Novel HEXOL-type cyclometallated iridium(III) complexes: Stereoselective synthesis and structure elucidation

Chemical Communications

Volumn , Issue 33, 2005, Pages 4155-4157

  Yang, Liangru ^a   Von Zelewsky, Alex ^a   Stoeckli Evans, Helen ^b  

^a UNIVERSITY OF FRIBOURG   (Switzerland)

^b UNIVERSITY OF NEUCHÂTEL   (Switzerland)

Author keywords

[No Author keywords available]

Indexed keywords

IRIDIUM COMPLEX; LIGAND; PINENOPYRIDINE DERIVATIVE; PYRIDINE DERIVATIVE; UNCLASSIFIED DRUG;

ARTICLE; CHIRALITY; CRYSTAL STRUCTURE; ENANTIOMER; NUCLEAR MAGNETIC RESONANCE; STEREOCHEMISTRY; SYNTHESIS; X RAY CRYSTALLOGRAPHY;

EID: 25144452296     PISSN: 13597345     EISSN: None     Source Type: Journal    
DOI: 10.1039/b507769a     Document Type: Article

References (13)

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10. 3. This was assumed to be equivalent to 2 molecules of dichloromethane per molecule of complex. Certain C-atoms on the exterior of the molecule undergo higher thermal motion than those at the interior of the molecule. The atomic coordinates correspond to the absolute structure of the molecule in the crystal. § Flack parameter x = -0.018(5).
11. 3 per molecule of complex. Attempts to refine the C atoms anisotropically were unsuccessful. The crystal diffracted weakly beyond 40° in 2θ and only 42% of the data can be considered to be observed I > 2σ (I). The atomic coordinates correspond to the absolute structure of the molecule in the crystal, ¶ Flack parameter x = 0.013(15).
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