. V.; Ziegler, T. Organometallics 2002, 21, 4432. (i) Nemcsok, D. S.; Kovács, A.; Rayón, V. M.; Frenking, G. Organometallics 2002, 21, 5803. (j) Pandey, K. K.; Lein, M.; Frenking, G. J. Am. Chem. Soc. 2003, 125, 1660. (k) Lein, M.; Frunzke, J.; Frenking, G. Angew. Chem., Int. Ed. 2003, 42, 1303. (l) Esterhuysen, C.; Frenking, G. Chem. Eur. J. 2003, 9, 3518. (m) Massera, C.; Frenking, G. Organometallics 2003, 22, 2758. (n) Rayón, V. M.; Frenking, G. Organometallics 2003, 22, 3304. (o) Lein, M.; Frunzke, J.; Frenking, G. Inorg. Chem. 2003, 42, 2504. (p) Dietz, O.; Rayón, V. M.; Frenking, G. Inorg. Chem. 2003, 42, 4977.
89. Recent examples: (a) Diefenbach, A.; Bickelhaupt, F. M.; Frenking, G. J. Am. Chem. Soc. 2000, 122, 6449. (b) Bickelhaupt, F. M.; DeKock, R. L.; Baerends, E. J. J. Am. Chem. Soc. 2002, 124, 1500. (c) Deubel, D. V. J. Am. Chem. Soc. 2002, 124, 5834. (d) Guerra, C. F.; Bickelhaupt, F. M. Angew. Chem., Int. Ed. 2002, 41, 2012. (e) Deubel, D. V.; Ziegler, T. Organometallics 2002, 21, 1603. (f) Cases, M.; Frenking, G.; Duran, M.; Solà, M. Organometallics 2002, 21, 4182. (g) Deubel, D. V. Organometallics 2002, 21, 4303. (h) Deubel, D. V.; Ziegler, T. Organometallics 2002, 21, 4432. (i) Nemcsok, D. S.; Kovács, A.; Rayón, V. M.; Frenking, G. Organometallics 2002, 21, 5803. (j) Pandey, K. K.; Lein, M.; Frenking, G. J. Am. Chem. Soc. 2003, 125, 1660. (k) Lein, M.; Frunzke, J.; Frenking, G. Angew. Chem., Int. Ed. 2003, 42, 1303. (l) Esterhuysen, C.; Frenking, G. Chem. Eur. J. 2003, 9, 3518. (m) Massera, C.; Frenking, G. Organometallics 2003, 22, 2758. (n) Rayón, V. M.; Frenking, G. Organometallics 2003, 22, 3304. (o) Lein, M.; Frunzke, J.; Frenking, G. Inorg. Chem. 2003, 42, 2504. (p) Dietz, O.; Rayón, V. M.; Frenking, G. Inorg. Chem. 2003, 42, 4977.
90. Recent examples: (a) Diefenbach, A.; Bickelhaupt, F. M.; Frenking, G. J. Am. Chem. Soc. 2000, 122, 6449. (b) Bickelhaupt, F. M.; DeKock, R. L.; Baerends, E. J. J. Am. Chem. Soc. 2002, 124, 1500. (c) Deubel, D. V. J. Am. Chem. Soc. 2002, 124, 5834. (d) Guerra, C. F.; Bickelhaupt, F. M. Angew. Chem., Int. Ed. 2002, 41, 2012. (e) Deubel, D. V.; Ziegler, T. Organometallics 2002, 21, 1603. (f) Cases, M.; Frenking, G.; Duran, M.; Solà, M. Organometallics 2002, 21, 4182. (g) Deubel, D. V. Organometallics 2002, 21, 4303. (h) Deubel, D. V.; Ziegler, T. Organometallics 2002, 21, 4432. (i) Nemcsok, D. S.; Kovács, A.; Rayón, V. M.; Frenking, G. Organometallics 2002, 21, 5803. (j) Pandey, K. K.; Lein, M.; Frenking, G. J. Am. Chem. Soc. 2003, 125, 1660. (k) Lein, M.; Frunzke, J.; Frenking, G. Angew. Chem., Int. Ed. 2003, 42, 1303. (l) Esterhuysen, C.; Frenking, G. Chem. Eur. J. 2003, 9, 3518. (m) Massera, C.; Frenking, G. Organometallics 2003, 22, 2758. (n) Rayón, V. M.; Frenking, G. Organometallics 2003, 22, 3304. (o) Lein, M.; Frunzke, J.; Frenking, G. Inorg. Chem. 2003, 42, 2504. (p) Dietz, O.; Rayón, V. M.; Frenking, G. Inorg. Chem. 2003, 42, 4977.
