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1
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25144446064
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note
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This research was supported by the Office of the Basic Energy Sciences, Materials Sciences Division, U. S. Department of Energy (DOE). The Ames Laboratory is operated for DOE by Iowa State University under Contract No. W-7405-Eng-82.
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4
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0003564296
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Kauzlarich, S., Ed.; VCH Publishers: New York, and references therein
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(c) Corbett, J. D. In Chemistry, Structure and Bonding of Zintl Phases and Ions; Kauzlarich, S., Ed.; VCH Publishers: New York, 1996 and references therein.
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Corbett, J.D.1
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Li, B.1
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16
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25144518022
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note
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Both compounds were synthesized from stoichiometric amounts of the elements in tantalum containers which were sealed by arc-welding under argon and enclosed in an evacuated silica tube. These were allowed to react at 650°C for 16 h before quenching, then at 300°C for 10 days, and slowly cooled (3°C/h) to room temperature. Both compounds have metallic luster and are air sensitive.
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19
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25144478668
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note
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14 The full-matrix least-squares refinement converged at R1/wR2 [I > 2σ(I)] = 0.0146/0.0344 and R1/wR2 (all data) = 0.0148/0.0344 with 180 reflections and 11 variables (see Supporting Information).
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21
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25144492496
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STOE and Cie GmbH; Hilpertstr: Darmstadt
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STOE WinXPOW 2.10, STOE and Cie GmbH; Hilpertstr: Darmstadt, 2004.
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STOE WinXPOW 2.10
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22
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0004150157
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Bruker AXS, Inc.: Madison, WI
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SHELXTL; Bruker AXS, Inc.: Madison, WI, 2000.
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(2000)
SHELXTL
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23
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25144507878
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note
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I = 0.0140, Rp = 0.0160, and Rwp = 0.0235. The graphical comparison between the observed and calculated powder patterns, and the refinement parameters are given in the Supporting Information.
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26
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0001711510
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(a) Yukro, G. A.; Barton, J. W.; Parr, J. G. Acta Crystallogr. 1959, 12, 909.
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Kaskel, S.1
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37
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25144513268
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note
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27
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38
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0040531371
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Max-Plank-Institut fur Festkorperforschung: Stuttgart, Germany
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van Schilfgarde, M.; Paxton, T. A.; Jepsen, O.; Andersen, O. K.; Krier, G. Program TB-LMTO; Max-Plank-Institut fur Festkorperforschung: Stuttgart, Germany, 1994.
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Program TB-LMTO
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Van Schilfgarde, M.1
Paxton, T.A.2
Jepsen, O.3
Andersen, O.K.4
Krier, G.5
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40
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25144488898
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note
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298 value is about 66.2 μΩ·cm (Supporting Information).
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