Excess molar enthalpies for mixtures of supercritical carbon dioxide and water + ethanol solutions

Journal of Supercritical Fluids

Volumn 36, Issue 1, 2005, Pages 23-30

  Pérez, Eduardo ^a   Sánchez Vicente, Yolanda ^a   Cabañas, Albertina ^a   Pando, Concepción ^a   Renuncio, Juan A R ^a  

^a UNIVERSIDAD COMPLUTENSE DE MADRID   (Spain)

Author keywords

Ethanol; Excess molar enthalpies; Mixtures; Supercritical carbon dioxide; Water

Indexed keywords

ENTHALPY; ETHANOL; MIXTURES; PHASE EQUILIBRIA; SOLUTIONS; TERNARY SYSTEMS; WATER;

BINARY SYSTEM; ETHANOL AQUEOUS SOLUTIONS; EXCESS MOLAR ENTHALPIES; SUPERCRITICAL CARBON DIOXIDES;

CARBON DIOXIDE;

EID: 24944498760     PISSN: 08968446     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.supflu.2005.03.006     Document Type: Article

References (30)

1. G. Brunner, and K. Kreim Separation of ethanol from aqueous solutions by gas extraction Ger. Chem. Eng. 9 1986 246
2. 2O system J. Chem. Eng. Jpn. 19 1986 48
3. E.A. Brignole, P.M. Andersen, and A. Fredeslund Supercritical fluid extraction of alcohols from water Ind. Eng. Chem. Res. 26 1987 254
4. 2 J. Chem. Eng. Jpn. 23 1990 199
5. L. Bernad, A. Keller, D. Barth, and M. Perrut Separation of ethanol from aqueous solutions by supercritical carbon dioxide - comparison between simulations and experiments J. Supercrit. Fluids 6 1993 9
6. N. Ikawa, Y. Nagase, T. Tada, S. Furuta, and R. Fukuzato Separation process of ethanol from aqueous solutions using supercritical carbon dioxide Fluid Phase Equilib. 83 1993 167
7. S. Yao, Y. Guan, and Z. Zhu Investigation of phase equilibrium for ternary systems containing ethanol, water and carbon dioxide at elevated pressures Fluid Phase Equilib. 99 1994 249
8. J.-H. Yoon, H. Lee, and B.H. Chung High pressure three-phase equilibria for the carbon dioxide-ethanol-water system Fluid Phase Equilib. 102 1994 287
9. J.S. Lim, Y.Y. Lee, and H.S. Chun Phase equilibria for carbon dioxide-ethanol-water system at elevated pressures J. Supercrit. Fluids 7 1994 219
10. J. Jung, and M. Perrut Particle design using supercritical fluids: literature and patent survey J. Supercrit. Fluids 20 2001 179
11. K. Ochi, W. Dai, Y. Wada, H. Hayashi, K. Kurihara, and K. Kojima Measurements and correlation of excess molar enthalpies for the systems containing supercritical carbon dioxide and alcohols Fluid Phase Equilib. 194-197 2002 919
12. J.B. Ott, C.E. Stouffer, G.V. Cornett, B.F. Woodfield, R.C. Wirthlin, and J.J. Christensen Excess enthalpies for (ethanol + water) at 298.15 K and pressures of 0.4, 5,10, and 15 MPa J. Chem. Thermodyn. 18 1986 1
13. J.B. Ott, G.V. Cornett, C.E. Stouffer, B.F. Woodfield, C. Guanquan, and J.J. Christensen Excess enthalpies of (ethanol + water) at 323.15, 333.15, 348.15, and 373.15 K and from 0.4 to 15 MPa J. Chem. Thermodyn. 18 1986 867
14. J.B. Ott, C.E. Stouffer, G.V. Cornett, B.F. Woodfield, C. Guanquan, and J.J. Christensen Excess enthalpies for (ethanol + water) at 398.15, 423.15, 448.15, and 473.15 K and pressures of 5 and 15 MPa J. Chem. Thermodyn. 19 1987 337
15. D.R. Cordray, R.M. Izatt, J.J. Christensen, and J.L. Oscarson The excess enthalpies of (carbon dioxide + ethanol) at 308.15, 325.15, 373.15, 413.15, and 473.15 K from 5.00 to 14.91 MPa J. Chem. Thermodyn. 20 1988 655
16. R.A. Hauser, J.P. Zhao, P.R. Tremaine, and A.E. Mather Excess molar enthalpies of six (carbon dioxide + a polar solvent) mixture at the temperatures 298.15 and 308.15 K and pressures from 7.5 to 12.6 MPa J. Chem. Thermodyn. 28 1996 1303
17. C. Wormald, M.J. Lloyd, and A. Fenghour The excess enthalpy of (steam + carbon dioxide) in the supercritical region up to T = 698.2 K and p = 25.5 MPa J. Chem. Thermodyn. 29 1977 1253 (and references herein)
18. J.J. Christensen, L.D. Hansen, R.M. Izatt, D.J. Eatough, and R.M. Hart Isothermal flow calorimeter Rev. Sci. Instrum. 47 1976 730
19. R.C. Castells, C. Menduiña, C. Pando, and J.A.R. Renuncio The excess enthalpies of (dinitrogen + toluene) at the temperature 313.15 K and pressures from 7.60 to 15.00 MPa J. Chem. Thermodyn. 26 1994 641
20. 2 + cyclohexane systems in the near-critical and supercritical regions Ind. Eng. Chem. Res. 39 2000 3566
21. http://webbook.nist.gov/chemistry/
22. J.B. Ott, C.E. Sipowska, M.S. Gruszkiewicz, and A.T. Woolley Excess volumes for (ethanol + water) at the temperature (298.15 and 348.15) K and pressures (0.4, 5 and 15) MPa and at the temperature 323.15 K and pressures (5 and 15) MPa J. Chem. Thermodyn. 25 1993 307
23. 2O} in the temperature range from 320 K to 420 K at pressures up to 200 MPa J. Chem. Thermodyn. 28 1996 1375
24. R. Wiebe The binary system carbon dioxide-water under pressure Chem. Rev. 29 1941 475
25. C.R. Coan, and J.A.D. King Solubility of water in compressed carbon dioxide, nitrous oxide, and ethane. Evidence for hydration of carbon dioxide and nitrous oxide in the gas phase J. Am. Chem. Soc. 93 1971 1857
26. 2 in water from -1.5 to 100 °C and from 0.1 to 100 MPa: evaluation of literature data and thermodynamic modeling Fluid Phase Equilib. 208 2003 265
27. F. Kohler Estimation of the thermodynamic data for a ternary system from the corresponding binary systems Monatsh. Chem. 91 1960 738
28. D.Y. Peng, and D.B. Robinson A new two-constant equation of state Ind. Eng. Chem. Fundam. 15 1976 59
29. D.S.H. Wong, and S.I. Sandler A theoretically correct mixing rule for cubic equations of state for both highly and slightly nonideal mixtures AIChE J. 38 1992 671
30. H. Renon, and J.M. Prausnitz Local compositions in thermodynamic excess function for liquid mixtures AIChE J. 14 1968 135