91. Recent examples: (a) Diefenbach, A.; Bickelhaupt, F. M.; Frenking, G. J. Am. Chem. Soc. 2000, 122, 6449. (b) Bickelhaupt, F. M.; DeKock, R. L.; Baerends, E. J. J. Am. Chem. Soc. 2002, 124, 1500. (c) Deubel, D. V. J. Am. Chem. Soc. 2002, 124, 5834. (d) Guerra, C. F.; Bickelhaupt, F. M. Angew. Chem., Int. Ed. 2002, 41, 2012. (e) Deubel, D. V.; Ziegler, T. Organometallics 2002, 21, 1603. (f) Cases, M.; Frenking, G.; Duran, M.; Solà, M. Organometallics 2002, 21, 4182. (g) Deubel, D. V. Organometallics 2002, 21, 4303. (h) Deubel, D. V.; Ziegler, T. Organometallics 2002, 21, 4432. (i) Nemcsok, D. S.; Kovács, A.; Rayón, V. M.; Frenking, G. Organometallics 2002, 21, 5803. (j) Pandey, K. K.; Lein, M.; Frenking, G. J. Am. Chem. Soc. 2003, 125, 1660. (k) Lein, M.; Frunzke, J.; Frenking, G. Angew. Chem., Int. Ed. 2003, 42, 1303. (l) Esterhuysen, C.; Frenking, G. Chem. Eur. J. 2003, 9, 3518. (m) Massera, C.; Frenking, G. Organometallics 2003, 22, 2758. (n) Rayón, V. M.; Frenking, G. Organometallics 2003, 22, 3304. (o) Lein, M.; Frunzke, J.; Frenking, G. Inorg. Chem. 2003, 42, 2504. (p) Dietz, O.; Rayón, V. M.; Frenking, G. Inorg. Chem. 2003, 42, 4977.
92. Recent examples: (a) Diefenbach, A.; Bickelhaupt, F. M.; Frenking, G. J. Am. Chem. Soc. 2000, 122, 6449. (b) Bickelhaupt, F. M.; DeKock, R. L.; Baerends, E. J. J. Am. Chem. Soc. 2002, 124, 1500. (c) Deubel, D. V. J. Am. Chem. Soc. 2002, 124, 5834. (d) Guerra, C. F.; Bickelhaupt, F. M. Angew. Chem., Int. Ed. 2002, 41, 2012. (e) Deubel, D. V.; Ziegler, T. Organometallics 2002, 21, 1603. (f) Cases, M.; Frenking, G.; Duran, M.; Solà, M. Organometallics 2002, 21, 4182. (g) Deubel, D. V. Organometallics 2002, 21, 4303. (h) Deubel, D. V.; Ziegler, T. Organometallics 2002, 21, 4432. (i) Nemcsok, D. S.; Kovács, A.; Rayón, V. M.; Frenking, G. Organometallics 2002, 21, 5803. (j) Pandey, K. K.; Lein, M.; Frenking, G. J. Am. Chem. Soc. 2003, 125, 1660. (k) Lein, M.; Frunzke, J.; Frenking, G. Angew. Chem., Int. Ed. 2003, 42, 1303. (l) Esterhuysen, C.; Frenking, G. Chem. Eur. J. 2003, 9, 3518. (m) Massera, C.; Frenking, G. Organometallics 2003, 22, 2758. (n) Rayón, V. M.; Frenking, G. Organometallics 2003, 22, 3304. (o) Lein, M.; Frunzke, J.; Frenking, G. Inorg. Chem. 2003, 42, 2504. (p) Dietz, O.; Rayón, V. M.; Frenking, G. Inorg. Chem. 2003, 42, 4977.
93. (a) Diefenbach, A.; Bickelhaupt, F. M. J. Chem. Phys. 2001, 115, 4030.
94. (b) Deubel, D. V. J. Phys. Chem. A 2001, 105, 4765.
95. (c) Deubel, D. V. J. Phys. Chem. A 2002, 106, 431.
96. (d) Deubel, D. V. J. Am. Chem. Soc. 2004, 126, 996.
97. (e) Deubel, D. V.; Muñiz, K. Chem. Eur. J. 2004, 10, in press.